Low temperature activation of methane over a zinc-exchanged heteropolyacid as an entry to its selective oxidation to methanol and acetic acid

Umesh Patil; Youssef Saih; Edy Abou-Hamad; Ali Imad Ali Hamieh; Jeremie Pelletier; Jean-Marie Basset

doi:10.1039/c4cc04950k

Low temperature activation of methane over a zinc-exchanged heteropolyacid as an entry to its selective oxidation to methanol and acetic acid

Umesh Patil, Youssef Saih, Edy Abou-Hamad, Ali Imad Ali Hamieh, Jeremie Pelletier, Jean-Marie Basset

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

A Zn-exchanged heteropolyacid supported onto silica (Zn-HPW/SiO2) activates methane at 25 °C into Zn-methyl. At higher temperatures and with CH4/O2 or CH4/CO2, it gives methanol and acetic acid respectively. This journal is

Original language	English (US)
Pages (from-to)	12348-12351
Number of pages	4
Journal	Chem. Commun.
Volume	50
Issue number	82
DOIs	https://doi.org/10.1039/c4cc04950k
State	Published - 2014

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: We gratefully acknowledge King Abdullah University of Science and Technology (KAUST) and Saudi Basic Industries Corporation (SABIC) for financial support.

ASJC Scopus subject areas

Materials Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Ceramics and Composites
General Chemistry
Catalysis
Electronic, Optical and Magnetic Materials

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10.1039/c4cc04950k

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author = "Umesh Patil and Youssef Saih and Edy Abou-Hamad and Hamieh, {Ali Imad Ali} and Jeremie Pelletier and Jean-Marie Basset",

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AU - Patil, Umesh

AU - Saih, Youssef

AU - Abou-Hamad, Edy

AU - Hamieh, Ali Imad Ali

AU - Pelletier, Jeremie

AU - Basset, Jean-Marie

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: We gratefully acknowledge King Abdullah University of Science and Technology (KAUST) and Saudi Basic Industries Corporation (SABIC) for financial support.

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Y1 - 2014

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AB - A Zn-exchanged heteropolyacid supported onto silica (Zn-HPW/SiO2) activates methane at 25 °C into Zn-methyl. At higher temperatures and with CH4/O2 or CH4/CO2, it gives methanol and acetic acid respectively. This journal is

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Low temperature activation of methane over a zinc-exchanged heteropolyacid as an entry to its selective oxidation to methanol and acetic acid

Abstract

Bibliographical note

ASJC Scopus subject areas

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