Investigation of the composition space diagram of the ZnF 2-3,5-diamino-1,2,4-triazole-HF-H2O chemical system and structural characterization of a new fluorinated guanazolate MOF [Zn 3F2]·(Am2TAZ)4

Amandine Cadiau; Charlotte Martineau; Francis Taulelle; Karim Adil

doi:10.1016/j.jfluchem.2013.02.016

Investigation of the composition space diagram of the ZnF ₂-3,5-diamino-1,2,4-triazole-HF-H₂O chemical system and structural characterization of a new fluorinated guanazolate MOF [Zn ₃F₂]·(Am₂TAZ)₄

Amandine Cadiau, Charlotte Martineau^*, Francis Taulelle, Karim Adil

^*Corresponding author for this work

Physical Sciences and Engineering

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

The ZnF₂-3,5-diamino-1,2,4-triazole-HF-H₂O system has been explored by hydrothermal syntheses over a large domain of concentrations using micro-wave heating. In the composition space diagram, the crystallization areas of two fluorinated guanazolate MOFs, [Zn₃F₂] ·(Am₂TAZ)₄ (I) and the previously described [ZnF]·(Am₂TAZ) (II), have been defined (with Am₂TAZ = 3,5-diamino-1,2,4-triazolate). Compound (I) (tetragonal, P 4/n n c (#126), a = 11.7055(6), c = 7.3291(4)) was characterized by single-crystal X-ray diffraction, thermogravimetric measurement and ¹H and ¹⁹F solid-state nuclear magnetic resonance (NMR) spectroscopy. Its crystal structure, showing a tfj topology, contains a unusual zinc double coordination. It can be described as infinite chains running along the crystallographic a- and b-directions in which clusters of Zn₂N₄ tetrahedra and ZnN₄F₂ octahedra alternate. The analysis of the ZnF ₂-HAm₂TAZ-HF-H₂O composition space diagram gives possible hints on a relationship between the HF concentration in solution and the zinc coordination environment in the final guanazolate fluorinated MOF obtained.

Original language	English (US)
Pages (from-to)	104-108
Number of pages	5
Journal	Journal of Fluorine Chemistry
Volume	150
DOIs	https://doi.org/10.1016/j.jfluchem.2013.02.016
State	Published - Jun 2013

Keywords

Fluorinated metal-organic framework materials
Hydrothermal synthesis
Microwave
Solid state NMR

ASJC Scopus subject areas

Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Environmental Chemistry
Organic Chemistry

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10.1016/j.jfluchem.2013.02.016

Cite this

@article{7171c0f0eaf7474ca7e50680e3b343a9,

title = "Investigation of the composition space diagram of the ZnF 2-3,5-diamino-1,2,4-triazole-HF-H2O chemical system and structural characterization of a new fluorinated guanazolate MOF [Zn 3F2]·(Am2TAZ)4",

abstract = "The ZnF2-3,5-diamino-1,2,4-triazole-HF-H2O system has been explored by hydrothermal syntheses over a large domain of concentrations using micro-wave heating. In the composition space diagram, the crystallization areas of two fluorinated guanazolate MOFs, [Zn3F2] ·(Am2TAZ)4 (I) and the previously described [ZnF]·(Am2TAZ) (II), have been defined (with Am2TAZ = 3,5-diamino-1,2,4-triazolate). Compound (I) (tetragonal, P 4/n n c (#126), a = 11.7055(6), c = 7.3291(4)) was characterized by single-crystal X-ray diffraction, thermogravimetric measurement and 1H and 19F solid-state nuclear magnetic resonance (NMR) spectroscopy. Its crystal structure, showing a tfj topology, contains a unusual zinc double coordination. It can be described as infinite chains running along the crystallographic a- and b-directions in which clusters of Zn2N4 tetrahedra and ZnN4F2 octahedra alternate. The analysis of the ZnF 2-HAm2TAZ-HF-H2O composition space diagram gives possible hints on a relationship between the HF concentration in solution and the zinc coordination environment in the final guanazolate fluorinated MOF obtained.",

keywords = "Fluorinated metal-organic framework materials, Hydrothermal synthesis, Microwave, Solid state NMR",

author = "Amandine Cadiau and Charlotte Martineau and Francis Taulelle and Karim Adil",

year = "2013",

month = jun,

doi = "10.1016/j.jfluchem.2013.02.016",

language = "English (US)",

volume = "150",

pages = "104--108",

journal = "Journal of Fluorine Chemistry",

issn = "0022-1139",

publisher = "Elsevier",

}

Investigation of the composition space diagram of the ZnF ₂-3,5-diamino-1,2,4-triazole-HF-H₂O chemical system and structural characterization of a new fluorinated guanazolate MOF [Zn ₃F₂]·(Am₂TAZ)₄. / Cadiau, Amandine; Martineau, Charlotte; Taulelle, Francis et al.
In: Journal of Fluorine Chemistry, Vol. 150, 06.2013, p. 104-108.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Investigation of the composition space diagram of the ZnF 2-3,5-diamino-1,2,4-triazole-HF-H2O chemical system and structural characterization of a new fluorinated guanazolate MOF [Zn 3F2]·(Am2TAZ)4

AU - Cadiau, Amandine

AU - Martineau, Charlotte

AU - Taulelle, Francis

AU - Adil, Karim

PY - 2013/6

Y1 - 2013/6

N2 - The ZnF2-3,5-diamino-1,2,4-triazole-HF-H2O system has been explored by hydrothermal syntheses over a large domain of concentrations using micro-wave heating. In the composition space diagram, the crystallization areas of two fluorinated guanazolate MOFs, [Zn3F2] ·(Am2TAZ)4 (I) and the previously described [ZnF]·(Am2TAZ) (II), have been defined (with Am2TAZ = 3,5-diamino-1,2,4-triazolate). Compound (I) (tetragonal, P 4/n n c (#126), a = 11.7055(6), c = 7.3291(4)) was characterized by single-crystal X-ray diffraction, thermogravimetric measurement and 1H and 19F solid-state nuclear magnetic resonance (NMR) spectroscopy. Its crystal structure, showing a tfj topology, contains a unusual zinc double coordination. It can be described as infinite chains running along the crystallographic a- and b-directions in which clusters of Zn2N4 tetrahedra and ZnN4F2 octahedra alternate. The analysis of the ZnF 2-HAm2TAZ-HF-H2O composition space diagram gives possible hints on a relationship between the HF concentration in solution and the zinc coordination environment in the final guanazolate fluorinated MOF obtained.

AB - The ZnF2-3,5-diamino-1,2,4-triazole-HF-H2O system has been explored by hydrothermal syntheses over a large domain of concentrations using micro-wave heating. In the composition space diagram, the crystallization areas of two fluorinated guanazolate MOFs, [Zn3F2] ·(Am2TAZ)4 (I) and the previously described [ZnF]·(Am2TAZ) (II), have been defined (with Am2TAZ = 3,5-diamino-1,2,4-triazolate). Compound (I) (tetragonal, P 4/n n c (#126), a = 11.7055(6), c = 7.3291(4)) was characterized by single-crystal X-ray diffraction, thermogravimetric measurement and 1H and 19F solid-state nuclear magnetic resonance (NMR) spectroscopy. Its crystal structure, showing a tfj topology, contains a unusual zinc double coordination. It can be described as infinite chains running along the crystallographic a- and b-directions in which clusters of Zn2N4 tetrahedra and ZnN4F2 octahedra alternate. The analysis of the ZnF 2-HAm2TAZ-HF-H2O composition space diagram gives possible hints on a relationship between the HF concentration in solution and the zinc coordination environment in the final guanazolate fluorinated MOF obtained.

KW - Fluorinated metal-organic framework materials

KW - Hydrothermal synthesis

KW - Microwave

KW - Solid state NMR

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DO - 10.1016/j.jfluchem.2013.02.016

M3 - Article

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SN - 0022-1139

VL - 150

SP - 104

EP - 108

JO - Journal of Fluorine Chemistry

JF - Journal of Fluorine Chemistry

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