@inbook{9581d20657b445a6ad294faca527c8a1,
title = "Mechanism of gold-catalyzed cycloisomerization of enynyl esters",
abstract = "A theoretical study on the Au-catalyzed cycloisomerization of a branched dienyne possessing an acetate at the propargylic position is presented. The peculiar architecture of the dienyne precursor, exhibiting both a 1,6- and a 1,5-enyne skeleton, leads, in the presence of alkynophilic gold catalysts, to a mixture of bicyclic compounds. DFT calculations are presented that rationalize in full THE manifold of reactions that lead to the different products.",
keywords = "Allenes, Cycloisomerization, Density functional theory calculations, Enynes, Gold catalysis, Homogeneous catalysis, Propargylic esters",
author = "Andrea Correa and Luigi Cavallo",
year = "2010",
doi = "10.1007/978-90-481-3433-5_18",
language = "English (US)",
isbn = "9789048134311",
series = "NATO Science for Peace and Security Series A: Chemistry and Biology",
publisher = "Springer Verlag",
pages = "293--303",
booktitle = "Green Metathesis Chemistry",
address = "Germany",
}