Infinite secondary building units and forbidden catenation in metal-organic frameworks

Nathaniel L. Rosi; Mohamed Eddaoudi; Jaheon Kim; Michael O'Keeffe; Omar M. Yaghi

doi:10.1002/1521-3773(20020118)41:2<284::AID-ANIE284>3.0.CO;2-M

Infinite secondary building units and forbidden catenation in metal-organic frameworks

Nathaniel L. Rosi, Mohamed Eddaoudi, Jaheon Kim, Michael O'Keeffe, Omar M. Yaghi^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

322 Scopus citations

Abstract

Interlinked Zn-O-C infinite secondary building units (SBUs) form the basis of the novel metalorganic frameworks (MOFs) [Zn₃(OH₂)(X)₂] · 4 DEF · 2H₂O (MOF-69A: X=4,4′-biphenyldicarboxylate; MOF-69B: X=2,6-naphthalenedicarboxylate; DEF = N,N′-diethylformamide). The nature of the infinite SBUs results in frameworks (structure of MOF-69A depicted) wherein catenation is forbidden.

Original language	English (US)
Pages (from-to)	284-287
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	41
Issue number	2
DOIs	https://doi.org/10.1002/1521-3773(20020118)41:2<284::AID-ANIE284>3.0.CO;2-M
State	Published - Jan 18 2002
Externally published	Yes

Keywords

Carboxylate ligands
Copolymerization
Interpenetration
Secondary building units
Zeolite analogues
Zinc

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/1521-3773(20020118)41:2<284::AID-ANIE284>3.0.CO;2-M

Cite this

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title = "Infinite secondary building units and forbidden catenation in metal-organic frameworks",

abstract = "Interlinked Zn-O-C infinite secondary building units (SBUs) form the basis of the novel metalorganic frameworks (MOFs) [Zn3(OH2)(X)2] · 4 DEF · 2H2O (MOF-69A: X=4,4′-biphenyldicarboxylate; MOF-69B: X=2,6-naphthalenedicarboxylate; DEF = N,N′-diethylformamide). The nature of the infinite SBUs results in frameworks (structure of MOF-69A depicted) wherein catenation is forbidden.",

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AU - Rosi, Nathaniel L.

AU - Eddaoudi, Mohamed

AU - Kim, Jaheon

AU - O'Keeffe, Michael

AU - Yaghi, Omar M.

PY - 2002/1/18

Y1 - 2002/1/18

N2 - Interlinked Zn-O-C infinite secondary building units (SBUs) form the basis of the novel metalorganic frameworks (MOFs) [Zn3(OH2)(X)2] · 4 DEF · 2H2O (MOF-69A: X=4,4′-biphenyldicarboxylate; MOF-69B: X=2,6-naphthalenedicarboxylate; DEF = N,N′-diethylformamide). The nature of the infinite SBUs results in frameworks (structure of MOF-69A depicted) wherein catenation is forbidden.

AB - Interlinked Zn-O-C infinite secondary building units (SBUs) form the basis of the novel metalorganic frameworks (MOFs) [Zn3(OH2)(X)2] · 4 DEF · 2H2O (MOF-69A: X=4,4′-biphenyldicarboxylate; MOF-69B: X=2,6-naphthalenedicarboxylate; DEF = N,N′-diethylformamide). The nature of the infinite SBUs results in frameworks (structure of MOF-69A depicted) wherein catenation is forbidden.

KW - Carboxylate ligands

KW - Copolymerization

KW - Interpenetration

KW - Secondary building units

KW - Zeolite analogues

KW - Zinc

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Infinite secondary building units and forbidden catenation in metal-organic frameworks

Abstract

Keywords

ASJC Scopus subject areas

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