Mechanism and Regioselectivity of Rh(III)-Catalyzed Intermolecular Annulation of Aryl-Substituted Diazenecarboxylates and Alkenes: DFT Insights

Chemistry

• Alkene 100%
• Density Functional Theory 100%
• Regioselectivity 100%
• Ring Formation 100%
• Kinetic Study 33%
• Density Functional Theory Study 33%
• Rate-Determining Step 33%
• Diazene 33%
• Nitrogen Atom 33%

Keyphrases

• Rh(III)-catalyzed 100%
• Cyclization Processes 33%
• Diazene 33%
• Rhodacycle 33%
• Ligand-assisted 33%
• Site Selectivity 33%
• Acetate Ligand 33%
• Alkene Insertion 33%