Insertion of a N-heterocyclic carbene (NHC) into a platinum - Olefin bond

Serena Fantasia; Heiko Jacobsen; Luigi Cavallo; Steven P. Nolan

doi:10.1021/om700447u

Insertion of a N-heterocyclic carbene (NHC) into a platinum - Olefin bond

Serena Fantasia, Heiko Jacobsen, Luigi Cavallo, Steven P. Nolan^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

45 Scopus citations

Abstract

The insertion of a N-heterocyclic carbene (NHC) into a coordinated olefin moiety is observed for a Pt-based system. Important intermediates along the reaction pathway have been isolated and fully characterized. Computational work supports a proposed mechanistic pathway involving external attack at the olefin by a NHC ligand rather than an intramolecular migratory insertion route.

Original language	English (US)
Pages (from-to)	3286-3288
Number of pages	3
Journal	Organometallics
Volume	26
Issue number	14
DOIs	https://doi.org/10.1021/om700447u
State	Published - Jul 2 2007
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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@article{0a7da95ce8384afdb9991e54f0adbc9b,

title = "Insertion of a N-heterocyclic carbene (NHC) into a platinum - Olefin bond",

abstract = "The insertion of a N-heterocyclic carbene (NHC) into a coordinated olefin moiety is observed for a Pt-based system. Important intermediates along the reaction pathway have been isolated and fully characterized. Computational work supports a proposed mechanistic pathway involving external attack at the olefin by a NHC ligand rather than an intramolecular migratory insertion route.",

author = "Serena Fantasia and Heiko Jacobsen and Luigi Cavallo and Nolan, {Steven P.}",

year = "2007",

month = jul,

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doi = "10.1021/om700447u",

language = "English (US)",

volume = "26",

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journal = "Organometallics",

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publisher = "American Chemical Society",

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T1 - Insertion of a N-heterocyclic carbene (NHC) into a platinum - Olefin bond

AU - Fantasia, Serena

AU - Jacobsen, Heiko

AU - Cavallo, Luigi

AU - Nolan, Steven P.

PY - 2007/7/2

Y1 - 2007/7/2

N2 - The insertion of a N-heterocyclic carbene (NHC) into a coordinated olefin moiety is observed for a Pt-based system. Important intermediates along the reaction pathway have been isolated and fully characterized. Computational work supports a proposed mechanistic pathway involving external attack at the olefin by a NHC ligand rather than an intramolecular migratory insertion route.

AB - The insertion of a N-heterocyclic carbene (NHC) into a coordinated olefin moiety is observed for a Pt-based system. Important intermediates along the reaction pathway have been isolated and fully characterized. Computational work supports a proposed mechanistic pathway involving external attack at the olefin by a NHC ligand rather than an intramolecular migratory insertion route.

UR - http://www.scopus.com/inward/record.url?scp=34547380848&partnerID=8YFLogxK

U2 - 10.1021/om700447u

DO - 10.1021/om700447u

M3 - Article

AN - SCOPUS:34547380848

SN - 0276-7333

VL - 26

SP - 3286

EP - 3288

JO - Organometallics

JF - Organometallics

IS - 14

ER -

Insertion of a N-heterocyclic carbene (NHC) into a platinum - Olefin bond

Abstract

ASJC Scopus subject areas

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