Abstract
Employing in situ-formed new organic ligands, two Pb(ii)-based metal-organic frameworks were synthesized. Compound 1 possesses a 3D framework while compound 2 has a layered structure. Solid state UV-visible absorptions indicate that the two compounds are semiconductors with band gaps of 1.70 and 1.78 eV. Magnetic properties reveal that they are temperature-independent diamagnetic.
Original language | English (US) |
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Pages (from-to) | 75-78 |
Number of pages | 4 |
Journal | CRYSTENGCOMM |
Volume | 14 |
Issue number | 1 |
DOIs | |
State | Published - Jan 7 2012 |
Externally published | Yes |
ASJC Scopus subject areas
- General Chemistry
- General Materials Science
- Condensed Matter Physics