Linear high molecular weight ladder polymers by optimized polycondensation of tetrahydroxytetramethylspirobisindane and 1,4-dicyanotetrafluorobenzene

Jingshe Song; Naiying Du; Ying Dai; Gilles P. Robertson; Michael D. Guiver; Sylvie Thomas; Ingo Pinnau

doi:10.1021/ma801000u

Linear high molecular weight ladder polymers by optimized polycondensation of tetrahydroxytetramethylspirobisindane and 1,4-dicyanotetrafluorobenzene

Jingshe Song, Naiying Du, Ying Dai, Gilles P. Robertson, Michael D. Guiver, Sylvie Thomas, Ingo Pinnau

Research output: Contribution to journal › Article › peer-review

100 Scopus citations

Abstract

A study on the optimization of conditions for polycondensation of 3,3,3′,3′-tetramethyl-1,1′-spirobisindane-5,5′,6, 6′-tetrol, TTSBI, with 1,4-dicyanotetrafluorobenzene (DCTB) in dimethylformamide (DMF) at 50-70 °C is reported. A linear PIM-1 polymer (PIM = polymer with intrinsic microporosity) with high molecular weight was obtained by optimized reaction conditions. Of the solvents tested, DMF was the preferred solvent for this reaction. The optimized molar ratio TTSBI/DCTB/K ₂CO₃ was 1/1/2.04. The mechanism of PIM-1 cross-linking during polymerization was studied, and gel-free, high molecular weight PIM-1 polymer was prepared. The physical properties of anhydrous K₂CO ₃ significantly affected the reaction rate, Flexible tough polymer films were cast from PIM-1 solution in chloroform, and pure permeability data are reported for several gases.

Original language	English (US)
Pages (from-to)	7411-7417
Number of pages	7
Journal	Macromolecules
Volume	41
Issue number	20
DOIs	https://doi.org/10.1021/ma801000u
State	Published - Oct 28 2008
Externally published	Yes

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

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@article{6cc053a3d05843a2ac97579bad7aea6b,

title = "Linear high molecular weight ladder polymers by optimized polycondensation of tetrahydroxytetramethylspirobisindane and 1,4-dicyanotetrafluorobenzene",

abstract = "A study on the optimization of conditions for polycondensation of 3,3,3′,3′-tetramethyl-1,1′-spirobisindane-5,5′,6, 6′-tetrol, TTSBI, with 1,4-dicyanotetrafluorobenzene (DCTB) in dimethylformamide (DMF) at 50-70 °C is reported. A linear PIM-1 polymer (PIM = polymer with intrinsic microporosity) with high molecular weight was obtained by optimized reaction conditions. Of the solvents tested, DMF was the preferred solvent for this reaction. The optimized molar ratio TTSBI/DCTB/K 2CO3 was 1/1/2.04. The mechanism of PIM-1 cross-linking during polymerization was studied, and gel-free, high molecular weight PIM-1 polymer was prepared. The physical properties of anhydrous K2CO 3 significantly affected the reaction rate, Flexible tough polymer films were cast from PIM-1 solution in chloroform, and pure permeability data are reported for several gases.",

author = "Jingshe Song and Naiying Du and Ying Dai and Robertson, {Gilles P.} and Guiver, {Michael D.} and Sylvie Thomas and Ingo Pinnau",

year = "2008",

month = oct,

day = "28",

doi = "10.1021/ma801000u",

language = "English (US)",

volume = "41",

pages = "7411--7417",

journal = "Macromolecules",

issn = "0024-9297",

publisher = "American Chemical Society",

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T1 - Linear high molecular weight ladder polymers by optimized polycondensation of tetrahydroxytetramethylspirobisindane and 1,4-dicyanotetrafluorobenzene

AU - Song, Jingshe

AU - Du, Naiying

AU - Dai, Ying

AU - Robertson, Gilles P.

AU - Guiver, Michael D.

AU - Thomas, Sylvie

AU - Pinnau, Ingo

PY - 2008/10/28

Y1 - 2008/10/28

N2 - A study on the optimization of conditions for polycondensation of 3,3,3′,3′-tetramethyl-1,1′-spirobisindane-5,5′,6, 6′-tetrol, TTSBI, with 1,4-dicyanotetrafluorobenzene (DCTB) in dimethylformamide (DMF) at 50-70 °C is reported. A linear PIM-1 polymer (PIM = polymer with intrinsic microporosity) with high molecular weight was obtained by optimized reaction conditions. Of the solvents tested, DMF was the preferred solvent for this reaction. The optimized molar ratio TTSBI/DCTB/K 2CO3 was 1/1/2.04. The mechanism of PIM-1 cross-linking during polymerization was studied, and gel-free, high molecular weight PIM-1 polymer was prepared. The physical properties of anhydrous K2CO 3 significantly affected the reaction rate, Flexible tough polymer films were cast from PIM-1 solution in chloroform, and pure permeability data are reported for several gases.

AB - A study on the optimization of conditions for polycondensation of 3,3,3′,3′-tetramethyl-1,1′-spirobisindane-5,5′,6, 6′-tetrol, TTSBI, with 1,4-dicyanotetrafluorobenzene (DCTB) in dimethylformamide (DMF) at 50-70 °C is reported. A linear PIM-1 polymer (PIM = polymer with intrinsic microporosity) with high molecular weight was obtained by optimized reaction conditions. Of the solvents tested, DMF was the preferred solvent for this reaction. The optimized molar ratio TTSBI/DCTB/K 2CO3 was 1/1/2.04. The mechanism of PIM-1 cross-linking during polymerization was studied, and gel-free, high molecular weight PIM-1 polymer was prepared. The physical properties of anhydrous K2CO 3 significantly affected the reaction rate, Flexible tough polymer films were cast from PIM-1 solution in chloroform, and pure permeability data are reported for several gases.

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U2 - 10.1021/ma801000u

DO - 10.1021/ma801000u

M3 - Article

AN - SCOPUS:55649085078

SN - 0024-9297

VL - 41

SP - 7411

EP - 7417

JO - Macromolecules

JF - Macromolecules

IS - 20

ER -

Linear high molecular weight ladder polymers by optimized polycondensation of tetrahydroxytetramethylspirobisindane and 1,4-dicyanotetrafluorobenzene

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