Metathesis of Ω-unsaturated glycosides with chloro-aryloxide complexes of tungsten, as a new synthetic route leading to unsaturated neutral bolaforms

Jan Ramza; Gerard Descotes; Jean Marie Basset; Andy Mutch

doi:10.1080/07328309608005433

Metathesis of Ω-unsaturated glycosides with chloro-aryloxide complexes of tungsten, as a new synthetic route leading to unsaturated neutral bolaforms

Jan Ramza^*, Gerard Descotes, Jean Marie Basset, Andy Mutch

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

Glucosides of unsaturated alcohols, bearing different functional groups on the carbohydrate units, underwent catalytic metathesis reaction affording neutral bolaforms in good yields. Tungsten aryloxo-complexes (1 and 2), due to large steric hindrance, were found to be superior catalysts for this process.

Original language	English (US)
Pages (from-to)	125-136
Number of pages	12
Journal	Journal of Carbohydrate Chemistry
Volume	15
Issue number	2
DOIs	https://doi.org/10.1080/07328309608005433
State	Published - 1996
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Organic Chemistry

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title = "Metathesis of Ω-unsaturated glycosides with chloro-aryloxide complexes of tungsten, as a new synthetic route leading to unsaturated neutral bolaforms",

abstract = "Glucosides of unsaturated alcohols, bearing different functional groups on the carbohydrate units, underwent catalytic metathesis reaction affording neutral bolaforms in good yields. Tungsten aryloxo-complexes (1 and 2), due to large steric hindrance, were found to be superior catalysts for this process.",

author = "Jan Ramza and Gerard Descotes and Basset, {Jean Marie} and Andy Mutch",

year = "1996",

doi = "10.1080/07328309608005433",

language = "English (US)",

volume = "15",

pages = "125--136",

journal = "Journal of Carbohydrate Chemistry",

issn = "0732-8303",

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number = "2",

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T1 - Metathesis of Ω-unsaturated glycosides with chloro-aryloxide complexes of tungsten, as a new synthetic route leading to unsaturated neutral bolaforms

AU - Ramza, Jan

AU - Descotes, Gerard

AU - Basset, Jean Marie

AU - Mutch, Andy

PY - 1996

Y1 - 1996

N2 - Glucosides of unsaturated alcohols, bearing different functional groups on the carbohydrate units, underwent catalytic metathesis reaction affording neutral bolaforms in good yields. Tungsten aryloxo-complexes (1 and 2), due to large steric hindrance, were found to be superior catalysts for this process.

AB - Glucosides of unsaturated alcohols, bearing different functional groups on the carbohydrate units, underwent catalytic metathesis reaction affording neutral bolaforms in good yields. Tungsten aryloxo-complexes (1 and 2), due to large steric hindrance, were found to be superior catalysts for this process.

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U2 - 10.1080/07328309608005433

DO - 10.1080/07328309608005433

M3 - Article

AN - SCOPUS:0030542922

SN - 0732-8303

VL - 15

SP - 125

EP - 136

JO - Journal of Carbohydrate Chemistry

JF - Journal of Carbohydrate Chemistry

IS - 2

ER -

Metathesis of Ω-unsaturated glycosides with chloro-aryloxide complexes of tungsten, as a new synthetic route leading to unsaturated neutral bolaforms

Abstract

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