Metal-free C-Se cross-coupling enabled by photoinduced inter-molecular charge transfer

Chen Zhu; Serik Zhumagazy; Huifeng Yue; Magnus Rueping

doi:10.1039/d1cc06152f

Metal-free C-Se cross-coupling enabled by photoinduced inter-molecular charge transfer

Chen Zhu, Serik Zhumagazy, Huifeng Yue, Magnus Rueping

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

Metal-free C-Se cross-couplings via the formation of electron-donor-acceptor (EDA) complexes have been developed. The visible-light induced reactions can be applied for the synthesis of a series of unsymmetrical diaryl selenides employing aryl bromides, aryl iodides as well as aryl chlorides under mild reaction conditions. The scale-up was readily achieved. UV-Vis spectroscopy measurements provide insight into the reaction mechanism.

Original language	English (US)
Journal	CHEMICAL COMMUNICATIONS
DOIs	https://doi.org/10.1039/d1cc06152f
State	Published - 2021

Bibliographical note

KAUST Repository Item: Exported on 2021-12-13
Acknowledged KAUST grant number(s): URF/1/4384
Acknowledgements: This work was financially supported by the King Abdullah University of Science and Technology (KAUST), Saudi Arabia, Office of Sponsored Research (URF/1/4384).

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https://repository.kaust.edu.sa/bitstream/10754/673976/1/manuscript.pdf

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title = "Metal-free C-Se cross-coupling enabled by photoinduced inter-molecular charge transfer",

abstract = "Metal-free C-Se cross-couplings via the formation of electron-donor-acceptor (EDA) complexes have been developed. The visible-light induced reactions can be applied for the synthesis of a series of unsymmetrical diaryl selenides employing aryl bromides, aryl iodides as well as aryl chlorides under mild reaction conditions. The scale-up was readily achieved. UV-Vis spectroscopy measurements provide insight into the reaction mechanism.",

author = "Chen Zhu and Serik Zhumagazy and Huifeng Yue and Magnus Rueping",

note = "KAUST Repository Item: Exported on 2021-12-13 Acknowledged KAUST grant number(s): URF/1/4384 Acknowledgements: This work was financially supported by the King Abdullah University of Science and Technology (KAUST), Saudi Arabia, Office of Sponsored Research (URF/1/4384).",

year = "2021",

doi = "10.1039/d1cc06152f",

language = "English (US)",

journal = "CHEMICAL COMMUNICATIONS",

issn = "1364-548X",

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T1 - Metal-free C-Se cross-coupling enabled by photoinduced inter-molecular charge transfer

AU - Zhu, Chen

AU - Zhumagazy, Serik

AU - Yue, Huifeng

AU - Rueping, Magnus

N1 - KAUST Repository Item: Exported on 2021-12-13 Acknowledged KAUST grant number(s): URF/1/4384 Acknowledgements: This work was financially supported by the King Abdullah University of Science and Technology (KAUST), Saudi Arabia, Office of Sponsored Research (URF/1/4384).

PY - 2021

Y1 - 2021

N2 - Metal-free C-Se cross-couplings via the formation of electron-donor-acceptor (EDA) complexes have been developed. The visible-light induced reactions can be applied for the synthesis of a series of unsymmetrical diaryl selenides employing aryl bromides, aryl iodides as well as aryl chlorides under mild reaction conditions. The scale-up was readily achieved. UV-Vis spectroscopy measurements provide insight into the reaction mechanism.

AB - Metal-free C-Se cross-couplings via the formation of electron-donor-acceptor (EDA) complexes have been developed. The visible-light induced reactions can be applied for the synthesis of a series of unsymmetrical diaryl selenides employing aryl bromides, aryl iodides as well as aryl chlorides under mild reaction conditions. The scale-up was readily achieved. UV-Vis spectroscopy measurements provide insight into the reaction mechanism.

UR - http://hdl.handle.net/10754/673976

UR - http://xlink.rsc.org/?DOI=D1CC06152F

U2 - 10.1039/d1cc06152f

DO - 10.1039/d1cc06152f

M3 - Article

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SN - 1364-548X

JO - CHEMICAL COMMUNICATIONS

JF - CHEMICAL COMMUNICATIONS

ER -

Metal-free C-Se cross-coupling enabled by photoinduced inter-molecular charge transfer

Abstract

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