In situ fabrication of a supported Ba3Ca1.18Nb 1.82O9-δ membrane electrolyte for a proton-conducting SOFC

Lei Bi; Shangquan Zhang; Shumin Fang; Lei Zhang; Haiying Gao; Guangyao Meng; Wei Liu

doi:10.1111/j.1551-2916.2008.02733.x

In situ fabrication of a supported Ba₃Ca_1.18Nb _1.82O_9-δ membrane electrolyte for a proton-conducting SOFC

Lei Bi, Shangquan Zhang, Shumin Fang, Lei Zhang, Haiying Gao, Guangyao Meng, Wei Liu^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

28 Scopus citations

Abstract

A thin Ba₃Ca_1.18Nb_1.82O _9-δ (BCN18) membrane electrolyte was prepared by a novel and facile method on a NiO-BCN18 anode substrate. The interesting aspect of the method was the adoption of a in situ reaction of BaCO₃, CaCO ₃, and Nb₂O₅ on the anode substrate to prepare a dense BCN18 membrane. The BCN18 membrane obtained, which was about 15 μm in thickness and showed high chemical stability against H₂O and CO ₂, attained a high density after sintering at 1400°C. The elemental composition of the BCN18 membrane prepared was identified by energy-dispersive X-ray spectroscopy analysis. With La_0.7Sr _0.3FeO_3-σ (LSF) as the cathode, the fuel cell performance with the structure of Ni-BCN18/BCN18/LSF was studied.

Original language	English (US)
Pages (from-to)	3806-3809
Number of pages	4
Journal	Journal of the American Ceramic Society
Volume	91
Issue number	11
DOIs	https://doi.org/10.1111/j.1551-2916.2008.02733.x
State	Published - Nov 2008
Externally published	Yes

ASJC Scopus subject areas

Ceramics and Composites
Materials Chemistry

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10.1111/j.1551-2916.2008.02733.x

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title = "In situ fabrication of a supported Ba3Ca1.18Nb 1.82O9-δ membrane electrolyte for a proton-conducting SOFC",

abstract = "A thin Ba3Ca1.18Nb1.82O 9-δ (BCN18) membrane electrolyte was prepared by a novel and facile method on a NiO-BCN18 anode substrate. The interesting aspect of the method was the adoption of a in situ reaction of BaCO3, CaCO 3, and Nb2O5 on the anode substrate to prepare a dense BCN18 membrane. The BCN18 membrane obtained, which was about 15 μm in thickness and showed high chemical stability against H2O and CO 2, attained a high density after sintering at 1400°C. The elemental composition of the BCN18 membrane prepared was identified by energy-dispersive X-ray spectroscopy analysis. With La0.7Sr 0.3FeO3-σ (LSF) as the cathode, the fuel cell performance with the structure of Ni-BCN18/BCN18/LSF was studied.",

author = "Lei Bi and Shangquan Zhang and Shumin Fang and Lei Zhang and Haiying Gao and Guangyao Meng and Wei Liu",

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doi = "10.1111/j.1551-2916.2008.02733.x",

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T1 - In situ fabrication of a supported Ba3Ca1.18Nb 1.82O9-δ membrane electrolyte for a proton-conducting SOFC

AU - Bi, Lei

AU - Zhang, Shangquan

AU - Fang, Shumin

AU - Zhang, Lei

AU - Gao, Haiying

AU - Meng, Guangyao

AU - Liu, Wei

PY - 2008/11

Y1 - 2008/11

N2 - A thin Ba3Ca1.18Nb1.82O 9-δ (BCN18) membrane electrolyte was prepared by a novel and facile method on a NiO-BCN18 anode substrate. The interesting aspect of the method was the adoption of a in situ reaction of BaCO3, CaCO 3, and Nb2O5 on the anode substrate to prepare a dense BCN18 membrane. The BCN18 membrane obtained, which was about 15 μm in thickness and showed high chemical stability against H2O and CO 2, attained a high density after sintering at 1400°C. The elemental composition of the BCN18 membrane prepared was identified by energy-dispersive X-ray spectroscopy analysis. With La0.7Sr 0.3FeO3-σ (LSF) as the cathode, the fuel cell performance with the structure of Ni-BCN18/BCN18/LSF was studied.

AB - A thin Ba3Ca1.18Nb1.82O 9-δ (BCN18) membrane electrolyte was prepared by a novel and facile method on a NiO-BCN18 anode substrate. The interesting aspect of the method was the adoption of a in situ reaction of BaCO3, CaCO 3, and Nb2O5 on the anode substrate to prepare a dense BCN18 membrane. The BCN18 membrane obtained, which was about 15 μm in thickness and showed high chemical stability against H2O and CO 2, attained a high density after sintering at 1400°C. The elemental composition of the BCN18 membrane prepared was identified by energy-dispersive X-ray spectroscopy analysis. With La0.7Sr 0.3FeO3-σ (LSF) as the cathode, the fuel cell performance with the structure of Ni-BCN18/BCN18/LSF was studied.

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In situ fabrication of a supported Ba₃Ca_1.18Nb _1.82O_9-δ membrane electrolyte for a proton-conducting SOFC

Abstract

ASJC Scopus subject areas

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