Mark-Houwink-Sakurada coefficients for conventional poly(methyl methacrylate) in tetrahydrofuran

Yuan Ju Chen; Jianbo Li; Nikos Hadjichristidis; Jimmy W. Mays

doi:10.1007/BF00296477

Mark-Houwink-Sakurada coefficients for conventional poly(methyl methacrylate) in tetrahydrofuran

Yuan Ju Chen^*, Jianbo Li, Nikos Hadjichristidis, Jimmy W. Mays

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

Intrinsic viscosities [η] in tetrahydrofuran (THF) at 30°C are reported for ten narrow molecular weight distribution poly(methyl methacrylate) (PMMA) samples covering nearly two orders of magnitude in molecular weight. By combining the viscosity results with absolute weight-average molecular weights {Mathematical expression} determined via low-angle laser light scattering (LALLS) experiments, we have accurately determined the Mark-Houwink-Sakurada (MHS) parameters for this polymer-solvent pair (K=7.56x10⁵ and a=0.731, when [η] is in dL g^-1).

Original language	English (US)
Pages (from-to)	575-578
Number of pages	4
Journal	Polymer Bulletin
Volume	30
Issue number	5
DOIs	https://doi.org/10.1007/BF00296477
State	Published - May 1993
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
Condensed Matter Physics
Polymers and Plastics
Materials Chemistry

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title = "Mark-Houwink-Sakurada coefficients for conventional poly(methyl methacrylate) in tetrahydrofuran",

abstract = "Intrinsic viscosities [η] in tetrahydrofuran (THF) at 30°C are reported for ten narrow molecular weight distribution poly(methyl methacrylate) (PMMA) samples covering nearly two orders of magnitude in molecular weight. By combining the viscosity results with absolute weight-average molecular weights {Mathematical expression} determined via low-angle laser light scattering (LALLS) experiments, we have accurately determined the Mark-Houwink-Sakurada (MHS) parameters for this polymer-solvent pair (K=7.56x105 and a=0.731, when [η] is in dL g-1).",

author = "Chen, {Yuan Ju} and Jianbo Li and Nikos Hadjichristidis and Mays, {Jimmy W.}",

year = "1993",

month = may,

doi = "10.1007/BF00296477",

language = "English (US)",

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pages = "575--578",

journal = "Polymer Bulletin",

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T1 - Mark-Houwink-Sakurada coefficients for conventional poly(methyl methacrylate) in tetrahydrofuran

AU - Chen, Yuan Ju

AU - Li, Jianbo

AU - Hadjichristidis, Nikos

AU - Mays, Jimmy W.

PY - 1993/5

Y1 - 1993/5

N2 - Intrinsic viscosities [η] in tetrahydrofuran (THF) at 30°C are reported for ten narrow molecular weight distribution poly(methyl methacrylate) (PMMA) samples covering nearly two orders of magnitude in molecular weight. By combining the viscosity results with absolute weight-average molecular weights {Mathematical expression} determined via low-angle laser light scattering (LALLS) experiments, we have accurately determined the Mark-Houwink-Sakurada (MHS) parameters for this polymer-solvent pair (K=7.56x105 and a=0.731, when [η] is in dL g-1).

AB - Intrinsic viscosities [η] in tetrahydrofuran (THF) at 30°C are reported for ten narrow molecular weight distribution poly(methyl methacrylate) (PMMA) samples covering nearly two orders of magnitude in molecular weight. By combining the viscosity results with absolute weight-average molecular weights {Mathematical expression} determined via low-angle laser light scattering (LALLS) experiments, we have accurately determined the Mark-Houwink-Sakurada (MHS) parameters for this polymer-solvent pair (K=7.56x105 and a=0.731, when [η] is in dL g-1).

UR - http://www.scopus.com/inward/record.url?scp=0000036735&partnerID=8YFLogxK

U2 - 10.1007/BF00296477

DO - 10.1007/BF00296477

M3 - Article

AN - SCOPUS:0000036735

SN - 0170-0839

VL - 30

SP - 575

EP - 578

JO - Polymer Bulletin

JF - Polymer Bulletin

IS - 5

ER -

Mark-Houwink-Sakurada coefficients for conventional poly(methyl methacrylate) in tetrahydrofuran

Abstract

ASJC Scopus subject areas

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