Abstract
In order to explore the potential of novel open metal organic frameworks (MOFs) with soc topology for gas storage applications, we performed a systematic physical adsorption study with Hydrogen, Methane and Carbon dioxide as adsorptives over a wide range of temperatures (77-323 K) and pressures (0-5 MPa) by using a volumetric low pressure adsorption analyzer equipped with a cryostat, and a high pressure gravimetric system. The advanced interpretation of our systematic adsorption data in combination with the results from a comprehensive structural and surface characterization allows one assessing the potential of these novel MOFs for gas storage and separation applications.
Original language | English (US) |
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Pages (from-to) | 345-353 |
Number of pages | 9 |
Journal | Microporous and Mesoporous Materials |
Volume | 129 |
Issue number | 3 |
DOIs | |
State | Published - Apr 15 2010 |
Keywords
- Adsorption
- Characterization
- Gas separation
- High pressure
- MOF
ASJC Scopus subject areas
- General Chemistry
- General Materials Science
- Condensed Matter Physics
- Mechanics of Materials