Abstract
In this work, a pre-designed Zr-based-MOF encompassing an organic linker with a redox active core is synthesized and its structure-property relationship as a supercapacitor electrode is investigated. An enhanced performance is revealed by the combination of this MOF's high porosity and redox core incorporation, which alters its double-layer and pseudocapacitance, respectively. An increase in the capacitance performance by a factor of two is achieved via post-synthetic structure rigidification using organic pillars.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 1883-1886 |
| Number of pages | 4 |
| Journal | Chemical communications (Cambridge, England) |
| Volume | 56 |
| Issue number | 12 |
| DOIs | |
| State | Published - 2020 |
Bibliographical note
KAUST Repository Item: Exported on 2020-10-01Acknowledged KAUST grant number(s): CRG2017
Acknowledgements: This work was financially supported by the King Abdullah University of Science and Technology (KAUST) under Award No.OSR-CRG2017 3379.
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CCDC 1849328: Experimental Crystal Structure Determination : catena-[(mu-25,35-(1,3,6,8-tetraoxo-1,3,6,8-tetrahydrobenzo[lmn][3,8]phenanthroline-2,7-diyl)bis([11,21:23,31-terphenyl]-14,34-dicarboxyato))-tetrakis(mu-oxo)-tetra-aqua-tri-zirconium(iv) unknown
Mallick, A. (Creator), Liang, H. (Creator), Shekhah, O. (Creator), Jia, J. (Creator), Mouchaham, G. (Creator), Shkurenko, A. (Creator), Belmabkhout, Y. (Creator), Alshareef, H. N. (Creator), Eddaoudi, M. (Creator) & Alshareef, H. N. (Creator), Cambridge Crystallographic Data Centre, Jan 18 2020
DOI: 10.5517/ccdc.csd.cc202cr7, http://hdl.handle.net/10754/664839
Dataset