Metal–organic frameworks for H2 and CH4 storage: insights on the pore geometry–sorption energetics relationship

Mohamed Al Kordi; Youssef Belmabkhout; Amy Cairns; Mohamed Eddaoudi

doi:10.1107/S2052252516019060

Metal–organic frameworks for H2 and CH4 storage: insights on the pore geometry–sorption energetics relationship

Mohamed Al Kordi, Youssef Belmabkhout, Amy Cairns, Mohamed Eddaoudi

Research output: Contribution to journal › Article › peer-review

32 Scopus citations

Abstract

This study aims to assess the possibility of improving H2 and CH4 binding affinity to the aromatic walls of a designed new Metal-Organic Framework (MOF) through simultaneous dispersive interactions. It is suggested here that desirable H2 and CH4 storage media at low pressures require narrow uniform pores associated with large surface area, a trade-off that is challenging to achieve.

Original language	English (US)
Pages (from-to)	131-135
Number of pages	5
Journal	IUCrJ
Volume	4
Issue number	2
DOIs	https://doi.org/10.1107/S2052252516019060
State	Published - Feb 10 2017

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: We acknowledge funding from King Abdullah University of Science and Technology (KAUST).

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10.1107/S2052252516019060

https://repository.kaust.edu.sa/bitstream/10754/623006/1/lq5001.pdf

Cite this

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abstract = "This study aims to assess the possibility of improving H2 and CH4 binding affinity to the aromatic walls of a designed new Metal-Organic Framework (MOF) through simultaneous dispersive interactions. It is suggested here that desirable H2 and CH4 storage media at low pressures require narrow uniform pores associated with large surface area, a trade-off that is challenging to achieve.",

author = "{Al Kordi}, Mohamed and Youssef Belmabkhout and Amy Cairns and Mohamed Eddaoudi",

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AU - Cairns, Amy

AU - Eddaoudi, Mohamed

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AB - This study aims to assess the possibility of improving H2 and CH4 binding affinity to the aromatic walls of a designed new Metal-Organic Framework (MOF) through simultaneous dispersive interactions. It is suggested here that desirable H2 and CH4 storage media at low pressures require narrow uniform pores associated with large surface area, a trade-off that is challenging to achieve.

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Metal–organic frameworks for H2 and CH4 storage: insights on the pore geometry–sorption energetics relationship

Abstract

Bibliographical note

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CCDC 1528379: Experimental Crystal Structure Determination : catena-[(mu7-4,4'-Sulfonyldibenzoato)-lead(ii)]

Cite this

Metal–organic frameworks for H2 and CH4 storage: insights on the pore geometry–sorption energetics relationship

Abstract

Bibliographical note

Access to Document

Other files and links

Fingerprint

Datasets

CCDC 1528379: Experimental Crystal Structure Determination : catena-[(mu7-4,4'-Sulfonyldibenzoato)-lead(ii)]

Cite this