Metal-organic framework based mixed matrix membranes: A solution for highly efficient CO2 capture?

Beatriz Seoane, Joaquin Coronas, Ignacio Gascon, Miren Etxeberria Benavides, Oʇuz Karvan, Jürgen Caro, Freek Kapteijn, Jorge Gascon Sabate*

*Corresponding author for this work

Research output: Contribution to journalReview articlepeer-review

704 Scopus citations


The field of metal-organic framework based mixed matrix membranes (M4s) is critically reviewed, with special emphasis on their application in CO2 capture during energy generation. After introducing the most relevant parameters affecting membrane performance, we define targets in terms of selectivity and productivity based on existing literature on process design for pre- and post-combustion CO2 capture. Subsequently, the state of the art in M4s is reviewed against these targets. Because final application of these membranes will only be possible if thin separation layers can be produced, the latest advances in the manufacture of M4 hollow fibers are discussed. Finally, the recent efforts in understanding the separation performance of these complex composite materials and future research directions are outlined.

Original languageEnglish (US)
Pages (from-to)2421-2454
Number of pages34
JournalChemical Society Reviews
Issue number8
StatePublished - Apr 21 2015

ASJC Scopus subject areas

  • General Chemistry


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