Intergrown new zeolite beta polymorphs with interconnected 12-ring channels solved by combining electron crystallography and single-crystal X-ray diffraction

Zhengbao Yu; Yu Han; Lan Zhao; Shiliang Huang; Qiyu Zheng; Shuangzheng Lin; Armando C. Cõrdova; Xiaodong Zou; Junliang Sun

doi:10.1021/cm301654d

Intergrown new zeolite beta polymorphs with interconnected 12-ring channels solved by combining electron crystallography and single-crystal X-ray diffraction

Zhengbao Yu, Yu Han, Lan Zhao, Shiliang Huang, Qiyu Zheng, Shuangzheng Lin, Armando C. Cõrdova, Xiaodong Zou, Junliang Sun

Research output: Contribution to journal › Article › peer-review

45 Scopus citations

Abstract

Two new polymorphs of zeolite beta, denoted as SU-78A and SU-78B, were synthesized by employing dicyclohexylammonium hydroxides as organic structure-directing agents. The structure was solved by combining transmission electron microscopy and single-crystal X-ray diffraction. SU-78 is an intergrowth of SU-78A and SU-78B and contains interconnected 12-ring channels in three directions. The two polymorphs are built from the same building layer, similar to that for the zeolite beta family. The layer stacking in SU-78, however, is different from those in zeolite beta polymorph A, B, and C, showing new zeolite framework topologies. SU-78 is thermally stable up to 600 °C. © 2012 American Chemical Society.

Original language	English (US)
Pages (from-to)	3701-3706
Number of pages	6
Journal	Chemistry of Materials
Volume	24
Issue number	19
DOIs	https://doi.org/10.1021/cm301654d
State	Published - Sep 27 2012

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: This work is supported financially by the Swedish Research Council (VR) and the Swedish Governmental Agency for Innovation Systems (VINNOVA) through the Berzelii Center EXSELENT, the Major State Basic Research Development Program of China (No. 2011CB932501), the National Natural Science Foundation of China (No. 20932004).

ASJC Scopus subject areas

Materials Chemistry
General Chemical Engineering
General Chemistry

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10.1021/cm301654d

Cite this

@article{e88b490cfc3a4cadac4177399e0dde4c,

title = "Intergrown new zeolite beta polymorphs with interconnected 12-ring channels solved by combining electron crystallography and single-crystal X-ray diffraction",

abstract = "Two new polymorphs of zeolite beta, denoted as SU-78A and SU-78B, were synthesized by employing dicyclohexylammonium hydroxides as organic structure-directing agents. The structure was solved by combining transmission electron microscopy and single-crystal X-ray diffraction. SU-78 is an intergrowth of SU-78A and SU-78B and contains interconnected 12-ring channels in three directions. The two polymorphs are built from the same building layer, similar to that for the zeolite beta family. The layer stacking in SU-78, however, is different from those in zeolite beta polymorph A, B, and C, showing new zeolite framework topologies. SU-78 is thermally stable up to 600 °C. {\textcopyright} 2012 American Chemical Society.",

author = "Zhengbao Yu and Yu Han and Lan Zhao and Shiliang Huang and Qiyu Zheng and Shuangzheng Lin and C{\~o}rdova, {Armando C.} and Xiaodong Zou and Junliang Sun",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: This work is supported financially by the Swedish Research Council (VR) and the Swedish Governmental Agency for Innovation Systems (VINNOVA) through the Berzelii Center EXSELENT, the Major State Basic Research Development Program of China (No. 2011CB932501), the National Natural Science Foundation of China (No. 20932004).",

year = "2012",

month = sep,

day = "27",

doi = "10.1021/cm301654d",

language = "English (US)",

volume = "24",

pages = "3701--3706",

journal = "Chemistry of Materials",

issn = "0897-4756",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Intergrown new zeolite beta polymorphs with interconnected 12-ring channels solved by combining electron crystallography and single-crystal X-ray diffraction

AU - Yu, Zhengbao

AU - Han, Yu

AU - Zhao, Lan

AU - Huang, Shiliang

AU - Zheng, Qiyu

AU - Lin, Shuangzheng

AU - Cõrdova, Armando C.

AU - Zou, Xiaodong

AU - Sun, Junliang

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: This work is supported financially by the Swedish Research Council (VR) and the Swedish Governmental Agency for Innovation Systems (VINNOVA) through the Berzelii Center EXSELENT, the Major State Basic Research Development Program of China (No. 2011CB932501), the National Natural Science Foundation of China (No. 20932004).

PY - 2012/9/27

Y1 - 2012/9/27

N2 - Two new polymorphs of zeolite beta, denoted as SU-78A and SU-78B, were synthesized by employing dicyclohexylammonium hydroxides as organic structure-directing agents. The structure was solved by combining transmission electron microscopy and single-crystal X-ray diffraction. SU-78 is an intergrowth of SU-78A and SU-78B and contains interconnected 12-ring channels in three directions. The two polymorphs are built from the same building layer, similar to that for the zeolite beta family. The layer stacking in SU-78, however, is different from those in zeolite beta polymorph A, B, and C, showing new zeolite framework topologies. SU-78 is thermally stable up to 600 °C. © 2012 American Chemical Society.

AB - Two new polymorphs of zeolite beta, denoted as SU-78A and SU-78B, were synthesized by employing dicyclohexylammonium hydroxides as organic structure-directing agents. The structure was solved by combining transmission electron microscopy and single-crystal X-ray diffraction. SU-78 is an intergrowth of SU-78A and SU-78B and contains interconnected 12-ring channels in three directions. The two polymorphs are built from the same building layer, similar to that for the zeolite beta family. The layer stacking in SU-78, however, is different from those in zeolite beta polymorph A, B, and C, showing new zeolite framework topologies. SU-78 is thermally stable up to 600 °C. © 2012 American Chemical Society.

UR - http://hdl.handle.net/10754/562360

UR - https://pubs.acs.org/doi/10.1021/cm301654d

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U2 - 10.1021/cm301654d

DO - 10.1021/cm301654d

M3 - Article

SN - 0897-4756

VL - 24

SP - 3701

EP - 3706

JO - Chemistry of Materials

JF - Chemistry of Materials

IS - 19

ER -

Intergrown new zeolite beta polymorphs with interconnected 12-ring channels solved by combining electron crystallography and single-crystal X-ray diffraction

Abstract

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CCDC 939502: Experimental Crystal Structure Determination : catena-[hexadecakis(N,N-Dicyclohexyl-N-ethyl-N-methylammonium) icosahectakis(mu2-oxo)-hexapentaconta(germanium-silicon)]

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Intergrown new zeolite beta polymorphs with interconnected 12-ring channels solved by combining electron crystallography and single-crystal X-ray diffraction

Abstract

Bibliographical note

ASJC Scopus subject areas

Access to Document

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CCDC 939502: Experimental Crystal Structure Determination : catena-[hexadecakis(N,N-Dicyclohexyl-N-ethyl-N-methylammonium) icosahectakis(mu2-oxo)-hexapentaconta(germanium-silicon)]

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