Insertion reactions of organic anhydrides into the Cu-O bond of [CuO tBu]: Syntheses and structures of functionalised copper (I) and copper (II) carboxylates

Lukasz Ponikiewski; Alexander Rothenberger

doi:10.1016/j.ica.2004.10.019

Insertion reactions of organic anhydrides into the Cu-O bond of [CuO ^tBu]: Syntheses and structures of functionalised copper (I) and copper (II) carboxylates

Lukasz Ponikiewski, Alexander Rothenberger^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

The insertion reaction of maleic anhydride into the Cu-O bond in [CuO ^tBu] produced the complexes [Cu₂(CO₂C ₂H₂CO₂^tBu)₄ • dme] (1), [Cu(CO₂C₂H₂CO₂ ^tBu)₂ • tmeda] (2) and [Cu₂(CO ₂C₂H₂CO₂^tBu)₂ • dppm]₂ (3) (dme = 1,2-dimethoxyethane; tmeda = N ¹,N¹,N²,N²-tetramethylethane-1,2- diamine; dppm = bis(diphenylphosphino)methane). This reaction represents a useful synthetic strategy for a range of functionalised Cu(I) and Cu(II) carboxylates.

Original language	English (US)
Pages (from-to)	1322-1326
Number of pages	5
Journal	Inorganica Chimica Acta
Volume	358
Issue number	4
DOIs	https://doi.org/10.1016/j.ica.2004.10.019
State	Published - Mar 1 2005
Externally published	Yes

Keywords

Copper (I)alkoxide
Copper carboxylates
Crystal structures
Insertion reactions
Organic anhydride

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/j.ica.2004.10.019

Cite this

@article{4d3e9e110e4046a9b72e471e47bbde00,

title = "Insertion reactions of organic anhydrides into the Cu-O bond of [CuO tBu]: Syntheses and structures of functionalised copper (I) and copper (II) carboxylates",

abstract = "The insertion reaction of maleic anhydride into the Cu-O bond in [CuO tBu] produced the complexes [Cu2(CO2C 2H2CO2tBu)4 • dme] (1), [Cu(CO2C2H2CO2 tBu)2 • tmeda] (2) and [Cu2(CO 2C2H2CO2tBu)2 • dppm]2 (3) (dme = 1,2-dimethoxyethane; tmeda = N 1,N1,N2,N2-tetramethylethane-1,2- diamine; dppm = bis(diphenylphosphino)methane). This reaction represents a useful synthetic strategy for a range of functionalised Cu(I) and Cu(II) carboxylates.",

keywords = "Copper (I)alkoxide, Copper carboxylates, Crystal structures, Insertion reactions, Organic anhydride",

author = "Lukasz Ponikiewski and Alexander Rothenberger",

year = "2005",

month = mar,

day = "1",

doi = "10.1016/j.ica.2004.10.019",

language = "English (US)",

volume = "358",

pages = "1322--1326",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier",

number = "4",

}

TY - JOUR

T1 - Insertion reactions of organic anhydrides into the Cu-O bond of [CuO tBu]

T2 - Syntheses and structures of functionalised copper (I) and copper (II) carboxylates

AU - Ponikiewski, Lukasz

AU - Rothenberger, Alexander

PY - 2005/3/1

Y1 - 2005/3/1

N2 - The insertion reaction of maleic anhydride into the Cu-O bond in [CuO tBu] produced the complexes [Cu2(CO2C 2H2CO2tBu)4 • dme] (1), [Cu(CO2C2H2CO2 tBu)2 • tmeda] (2) and [Cu2(CO 2C2H2CO2tBu)2 • dppm]2 (3) (dme = 1,2-dimethoxyethane; tmeda = N 1,N1,N2,N2-tetramethylethane-1,2- diamine; dppm = bis(diphenylphosphino)methane). This reaction represents a useful synthetic strategy for a range of functionalised Cu(I) and Cu(II) carboxylates.

AB - The insertion reaction of maleic anhydride into the Cu-O bond in [CuO tBu] produced the complexes [Cu2(CO2C 2H2CO2tBu)4 • dme] (1), [Cu(CO2C2H2CO2 tBu)2 • tmeda] (2) and [Cu2(CO 2C2H2CO2tBu)2 • dppm]2 (3) (dme = 1,2-dimethoxyethane; tmeda = N 1,N1,N2,N2-tetramethylethane-1,2- diamine; dppm = bis(diphenylphosphino)methane). This reaction represents a useful synthetic strategy for a range of functionalised Cu(I) and Cu(II) carboxylates.

KW - Copper (I)alkoxide

KW - Copper carboxylates

KW - Crystal structures

KW - Insertion reactions

KW - Organic anhydride

UR - http://www.scopus.com/inward/record.url?scp=13844313394&partnerID=8YFLogxK

U2 - 10.1016/j.ica.2004.10.019

DO - 10.1016/j.ica.2004.10.019

M3 - Article

AN - SCOPUS:13844313394

SN - 0020-1693

VL - 358

SP - 1322

EP - 1326

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 4

ER -