Importance of small loops within PIM-1 topology on gas separation selectivity in thin film composite membranes

Andrew B. Foster; Joseph L. Beal; Marzieh Tamaddondar; Jose Miguel Luque-Alled; Ben Robertson; Michael Mathias; Patricia Gorgojo; Peter M. Budd

doi:10.1039/d1ta03712a

Importance of small loops within PIM-1 topology on gas separation selectivity in thin film composite membranes

Andrew B. Foster, Joseph L. Beal, Marzieh Tamaddondar, Jose Miguel Luque-Alled, Ben Robertson, Michael Mathias, Patricia Gorgojo, Peter M. Budd

Research output: Contribution to journal › Article › peer-review

37 Scopus citations

Abstract

Studies of blends of topologically distinct samples of the polymer of intrinsic microporosity PIM-1 provide, for the CO2/N2 gas pair, insight into the optimum loop topology required for high selectivity and permeance of thin film composite (TFC) membranes.

Original language	English (US)
Journal	JOURNAL OF MATERIALS CHEMISTRY A
DOIs	https://doi.org/10.1039/d1ta03712a
State	Published - 2021
Externally published	Yes

Bibliographical note

KAUST Repository Item: Exported on 2021-10-07
Acknowledgements: P. M. B., M. T. and A. B. F. would like to thank the support of Programme Grant EP/M01486X/1 (SynFabFun) funded by the Engineering and Physical Sciences Research Council (EPSRC). We thank Emma Enston, Anne Davies, Martin Jennings and Teruo Hashimoto for their assistance in obtaining the MALDITOF mass spectra, elemental analysis and TEM analysis, respectively. We thank Prof. Ingo Pinnau (King Abdullah
University of Science and Technology, Saudi Arabia) for kindly providing the porous polyacrylonitrile (PAN) membrane (Sepro PA350 ultrafiltration membrane) used in preparation of TFC membranes.

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title = "Importance of small loops within PIM-1 topology on gas separation selectivity in thin film composite membranes",

abstract = "Studies of blends of topologically distinct samples of the polymer of intrinsic microporosity PIM-1 provide, for the CO2/N2 gas pair, insight into the optimum loop topology required for high selectivity and permeance of thin film composite (TFC) membranes.",

author = "Foster, {Andrew B.} and Beal, {Joseph L.} and Marzieh Tamaddondar and Luque-Alled, {Jose Miguel} and Ben Robertson and Michael Mathias and Patricia Gorgojo and Budd, {Peter M.}",

note = "KAUST Repository Item: Exported on 2021-10-07 Acknowledgements: P. M. B., M. T. and A. B. F. would like to thank the support of Programme Grant EP/M01486X/1 (SynFabFun) funded by the Engineering and Physical Sciences Research Council (EPSRC). We thank Emma Enston, Anne Davies, Martin Jennings and Teruo Hashimoto for their assistance in obtaining the MALDITOF mass spectra, elemental analysis and TEM analysis, respectively. We thank Prof. Ingo Pinnau (King Abdullah University of Science and Technology, Saudi Arabia) for kindly providing the porous polyacrylonitrile (PAN) membrane (Sepro PA350 ultrafiltration membrane) used in preparation of TFC membranes.",

year = "2021",

doi = "10.1039/d1ta03712a",

language = "English (US)",

journal = "JOURNAL OF MATERIALS CHEMISTRY A",

issn = "2050-7496",

publisher = "Royal Society of Chemistry",

}

TY - JOUR

T1 - Importance of small loops within PIM-1 topology on gas separation selectivity in thin film composite membranes

AU - Foster, Andrew B.

AU - Beal, Joseph L.

AU - Tamaddondar, Marzieh

AU - Luque-Alled, Jose Miguel

AU - Robertson, Ben

AU - Mathias, Michael

AU - Gorgojo, Patricia

AU - Budd, Peter M.

N1 - KAUST Repository Item: Exported on 2021-10-07 Acknowledgements: P. M. B., M. T. and A. B. F. would like to thank the support of Programme Grant EP/M01486X/1 (SynFabFun) funded by the Engineering and Physical Sciences Research Council (EPSRC). We thank Emma Enston, Anne Davies, Martin Jennings and Teruo Hashimoto for their assistance in obtaining the MALDITOF mass spectra, elemental analysis and TEM analysis, respectively. We thank Prof. Ingo Pinnau (King Abdullah University of Science and Technology, Saudi Arabia) for kindly providing the porous polyacrylonitrile (PAN) membrane (Sepro PA350 ultrafiltration membrane) used in preparation of TFC membranes.

PY - 2021

Y1 - 2021

N2 - Studies of blends of topologically distinct samples of the polymer of intrinsic microporosity PIM-1 provide, for the CO2/N2 gas pair, insight into the optimum loop topology required for high selectivity and permeance of thin film composite (TFC) membranes.

AB - Studies of blends of topologically distinct samples of the polymer of intrinsic microporosity PIM-1 provide, for the CO2/N2 gas pair, insight into the optimum loop topology required for high selectivity and permeance of thin film composite (TFC) membranes.

UR - http://hdl.handle.net/10754/672184

UR - http://xlink.rsc.org/?DOI=D1TA03712A

U2 - 10.1039/d1ta03712a

DO - 10.1039/d1ta03712a

M3 - Article

SN - 2050-7496

JO - JOURNAL OF MATERIALS CHEMISTRY A

JF - JOURNAL OF MATERIALS CHEMISTRY A

ER -

Importance of small loops within PIM-1 topology on gas separation selectivity in thin film composite membranes

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