Light-mediated heterogeneous cross dehydrogenative coupling reactions: Metal oxides as efficient, recyclable, photoredox catalysts in C-C bond-forming reactions

Magnus Rueping; Jochen Zoller; David C. Fabry; Konstantin Poscharny; René M. Koenigs; Thomas E. Weirich; Joachim Mayer

doi:10.1002/chem.201103242

Light-mediated heterogeneous cross dehydrogenative coupling reactions: Metal oxides as efficient, recyclable, photoredox catalysts in C-C bond-forming reactions

Magnus Rueping^*, Jochen Zoller, David C. Fabry, Konstantin Poscharny, René M. Koenigs, Thomas E. Weirich, Joachim Mayer

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

224 Scopus citations

Abstract

Let there be light: A heterogeneous photocatalytic system based on easily recyclable TiO ₂ or ZnO allows cross dehydrogenative coupling reactions of tertiary amines. The newly developed protocols have successfully been applied to various C-C and C-P bond-forming reactions to provide nitro amines as well as amino ketones, nitriles and phosphonates.

Original language	English (US)
Pages (from-to)	3478-3481
Number of pages	4
Journal	Chemistry - A European Journal
Volume	18
Issue number	12
DOIs	https://doi.org/10.1002/chem.201103242
State	Published - Mar 19 2012
Externally published	Yes

Keywords

C-C coupling
heterogeneous catalysis
photocatalysis
redox reaction

ASJC Scopus subject areas

Catalysis
Organic Chemistry

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10.1002/chem.201103242

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title = "Light-mediated heterogeneous cross dehydrogenative coupling reactions: Metal oxides as efficient, recyclable, photoredox catalysts in C-C bond-forming reactions",

abstract = "Let there be light: A heterogeneous photocatalytic system based on easily recyclable TiO 2 or ZnO allows cross dehydrogenative coupling reactions of tertiary amines. The newly developed protocols have successfully been applied to various C-C and C-P bond-forming reactions to provide nitro amines as well as amino ketones, nitriles and phosphonates.",

keywords = "C-C coupling, heterogeneous catalysis, photocatalysis, redox reaction",

author = "Magnus Rueping and Jochen Zoller and Fabry, {David C.} and Konstantin Poscharny and Koenigs, {Ren{\'e} M.} and Weirich, {Thomas E.} and Joachim Mayer",

year = "2012",

month = mar,

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doi = "10.1002/chem.201103242",

language = "English (US)",

volume = "18",

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T1 - Light-mediated heterogeneous cross dehydrogenative coupling reactions

T2 - Metal oxides as efficient, recyclable, photoredox catalysts in C-C bond-forming reactions

AU - Rueping, Magnus

AU - Zoller, Jochen

AU - Fabry, David C.

AU - Poscharny, Konstantin

AU - Koenigs, René M.

AU - Weirich, Thomas E.

AU - Mayer, Joachim

PY - 2012/3/19

Y1 - 2012/3/19

N2 - Let there be light: A heterogeneous photocatalytic system based on easily recyclable TiO 2 or ZnO allows cross dehydrogenative coupling reactions of tertiary amines. The newly developed protocols have successfully been applied to various C-C and C-P bond-forming reactions to provide nitro amines as well as amino ketones, nitriles and phosphonates.

AB - Let there be light: A heterogeneous photocatalytic system based on easily recyclable TiO 2 or ZnO allows cross dehydrogenative coupling reactions of tertiary amines. The newly developed protocols have successfully been applied to various C-C and C-P bond-forming reactions to provide nitro amines as well as amino ketones, nitriles and phosphonates.

KW - C-C coupling

KW - heterogeneous catalysis

KW - photocatalysis

KW - redox reaction

UR - http://www.scopus.com/inward/record.url?scp=84859029745&partnerID=8YFLogxK

U2 - 10.1002/chem.201103242

DO - 10.1002/chem.201103242

M3 - Article

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AN - SCOPUS:84859029745

SN - 0947-6539

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JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 12

ER -

Light-mediated heterogeneous cross dehydrogenative coupling reactions: Metal oxides as efficient, recyclable, photoredox catalysts in C-C bond-forming reactions

Abstract

Keywords

ASJC Scopus subject areas

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