K
                        10
                        M
                        4
                        M′
                        4
                        S
                        17
                         (M = Mn, Fe, Co, Zn; M′ = Sn, Ge) and Cs
                        10
                        Cd
                        4
                        Sn
                        4
                        S 
                        17: Compounds with a discrete supertetrahedral cluster

Oleg Palchik; Ratnasabapathy G. Iyer; Christian Canlas; David P. Weliky; Mercouri G. Kanatzidis

doi:10.1002/zaac.200400154

K ₁₀ M ₄ M′ ₄ S ₁₇ (M = Mn, Fe, Co, Zn; M′ = Sn, Ge) and Cs ₁₀ Cd ₄ Sn ₄ S ₁₇: Compounds with a discrete supertetrahedral cluster

Oleg Palchik^*, Ratnasabapathy G. Iyer, Christian Canlas, David P. Weliky, Mercouri G. Kanatzidis

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

49 Scopus citations

Abstract

The cluster compounds K ₁₀ Zn ₄ Sn ₄ S ₁₇ , K ₁₀ Mn ₄ Sn ₄ S ₁₇ , K ₁₀ Fe ₄ Sn ₄ S ₁₇ , K ₁₀ Co ₄ Sn ₄ S ₁₇ , Cs ₁₀ Cd ₄ Sn ₄ S ₁₇ and K ₁₀ Zn ₄ Ge ₄ S ₁₇ are described. The structures of these compounds, refined by single-crystal X-ray diffraction techniques, contain the discrete cluster [M ₄ M′ ₄ S ₁₇ ] ^10- (M = Zn, Mn, Co, Fe, Cd; M′ = Sn or Ge) which has the structure of Si ₈ C ₁₇ H ₃₆ . It is built from the sulfur-connected tetrahedral SnS ₄ and MS ₄ units with the additional quadruply bridging sulfur atom at the center of the cluster. All compound show some solubility and stability in water and formamide. Cs ₁₀ Cd ₄ Sn ₄ S ₁₇ and K ₁₀ Zn ₄ Ge ₄ S ₁₇ show photoluminescence at room temperature.The magnetic properties of K ₁₀ Mn ₄ Sn ₄ S ₁₇ , K ₁₀ Fe ₄ Sn ₄ S ₁₇ , K ₁₀ Co ₄ Sn ₄ S ₁₇ indicate strong antiferromagnetic interactions arising from spin coupling within the cluster but their magnetic susceptibility is characterized with a discrepancy between field-cooled and zero field-cooled measurements.

Original language	English (US)
Pages (from-to)	2237-2247
Number of pages	11
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	630
Issue number	13-14
DOIs	https://doi.org/10.1002/zaac.200400154
State	Published - Dec 1 2004

Keywords

Cluster compound
Germanium
Sulfides
Tin

ASJC Scopus subject areas

Inorganic Chemistry

Access to Document

10.1002/zaac.200400154

Cite this

Palchik, O., Iyer, R. G., Canlas, C., Weliky, D. P., & Kanatzidis, M. G. (2004). K ₁₀ M ₄ M′ ₄ S ₁₇ (M = Mn, Fe, Co, Zn; M′ = Sn, Ge) and Cs ₁₀ Cd ₄ Sn ₄ S ₁₇: Compounds with a discrete supertetrahedral cluster. Zeitschrift fur Anorganische und Allgemeine Chemie, 630(13-14), 2237-2247. https://doi.org/10.1002/zaac.200400154

Palchik, Oleg ; Iyer, Ratnasabapathy G. ; Canlas, Christian et al. / K ₁₀ M ₄ M′ ₄ S ₁₇ (M = Mn, Fe, Co, Zn; M′ = Sn, Ge) and Cs ₁₀ Cd ₄ Sn ₄ S ₁₇ : Compounds with a discrete supertetrahedral cluster. In: Zeitschrift fur Anorganische und Allgemeine Chemie. 2004 ; Vol. 630, No. 13-14. pp. 2237-2247.

@article{acd67aaa06ef44518b04e0ab20faff26,

title = "K 10 M 4 M′ 4 S 17 (M = Mn, Fe, Co, Zn; M′ = Sn, Ge) and Cs 10 Cd 4 Sn 4 S 17: Compounds with a discrete supertetrahedral cluster",

abstract = " The cluster compounds K 10 Zn 4 Sn 4 S 17 , K 10 Mn 4 Sn 4 S 17 , K 10 Fe 4 Sn 4 S 17 , K 10 Co 4 Sn 4 S 17 , Cs 10 Cd 4 Sn 4 S 17 and K 10 Zn 4 Ge 4 S 17 are described. The structures of these compounds, refined by single-crystal X-ray diffraction techniques, contain the discrete cluster [M 4 M′ 4 S 17 ] 10- (M = Zn, Mn, Co, Fe, Cd; M′ = Sn or Ge) which has the structure of Si 8 C 17 H 36 . It is built from the sulfur-connected tetrahedral SnS 4 and MS 4 units with the additional quadruply bridging sulfur atom at the center of the cluster. All compound show some solubility and stability in water and formamide. Cs 10 Cd 4 Sn 4 S 17 and K 10 Zn 4 Ge 4 S 17 show photoluminescence at room temperature.The magnetic properties of K 10 Mn 4 Sn 4 S 17 , K 10 Fe 4 Sn 4 S 17 , K 10 Co 4 Sn 4 S 17 indicate strong antiferromagnetic interactions arising from spin coupling within the cluster but their magnetic susceptibility is characterized with a discrepancy between field-cooled and zero field-cooled measurements. ",

keywords = "Cluster compound, Germanium, Sulfides, Tin",

author = "Oleg Palchik and Iyer, {Ratnasabapathy G.} and Christian Canlas and Weliky, {David P.} and Kanatzidis, {Mercouri G.}",

year = "2004",

month = dec,

day = "1",

doi = "10.1002/zaac.200400154",

language = "English (US)",

volume = "630",

pages = "2237--2247",

journal = "Zeitschrift fur Anorganische und Allgemeine Chemie",

issn = "0044-2313",

publisher = "Wiley",

number = "13-14",

}

Palchik, O, Iyer, RG, Canlas, C, Weliky, DP & Kanatzidis, MG 2004, 'K ₁₀ M ₄ M′ ₄ S ₁₇ (M = Mn, Fe, Co, Zn; M′ = Sn, Ge) and Cs ₁₀ Cd ₄ Sn ₄ S ₁₇: Compounds with a discrete supertetrahedral cluster', Zeitschrift fur Anorganische und Allgemeine Chemie, vol. 630, no. 13-14, pp. 2237-2247. https://doi.org/10.1002/zaac.200400154

K ₁₀ M ₄ M′ ₄ S ₁₇ (M = Mn, Fe, Co, Zn; M′ = Sn, Ge) and Cs ₁₀ Cd ₄ Sn ₄ S ₁₇ : Compounds with a discrete supertetrahedral cluster. / Palchik, Oleg; Iyer, Ratnasabapathy G.; Canlas, Christian et al.

In: Zeitschrift fur Anorganische und Allgemeine Chemie, Vol. 630, No. 13-14, 01.12.2004, p. 2237-2247.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - K 10 M 4 M′ 4 S 17 (M = Mn, Fe, Co, Zn; M′ = Sn, Ge) and Cs 10 Cd 4 Sn 4 S 17

T2 - Compounds with a discrete supertetrahedral cluster

AU - Palchik, Oleg

AU - Iyer, Ratnasabapathy G.

AU - Canlas, Christian

AU - Weliky, David P.

AU - Kanatzidis, Mercouri G.

PY - 2004/12/1

Y1 - 2004/12/1

N2 - The cluster compounds K 10 Zn 4 Sn 4 S 17 , K 10 Mn 4 Sn 4 S 17 , K 10 Fe 4 Sn 4 S 17 , K 10 Co 4 Sn 4 S 17 , Cs 10 Cd 4 Sn 4 S 17 and K 10 Zn 4 Ge 4 S 17 are described. The structures of these compounds, refined by single-crystal X-ray diffraction techniques, contain the discrete cluster [M 4 M′ 4 S 17 ] 10- (M = Zn, Mn, Co, Fe, Cd; M′ = Sn or Ge) which has the structure of Si 8 C 17 H 36 . It is built from the sulfur-connected tetrahedral SnS 4 and MS 4 units with the additional quadruply bridging sulfur atom at the center of the cluster. All compound show some solubility and stability in water and formamide. Cs 10 Cd 4 Sn 4 S 17 and K 10 Zn 4 Ge 4 S 17 show photoluminescence at room temperature.The magnetic properties of K 10 Mn 4 Sn 4 S 17 , K 10 Fe 4 Sn 4 S 17 , K 10 Co 4 Sn 4 S 17 indicate strong antiferromagnetic interactions arising from spin coupling within the cluster but their magnetic susceptibility is characterized with a discrepancy between field-cooled and zero field-cooled measurements.

AB - The cluster compounds K 10 Zn 4 Sn 4 S 17 , K 10 Mn 4 Sn 4 S 17 , K 10 Fe 4 Sn 4 S 17 , K 10 Co 4 Sn 4 S 17 , Cs 10 Cd 4 Sn 4 S 17 and K 10 Zn 4 Ge 4 S 17 are described. The structures of these compounds, refined by single-crystal X-ray diffraction techniques, contain the discrete cluster [M 4 M′ 4 S 17 ] 10- (M = Zn, Mn, Co, Fe, Cd; M′ = Sn or Ge) which has the structure of Si 8 C 17 H 36 . It is built from the sulfur-connected tetrahedral SnS 4 and MS 4 units with the additional quadruply bridging sulfur atom at the center of the cluster. All compound show some solubility and stability in water and formamide. Cs 10 Cd 4 Sn 4 S 17 and K 10 Zn 4 Ge 4 S 17 show photoluminescence at room temperature.The magnetic properties of K 10 Mn 4 Sn 4 S 17 , K 10 Fe 4 Sn 4 S 17 , K 10 Co 4 Sn 4 S 17 indicate strong antiferromagnetic interactions arising from spin coupling within the cluster but their magnetic susceptibility is characterized with a discrepancy between field-cooled and zero field-cooled measurements.

KW - Cluster compound

KW - Germanium

KW - Sulfides

KW - Tin

UR - http://www.scopus.com/inward/record.url?scp=8844239949&partnerID=8YFLogxK

U2 - 10.1002/zaac.200400154

DO - 10.1002/zaac.200400154

M3 - Article

AN - SCOPUS:8844239949

VL - 630

SP - 2237

EP - 2247

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

SN - 0044-2313

IS - 13-14

ER -

Palchik O, Iyer RG, Canlas C, Weliky DP, Kanatzidis MG. K ₁₀ M ₄ M′ ₄ S ₁₇ (M = Mn, Fe, Co, Zn; M′ = Sn, Ge) and Cs ₁₀ Cd ₄ Sn ₄ S ₁₇: Compounds with a discrete supertetrahedral cluster. Zeitschrift fur Anorganische und Allgemeine Chemie. 2004 Dec 1;630(13-14):2237-2247. doi: 10.1002/zaac.200400154