TY - JOUR
T1 - Influence of Filler Pore Structure and Polymer on the Performance of MOF-Based Mixed-Matrix Membranes for CO2
Capture
AU - Sabetghadam, Anahid
AU - Liu, Xinlei
AU - Benzaqui, Marvin
AU - Gkaniatsou, Effrosyni
AU - Orsi, Angelica
AU - Lozinska, Magdalena M.
AU - Sicard, Clemence
AU - Johnson, Timothy
AU - Steunou, Nathalie
AU - Wright, Paul A.
AU - Serre, Christian
AU - Gascon, Jorge
AU - Kapteijn, Freek
N1 - KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: Financial support of the European Research Council under theEuropean Union’s Seventh Framework Programme (FP/2007-2013), M4CO2 project (608490) is gratefully acknowledged.
PY - 2018/5/14
Y1 - 2018/5/14
N2 - To gain insight into the influence of metal-organic framework (MOF) fillers and polymers on membrane performance, eight different composites were studied by combining four MOFs and two polymers. MOF materials (NH-MIL-53(Al), MIL-69(Al), MIL-96(Al) and ZIF-94) with various chemical functionalities, topologies, and dimensionalities of porosity were employed as fillers, and two typical polymers with different permeability-selectivity properties (6FDA-DAM and Pebax) were selected as matrices. The best-performing MOF-polymer composites were prepared by loading 25wt% of MIL-96(Al) as filler, which improved the permeability and selectivity of 6FDA-DAM to 32 and 10%, while for Pebax they were enhanced to 25 and 18%, respectively. The observed differences in membrane performance in the separation of CO from N are explained on the basis of gas solubility, diffusivity properties, and compatibility between the filler and polymer phases.
AB - To gain insight into the influence of metal-organic framework (MOF) fillers and polymers on membrane performance, eight different composites were studied by combining four MOFs and two polymers. MOF materials (NH-MIL-53(Al), MIL-69(Al), MIL-96(Al) and ZIF-94) with various chemical functionalities, topologies, and dimensionalities of porosity were employed as fillers, and two typical polymers with different permeability-selectivity properties (6FDA-DAM and Pebax) were selected as matrices. The best-performing MOF-polymer composites were prepared by loading 25wt% of MIL-96(Al) as filler, which improved the permeability and selectivity of 6FDA-DAM to 32 and 10%, while for Pebax they were enhanced to 25 and 18%, respectively. The observed differences in membrane performance in the separation of CO from N are explained on the basis of gas solubility, diffusivity properties, and compatibility between the filler and polymer phases.
UR - http://hdl.handle.net/10754/628017
UR - https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.201800253
UR - http://www.scopus.com/inward/record.url?scp=85047390474&partnerID=8YFLogxK
U2 - 10.1002/chem.201800253
DO - 10.1002/chem.201800253
M3 - Article
SN - 0947-6539
VL - 24
SP - 7949
EP - 7956
JO - Chemistry - A European Journal
JF - Chemistry - A European Journal
IS - 31
ER -