Industrial Separation Challenges: How Does Supramolecular Chemistry Help?

Gengwu Zhang, Weibin Lin, Feihe Huang*, Jonathan Sessler*, Niveen M. Khashab*

*Corresponding author for this work

Research output: Contribution to journalReview articlepeer-review

2 Scopus citations

Abstract

The chemical industry and the chemical processes underscoring it are under intense scrutiny as the demands for the transition to more sustainable and environmentally friendly practices are increasing. Traditional industrial separation systems, such as thermally driven distillation for hydrocarbon purification, are energy intensive. The development of more energy efficient separation technologies is thus emerging as a critical need, as is the creation of new materials that may permit a transition away from classic distillation-based separations. In this Perspective, we focus on porous organic cages and macrocycles that can adsorb guest molecules selectively through various host-guest interactions and permit molecular sieving behavior at the molecular level. Specifically, we summarize the recent advances where receptor-based adsorbent materials have been shown to be effective for industrially relevant hydrocarbon separations, highlighting the underlying host-guest interactions that impart selectivity and permit the observed separations. This approach to sustainable separations is currently in its infancy. Nevertheless, several receptor-based adsorbent materials with extrinsic/intrinsic voids or special functional groups have been reported in recent years that can selectively capture various targeted guest molecules. We believe that the understanding of the interactions that drive selectivity at a molecular level accruing from these initial systems will permit an ever-more-effective “bottom-up” design of tailored molecular sieves that, in due course, will allow adsorbent material-based approaches to separations to transition from the laboratory into an industrial setting.

Original languageEnglish (US)
Pages (from-to)19143-19163
Number of pages21
JournalJournal of the American Chemical Society
Volume145
Issue number35
DOIs
StateAccepted/In press - 2023

Bibliographical note

Funding Information:
This work was supported by the King Abdullah University of Science and Technology Office of Sponsored Research (OSR-2019-CRG8-4032) to N.M.K., J.L.S, and F.H. J.L.S. also acknowledges the Robert A. Foundation for chair support (F-0018). F.H. further thanks the National Key Research and Development Program of China (2021YFA0910100), the National Natural Science Foundation of China (22035006), the Zhejiang Provincial Natural Science Foundation of China (LD21B020001), the Starry Night Science Fund of Zhejiang University Shanghai Institute for Advanced Study (SN-ZJU-SIAS-006), and a Leading Innovation Team grant from the Department of Science and Technology of Zhejiang Province (2022R01005) for financial support.

Publisher Copyright:
© 2023 American Chemical Society

ASJC Scopus subject areas

  • Catalysis
  • General Chemistry
  • Biochemistry
  • Colloid and Surface Chemistry

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