TY - JOUR
T1 - Magnesium complexes in hydroelementation and reduction catalysis: Opportunities and Challenges
AU - Magre, Marc
AU - Szewczyk, Marcin
AU - Rueping, Magnus
N1 - KAUST Repository Item: Exported on 2021-06-16
PY - 2021/6/10
Y1 - 2021/6/10
N2 - The addition of a Y-H (Y= B, Si, Sn, N, P and O) bonds and H2 to unsaturated bonds is a powerful and atom economic method for the synthesis of fine chemicals. In the recent years, magnesium-based organometallic complexes have appeared as an alternative to transition metal catalysts for the hydrofunctionalization and hydrogenation of unsaturated systems. This review focuses on the progress of magnesium catalysis for the hydrofunctionalization and hydrogenation of unsaturated bonds, provides a critical assessment of the state-of-the-art research, highlights the major developments achieved in the past three years and provides an overview of the challenges and opportunities.
AB - The addition of a Y-H (Y= B, Si, Sn, N, P and O) bonds and H2 to unsaturated bonds is a powerful and atom economic method for the synthesis of fine chemicals. In the recent years, magnesium-based organometallic complexes have appeared as an alternative to transition metal catalysts for the hydrofunctionalization and hydrogenation of unsaturated systems. This review focuses on the progress of magnesium catalysis for the hydrofunctionalization and hydrogenation of unsaturated bonds, provides a critical assessment of the state-of-the-art research, highlights the major developments achieved in the past three years and provides an overview of the challenges and opportunities.
UR - http://hdl.handle.net/10754/669587
UR - https://linkinghub.elsevier.com/retrieve/pii/S2452223621000821
U2 - 10.1016/j.cogsc.2021.100526
DO - 10.1016/j.cogsc.2021.100526
M3 - Article
SN - 2452-2236
SP - 100526
JO - Current Opinion in Green and Sustainable Chemistry
JF - Current Opinion in Green and Sustainable Chemistry
ER -