In situ formation of new organic ligands to construct two novel self-charge-transfer Pb(ii)-based frameworks

Yi Liu; Melvin Jun Wei Tan; Fengxia Wei; Yufeng Tian; Tom Wu; Christian Kloc; Fengwei Huo; Qingyu Yan; Huey Hoon Hng; Jan Ma; Qichun Zhang

doi:10.1039/c1ce06006f

In situ formation of new organic ligands to construct two novel self-charge-transfer Pb(ii)-based frameworks

Yi Liu, Melvin Jun Wei Tan, Fengxia Wei, Yufeng Tian, Tom Wu, Christian Kloc, Fengwei Huo, Qingyu Yan, Huey Hoon Hng, Jan Ma, Qichun Zhang^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

Employing in situ-formed new organic ligands, two Pb(ii)-based metal-organic frameworks were synthesized. Compound 1 possesses a 3D framework while compound 2 has a layered structure. Solid state UV-visible absorptions indicate that the two compounds are semiconductors with band gaps of 1.70 and 1.78 eV. Magnetic properties reveal that they are temperature-independent diamagnetic.

Original language	English (US)
Pages (from-to)	75-78
Number of pages	4
Journal	CRYSTENGCOMM
Volume	14
Issue number	1
DOIs	https://doi.org/10.1039/c1ce06006f
State	Published - Jan 7 2012
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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abstract = "Employing in situ-formed new organic ligands, two Pb(ii)-based metal-organic frameworks were synthesized. Compound 1 possesses a 3D framework while compound 2 has a layered structure. Solid state UV-visible absorptions indicate that the two compounds are semiconductors with band gaps of 1.70 and 1.78 eV. Magnetic properties reveal that they are temperature-independent diamagnetic.",

author = "Yi Liu and {Wei Tan}, {Melvin Jun} and Fengxia Wei and Yufeng Tian and Tom Wu and Christian Kloc and Fengwei Huo and Qingyu Yan and Hng, {Huey Hoon} and Jan Ma and Qichun Zhang",

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AU - Liu, Yi

AU - Wei Tan, Melvin Jun

AU - Wei, Fengxia

AU - Tian, Yufeng

AU - Wu, Tom

AU - Kloc, Christian

AU - Huo, Fengwei

AU - Yan, Qingyu

AU - Hng, Huey Hoon

AU - Ma, Jan

AU - Zhang, Qichun

PY - 2012/1/7

Y1 - 2012/1/7

N2 - Employing in situ-formed new organic ligands, two Pb(ii)-based metal-organic frameworks were synthesized. Compound 1 possesses a 3D framework while compound 2 has a layered structure. Solid state UV-visible absorptions indicate that the two compounds are semiconductors with band gaps of 1.70 and 1.78 eV. Magnetic properties reveal that they are temperature-independent diamagnetic.

AB - Employing in situ-formed new organic ligands, two Pb(ii)-based metal-organic frameworks were synthesized. Compound 1 possesses a 3D framework while compound 2 has a layered structure. Solid state UV-visible absorptions indicate that the two compounds are semiconductors with band gaps of 1.70 and 1.78 eV. Magnetic properties reveal that they are temperature-independent diamagnetic.

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U2 - 10.1039/c1ce06006f

DO - 10.1039/c1ce06006f

M3 - Article

AN - SCOPUS:82955190553

SN - 1466-8033

VL - 14

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JO - CRYSTENGCOMM

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IS - 1

ER -

In situ formation of new organic ligands to construct two novel self-charge-transfer Pb(ii)-based frameworks

Abstract

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