Lanthanide metal organic frameworks based on octahedral secondary building units: Structural, luminescent, and magnetic properties

Hua Bin Zhang; Yan Peng; Xiao Chen Shan; Chong Bin Tian; null Ping-Lin; Shao Wu Du

doi:10.1016/j.inoche.2011.04.014

Lanthanide metal organic frameworks based on octahedral secondary building units: Structural, luminescent, and magnetic properties

Hua Bin Zhang, Yan Peng, Xiao Chen Shan, Chong Bin Tian, Ping-Lin, Shao Wu Du

Research output: Contribution to journal › Article › peer-review

37 Scopus citations

Abstract

Three new lanthanide metal organic frameworks (LnMOFs), [HNMe 2][Ln2(m-BDC)3(phen)2] (Ln = Eu 1, Gd 2, Tb 3, m-H2BDC = 1,3-benzenedicarboxylic acid, phen = 1,10-phenanthroline), have been solvothermally synthesized through self-assembly reactions. Complexes 1-3 are isostructural and possess 3D architectures based on the octahedral [Ln2(COO)6] SBUs with a pcu net topology. Photoluminescence measurements show that 1 and 3 are highly emissive at room temperature with quantum yields of 86.87% (at 330 nm) and 85.62% (at 345 nm), respectively, and may be good candidates for light-emitting diodes (LEDs) and light applications. The magnetic properties of 2 and 3 have also been investigated through the measurement of their magnetic susceptibilities over the temperature range of 2-300 K. © 2011 Elsevier B.V.

Original language	English (US)
Pages (from-to)	1165-1169
Number of pages	5
Journal	Inorganic Chemistry Communications
Volume	14
Issue number	7
DOIs	https://doi.org/10.1016/j.inoche.2011.04.014
State	Published - Jul 1 2011
Externally published	Yes

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Generated from Scopus record by KAUST IRTS on 2022-09-15

ASJC Scopus subject areas

Materials Chemistry
Physical and Theoretical Chemistry
Inorganic Chemistry

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title = "Lanthanide metal organic frameworks based on octahedral secondary building units: Structural, luminescent, and magnetic properties",

abstract = "Three new lanthanide metal organic frameworks (LnMOFs), [HNMe 2][Ln2(m-BDC)3(phen)2] (Ln = Eu 1, Gd 2, Tb 3, m-H2BDC = 1,3-benzenedicarboxylic acid, phen = 1,10-phenanthroline), have been solvothermally synthesized through self-assembly reactions. Complexes 1-3 are isostructural and possess 3D architectures based on the octahedral [Ln2(COO)6] SBUs with a pcu net topology. Photoluminescence measurements show that 1 and 3 are highly emissive at room temperature with quantum yields of 86.87% (at 330 nm) and 85.62% (at 345 nm), respectively, and may be good candidates for light-emitting diodes (LEDs) and light applications. The magnetic properties of 2 and 3 have also been investigated through the measurement of their magnetic susceptibilities over the temperature range of 2-300 K. {\textcopyright} 2011 Elsevier B.V.",

author = "Zhang, {Hua Bin} and Yan Peng and Shan, {Xiao Chen} and Tian, {Chong Bin} and Ping-Lin and Du, {Shao Wu}",

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year = "2011",

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doi = "10.1016/j.inoche.2011.04.014",

language = "English (US)",

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T1 - Lanthanide metal organic frameworks based on octahedral secondary building units: Structural, luminescent, and magnetic properties

AU - Zhang, Hua Bin

AU - Peng, Yan

AU - Shan, Xiao Chen

AU - Tian, Chong Bin

AU - Ping-Lin, null

AU - Du, Shao Wu

N1 - Generated from Scopus record by KAUST IRTS on 2022-09-15

PY - 2011/7/1

Y1 - 2011/7/1

N2 - Three new lanthanide metal organic frameworks (LnMOFs), [HNMe 2][Ln2(m-BDC)3(phen)2] (Ln = Eu 1, Gd 2, Tb 3, m-H2BDC = 1,3-benzenedicarboxylic acid, phen = 1,10-phenanthroline), have been solvothermally synthesized through self-assembly reactions. Complexes 1-3 are isostructural and possess 3D architectures based on the octahedral [Ln2(COO)6] SBUs with a pcu net topology. Photoluminescence measurements show that 1 and 3 are highly emissive at room temperature with quantum yields of 86.87% (at 330 nm) and 85.62% (at 345 nm), respectively, and may be good candidates for light-emitting diodes (LEDs) and light applications. The magnetic properties of 2 and 3 have also been investigated through the measurement of their magnetic susceptibilities over the temperature range of 2-300 K. © 2011 Elsevier B.V.

AB - Three new lanthanide metal organic frameworks (LnMOFs), [HNMe 2][Ln2(m-BDC)3(phen)2] (Ln = Eu 1, Gd 2, Tb 3, m-H2BDC = 1,3-benzenedicarboxylic acid, phen = 1,10-phenanthroline), have been solvothermally synthesized through self-assembly reactions. Complexes 1-3 are isostructural and possess 3D architectures based on the octahedral [Ln2(COO)6] SBUs with a pcu net topology. Photoluminescence measurements show that 1 and 3 are highly emissive at room temperature with quantum yields of 86.87% (at 330 nm) and 85.62% (at 345 nm), respectively, and may be good candidates for light-emitting diodes (LEDs) and light applications. The magnetic properties of 2 and 3 have also been investigated through the measurement of their magnetic susceptibilities over the temperature range of 2-300 K. © 2011 Elsevier B.V.

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DO - 10.1016/j.inoche.2011.04.014

M3 - Article

SN - 1387-7003

VL - 14

SP - 1165

EP - 1169

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 7

ER -

Lanthanide metal organic frameworks based on octahedral secondary building units: Structural, luminescent, and magnetic properties

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