Influence of synthetic conditions on the formation of thermally and hydrolytically stable Sc-based metal–organic frameworks

Marina O. Barsukova; Denis G. Samsonenko; Aleksandr A. Sapianik; Sergey A. Sapchenko; Vladimir P. Fedin

doi:10.1016/j.poly.2018.01.031

Influence of synthetic conditions on the formation of thermally and hydrolytically stable Sc-based metal–organic frameworks

Marina O. Barsukova^*, Denis G. Samsonenko, Aleksandr A. Sapianik, Sergey A. Sapchenko, Vladimir P. Fedin

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

Three new coordination polymers ((CH₃)₂NH₂)[Sc(H₂O)₂(fdc)₂]·1,5CH₃CN (1), ((CH₃)₂NH₂)₂[Sc(fdc)₂(HCOO)] (2), [Sc₂(H₂O)₂(fdc)₃] (3) based on scandium cations and 2,5-furandicarboxylate ligand (fdc²⁻) have been synthesized and characterized by single crystal and powder X-ray diffraction crystallography, TG, elemental analyses and IR-spectroscopy. Compound 1 is formed from layers bind by hydrogen bonds. Calculated accessible for solvent volume is 41%. Compound 2 is a structure of negatively charged layers connected with interlayer dimethylammonium cations. Layered compound 3 appeared to be thermally stable (up to 300 °C) and retain its structure in wide range of pH from 1 to 13. Additionally, the solid-state luminescence properties of compounds 2 and 3 we investigated.

Original language	English (US)
Pages (from-to)	219-224
Number of pages	6
Journal	Polyhedron
Volume	144
DOIs	https://doi.org/10.1016/j.poly.2018.01.031
State	Published - Apr 1 2018

Bibliographical note

Funding Information:
The reported study was funded by RFBR and Government of the Novosibirsk region according to the research project № 17-43-543116.

Publisher Copyright:
© 2018 Elsevier Ltd

Keywords

2,5-furandicarboxylic acid
Coordination polymers
Luminescence
Metal–organic framework
Scandium complexes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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title = "Influence of synthetic conditions on the formation of thermally and hydrolytically stable Sc-based metal–organic frameworks",

abstract = "Three new coordination polymers ((CH3)2NH2)[Sc(H2O)2(fdc)2]·1,5CH3CN (1), ((CH3)2NH2)2[Sc(fdc)2(HCOO)] (2), [Sc2(H2O)2(fdc)3] (3) based on scandium cations and 2,5-furandicarboxylate ligand (fdc2−) have been synthesized and characterized by single crystal and powder X-ray diffraction crystallography, TG, elemental analyses and IR-spectroscopy. Compound 1 is formed from layers bind by hydrogen bonds. Calculated accessible for solvent volume is 41%. Compound 2 is a structure of negatively charged layers connected with interlayer dimethylammonium cations. Layered compound 3 appeared to be thermally stable (up to 300 °C) and retain its structure in wide range of pH from 1 to 13. Additionally, the solid-state luminescence properties of compounds 2 and 3 we investigated.",

keywords = "2,5-furandicarboxylic acid, Coordination polymers, Luminescence, Metal–organic framework, Scandium complexes",

author = "Barsukova, {Marina O.} and Samsonenko, {Denis G.} and Sapianik, {Aleksandr A.} and Sapchenko, {Sergey A.} and Fedin, {Vladimir P.}",

note = "Funding Information: The reported study was funded by RFBR and Government of the Novosibirsk region according to the research project № 17-43-543116. Publisher Copyright: {\textcopyright} 2018 Elsevier Ltd",

year = "2018",

month = apr,

day = "1",

doi = "10.1016/j.poly.2018.01.031",

language = "English (US)",

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T1 - Influence of synthetic conditions on the formation of thermally and hydrolytically stable Sc-based metal–organic frameworks

AU - Barsukova, Marina O.

AU - Samsonenko, Denis G.

AU - Sapianik, Aleksandr A.

AU - Sapchenko, Sergey A.

AU - Fedin, Vladimir P.

PY - 2018/4/1

Y1 - 2018/4/1

N2 - Three new coordination polymers ((CH3)2NH2)[Sc(H2O)2(fdc)2]·1,5CH3CN (1), ((CH3)2NH2)2[Sc(fdc)2(HCOO)] (2), [Sc2(H2O)2(fdc)3] (3) based on scandium cations and 2,5-furandicarboxylate ligand (fdc2−) have been synthesized and characterized by single crystal and powder X-ray diffraction crystallography, TG, elemental analyses and IR-spectroscopy. Compound 1 is formed from layers bind by hydrogen bonds. Calculated accessible for solvent volume is 41%. Compound 2 is a structure of negatively charged layers connected with interlayer dimethylammonium cations. Layered compound 3 appeared to be thermally stable (up to 300 °C) and retain its structure in wide range of pH from 1 to 13. Additionally, the solid-state luminescence properties of compounds 2 and 3 we investigated.

AB - Three new coordination polymers ((CH3)2NH2)[Sc(H2O)2(fdc)2]·1,5CH3CN (1), ((CH3)2NH2)2[Sc(fdc)2(HCOO)] (2), [Sc2(H2O)2(fdc)3] (3) based on scandium cations and 2,5-furandicarboxylate ligand (fdc2−) have been synthesized and characterized by single crystal and powder X-ray diffraction crystallography, TG, elemental analyses and IR-spectroscopy. Compound 1 is formed from layers bind by hydrogen bonds. Calculated accessible for solvent volume is 41%. Compound 2 is a structure of negatively charged layers connected with interlayer dimethylammonium cations. Layered compound 3 appeared to be thermally stable (up to 300 °C) and retain its structure in wide range of pH from 1 to 13. Additionally, the solid-state luminescence properties of compounds 2 and 3 we investigated.

KW - 2,5-furandicarboxylic acid

KW - Coordination polymers

KW - Luminescence

KW - Metal–organic framework

KW - Scandium complexes

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DO - 10.1016/j.poly.2018.01.031

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SN - 0277-5387

VL - 144

SP - 219

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JO - Polyhedron

JF - Polyhedron

ER -

Influence of synthetic conditions on the formation of thermally and hydrolytically stable Sc-based metal–organic frameworks

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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