Metal-organic frameworks constructed from pentagonal antiprismatic and cuboctahedral secondary building units

D. T. Vodak; M. E. Braun; J. Kim; Mohamed Eddaoudi; O. M. Yaghi

Metal-organic frameworks constructed from pentagonal antiprismatic and cuboctahedral secondary building units

D. T. Vodak, M. E. Braun, J. Kim, Mohamed Eddaoudi, O. M. Yaghi^*

^*Corresponding author for this work

Physical Sciences and Engineering

Research output: Contribution to journal › Article › peer-review

136 Scopus citations

Abstract

Two crystalline metal-organic frameworks formulated as Zn₆(NDC)₅(OH)₂(DMF)₂·4DMF, MOF-48, and Zn₇(m-BDC)₆(OH)₄(H ₂O)₂·6DMF-4H₂O, MOF-49, (NDC = 1,4-naphthalenedicarboxylate; m-BDC = 1,3-benzenedicarboxylate) have been synthesized and fully characterized by single crystal X-ray diffraction studies, which reveal that the frameworks are constructed from pentagonal antiprismatic (MOF-48) and cuboctahedral (MOF-49) secondary building units respectively, however, both are reticulated into 3-D structures having the B network of CaB₆.

Original language	English (US)
Pages (from-to)	2534-2535
Number of pages	2
Journal	Chemical Communications
Issue number	24
State	Published - Dec 21 2001

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Cite this

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title = "Metal-organic frameworks constructed from pentagonal antiprismatic and cuboctahedral secondary building units",

abstract = "Two crystalline metal-organic frameworks formulated as Zn6(NDC)5(OH)2(DMF)2·4DMF, MOF-48, and Zn7(m-BDC)6(OH)4(H 2O)2·6DMF-4H2O, MOF-49, (NDC = 1,4-naphthalenedicarboxylate; m-BDC = 1,3-benzenedicarboxylate) have been synthesized and fully characterized by single crystal X-ray diffraction studies, which reveal that the frameworks are constructed from pentagonal antiprismatic (MOF-48) and cuboctahedral (MOF-49) secondary building units respectively, however, both are reticulated into 3-D structures having the B network of CaB6.",

author = "Vodak, {D. T.} and Braun, {M. E.} and J. Kim and Mohamed Eddaoudi and Yaghi, {O. M.}",

year = "2001",

month = dec,

day = "21",

language = "English (US)",

pages = "2534--2535",

journal = "Chemical Communications",

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TY - JOUR

T1 - Metal-organic frameworks constructed from pentagonal antiprismatic and cuboctahedral secondary building units

AU - Vodak, D. T.

AU - Braun, M. E.

AU - Kim, J.

AU - Eddaoudi, Mohamed

AU - Yaghi, O. M.

PY - 2001/12/21

Y1 - 2001/12/21

N2 - Two crystalline metal-organic frameworks formulated as Zn6(NDC)5(OH)2(DMF)2·4DMF, MOF-48, and Zn7(m-BDC)6(OH)4(H 2O)2·6DMF-4H2O, MOF-49, (NDC = 1,4-naphthalenedicarboxylate; m-BDC = 1,3-benzenedicarboxylate) have been synthesized and fully characterized by single crystal X-ray diffraction studies, which reveal that the frameworks are constructed from pentagonal antiprismatic (MOF-48) and cuboctahedral (MOF-49) secondary building units respectively, however, both are reticulated into 3-D structures having the B network of CaB6.

AB - Two crystalline metal-organic frameworks formulated as Zn6(NDC)5(OH)2(DMF)2·4DMF, MOF-48, and Zn7(m-BDC)6(OH)4(H 2O)2·6DMF-4H2O, MOF-49, (NDC = 1,4-naphthalenedicarboxylate; m-BDC = 1,3-benzenedicarboxylate) have been synthesized and fully characterized by single crystal X-ray diffraction studies, which reveal that the frameworks are constructed from pentagonal antiprismatic (MOF-48) and cuboctahedral (MOF-49) secondary building units respectively, however, both are reticulated into 3-D structures having the B network of CaB6.

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M3 - Article

AN - SCOPUS:0035930637

SN - 1359-7345

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EP - 2535

JO - Chemical Communications

JF - Chemical Communications

IS - 24

ER -

Metal-organic frameworks constructed from pentagonal antiprismatic and cuboctahedral secondary building units

Abstract

ASJC Scopus subject areas

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