Iodine nanotrap for highly efficient iodine capture under high temperature

Feng Shui; Qiong Lei; Xinglong Dong; Tingting Pan; Zhiyuan Zhang; Jinli Li; Mao Yi; Laiyu Zhang; Xiongli Liu; Zifeng You; Shiqi Yang; Rufeng Yang; Hongbo Zhang; Jixin Li; Zhan Shi; Jun Yin; Baiyan Li; Xian He Bu

doi:10.1016/j.cej.2023.143525

Iodine nanotrap for highly efficient iodine capture under high temperature

Feng Shui, Qiong Lei, Xinglong Dong, Tingting Pan, Zhiyuan Zhang, Jinli Li, Mao Yi, Laiyu Zhang, Xiongli Liu, Zifeng You, Shiqi Yang, Rufeng Yang, Hongbo Zhang, Jixin Li, Zhan Shi, Jun Yin, Baiyan Li, Xian He Bu

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

Covalent organic frameworks have been recognized as promising porous materials for the radioactive iodine capture. However, most COFs often suffer from low adsorption capacity under practical conditions (typically ≥ 150 °C, ≤ 150 ppmv I2) due to the lack of strong binding sites and low affinity toward iodine, which restricts their application in industrial relevant conditions. Here, we develop a strategy of constructing highly efficient I2 nanotraps by manipulating two kinds of adsorption sites (ionic binding sites and Lewis binding sites) located at adjacent spatial positions, thereby realizing the synergistic binding toward I2. The obtained I2 nanotrap 4F-iCOF-TpBpy-I- delivers a remarkable I2 uptake capacity of 37 wt% at 150 °C and 150 ppmv of I2, which illustrate a record-high value for all COFs reported so far. This work opens a new avenue for the rational design of COF materials toward highly efficient I2 capture and related application.

Original language	English (US)
Pages (from-to)	143525
Journal	Chemical Engineering Journal
Volume	468
DOIs	https://doi.org/10.1016/j.cej.2023.143525
State	Published - May 26 2023

Bibliographical note

KAUST Repository Item: Exported on 2023-06-06
Acknowledgements: The authors acknowledge the National Science Foundation of China (NO. 21978138 and 22035003), the Fundamental Research Funds for the Central Universities (Nankai University) and the Haihe Laboratory of Sustainable Chemical Transformations (YYJC202101), the Ph. D. Candidate Research Innovation Fund of NKU School of Materials Science and Engineering for financial support of this work.

ASJC Scopus subject areas

Environmental Chemistry
General Chemical Engineering
General Chemistry
Industrial and Manufacturing Engineering

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10.1016/j.cej.2023.143525

Cite this

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title = "Iodine nanotrap for highly efficient iodine capture under high temperature",

abstract = "Covalent organic frameworks have been recognized as promising porous materials for the radioactive iodine capture. However, most COFs often suffer from low adsorption capacity under practical conditions (typically ≥ 150 °C, ≤ 150 ppmv I2) due to the lack of strong binding sites and low affinity toward iodine, which restricts their application in industrial relevant conditions. Here, we develop a strategy of constructing highly efficient I2 nanotraps by manipulating two kinds of adsorption sites (ionic binding sites and Lewis binding sites) located at adjacent spatial positions, thereby realizing the synergistic binding toward I2. The obtained I2 nanotrap 4F-iCOF-TpBpy-I- delivers a remarkable I2 uptake capacity of 37 wt% at 150 °C and 150 ppmv of I2, which illustrate a record-high value for all COFs reported so far. This work opens a new avenue for the rational design of COF materials toward highly efficient I2 capture and related application.",

author = "Feng Shui and Qiong Lei and Xinglong Dong and Tingting Pan and Zhiyuan Zhang and Jinli Li and Mao Yi and Laiyu Zhang and Xiongli Liu and Zifeng You and Shiqi Yang and Rufeng Yang and Hongbo Zhang and Jixin Li and Zhan Shi and Jun Yin and Baiyan Li and Bu, {Xian He}",

note = "KAUST Repository Item: Exported on 2023-06-06 Acknowledgements: The authors acknowledge the National Science Foundation of China (NO. 21978138 and 22035003), the Fundamental Research Funds for the Central Universities (Nankai University) and the Haihe Laboratory of Sustainable Chemical Transformations (YYJC202101), the Ph. D. Candidate Research Innovation Fund of NKU School of Materials Science and Engineering for financial support of this work.",

year = "2023",

month = may,

day = "26",

doi = "10.1016/j.cej.2023.143525",

language = "English (US)",

volume = "468",

pages = "143525",

journal = "Chemical Engineering Journal",

issn = "1385-8947",

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TY - JOUR

T1 - Iodine nanotrap for highly efficient iodine capture under high temperature

AU - Shui, Feng

AU - Lei, Qiong

AU - Dong, Xinglong

AU - Pan, Tingting

AU - Zhang, Zhiyuan

AU - Li, Jinli

AU - Yi, Mao

AU - Zhang, Laiyu

AU - Liu, Xiongli

AU - You, Zifeng

AU - Yang, Shiqi

AU - Yang, Rufeng

AU - Zhang, Hongbo

AU - Li, Jixin

AU - Shi, Zhan

AU - Yin, Jun

AU - Li, Baiyan

AU - Bu, Xian He

N1 - KAUST Repository Item: Exported on 2023-06-06 Acknowledgements: The authors acknowledge the National Science Foundation of China (NO. 21978138 and 22035003), the Fundamental Research Funds for the Central Universities (Nankai University) and the Haihe Laboratory of Sustainable Chemical Transformations (YYJC202101), the Ph. D. Candidate Research Innovation Fund of NKU School of Materials Science and Engineering for financial support of this work.

PY - 2023/5/26

Y1 - 2023/5/26

N2 - Covalent organic frameworks have been recognized as promising porous materials for the radioactive iodine capture. However, most COFs often suffer from low adsorption capacity under practical conditions (typically ≥ 150 °C, ≤ 150 ppmv I2) due to the lack of strong binding sites and low affinity toward iodine, which restricts their application in industrial relevant conditions. Here, we develop a strategy of constructing highly efficient I2 nanotraps by manipulating two kinds of adsorption sites (ionic binding sites and Lewis binding sites) located at adjacent spatial positions, thereby realizing the synergistic binding toward I2. The obtained I2 nanotrap 4F-iCOF-TpBpy-I- delivers a remarkable I2 uptake capacity of 37 wt% at 150 °C and 150 ppmv of I2, which illustrate a record-high value for all COFs reported so far. This work opens a new avenue for the rational design of COF materials toward highly efficient I2 capture and related application.

AB - Covalent organic frameworks have been recognized as promising porous materials for the radioactive iodine capture. However, most COFs often suffer from low adsorption capacity under practical conditions (typically ≥ 150 °C, ≤ 150 ppmv I2) due to the lack of strong binding sites and low affinity toward iodine, which restricts their application in industrial relevant conditions. Here, we develop a strategy of constructing highly efficient I2 nanotraps by manipulating two kinds of adsorption sites (ionic binding sites and Lewis binding sites) located at adjacent spatial positions, thereby realizing the synergistic binding toward I2. The obtained I2 nanotrap 4F-iCOF-TpBpy-I- delivers a remarkable I2 uptake capacity of 37 wt% at 150 °C and 150 ppmv of I2, which illustrate a record-high value for all COFs reported so far. This work opens a new avenue for the rational design of COF materials toward highly efficient I2 capture and related application.

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UR - https://linkinghub.elsevier.com/retrieve/pii/S1385894723022568

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U2 - 10.1016/j.cej.2023.143525

DO - 10.1016/j.cej.2023.143525

M3 - Article

SN - 1385-8947

VL - 468

SP - 143525

JO - Chemical Engineering Journal

JF - Chemical Engineering Journal

ER -

Iodine nanotrap for highly efficient iodine capture under high temperature

Abstract

Bibliographical note

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