Metathesis of Functionalized Alkane: Understanding the Unsolved Story

Mykyta Tretiakov; Yury Lebedev; Manoja Samantaray; Aya Saidi; Magnus Rueping; Jean-Marie Basset

doi:10.3390/catal9030238

Metathesis of Functionalized Alkane: Understanding the Unsolved Story

Mykyta Tretiakov, Yury Lebedev, Manoja Samantaray, Aya Saidi, Magnus Rueping, Jean-Marie Basset

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1 Scopus citations

Abstract

For the first time, we developed a method which enables a functionalized alkane to be metathesized to its lower and higher homologues. For this metathesis reaction, we used [(≡Si-O-)W(CH3)5] as a catalyst precursor and 9-hexyl-9H-carbazole as a reactant.

Original language	English (US)
Pages (from-to)	238
Journal	Catalysts
Volume	9
Issue number	3
DOIs	https://doi.org/10.3390/catal9030238
State	Published - Mar 4 2019

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: Funding: This work was supported by funds from King Abdullah University of Science and Technology (KAUST). Acknowledgments: The authors acknowledge Salim Sioud (KAUST ACL Core Lab), Kristina Smirnova and Miguel Dinis Veloso Guerreiro for technical assistance.

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https://repository.kaust.edu.sa/bitstream/10754/631547/1/catalysts-09-00238-v2.pdf

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abstract = "For the first time, we developed a method which enables a functionalized alkane to be metathesized to its lower and higher homologues. For this metathesis reaction, we used [(≡Si-O-)W(CH3)5] as a catalyst precursor and 9-hexyl-9H-carbazole as a reactant.",

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AU - Samantaray, Manoja

AU - Saidi, Aya

AU - Rueping, Magnus

AU - Basset, Jean-Marie

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: Funding: This work was supported by funds from King Abdullah University of Science and Technology (KAUST). Acknowledgments: The authors acknowledge Salim Sioud (KAUST ACL Core Lab), Kristina Smirnova and Miguel Dinis Veloso Guerreiro for technical assistance.

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AB - For the first time, we developed a method which enables a functionalized alkane to be metathesized to its lower and higher homologues. For this metathesis reaction, we used [(≡Si-O-)W(CH3)5] as a catalyst precursor and 9-hexyl-9H-carbazole as a reactant.

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Metathesis of Functionalized Alkane: Understanding the Unsolved Story

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