Implantation of Iron(III) in porphyrinic metal organic frameworks for highly improved photocatalytic performance

Li Shi; Liuqing Yang; Huabin Zhang; Kun Chang; Guixia Zhao; Tetsuya Kako; Jinhua Ye

doi:10.1016/j.apcatb.2017.10.033

Implantation of Iron(III) in porphyrinic metal organic frameworks for highly improved photocatalytic performance

Li Shi, Liuqing Yang, Huabin Zhang, Kun Chang, Guixia Zhao, Tetsuya Kako, Jinhua Ye

Research output: Contribution to journal › Article › peer-review

135 Scopus citations

Abstract

Herein a simple approach is proposed to greatly improve the photocatalytic performance of a porphyrinic metal organic framework (PCN-224) by implantation of coordinatively unsaturated Fe(III) sites into the porphyrin unit. Taking the photooxidation of isopropanol (IPA) as a model reaction, the newly developed Fe@PCN-224 exhibits significantly enhanced photocatalytic activity, which is equivalent to an 8.9-fold improvement in acetone evolution rate and 9.3-fold enhancements in CO2 generation rate compared with the PCN-224. Mechanism investigation reveals that the presence of Fe(III) sites in the PCN-224 can not only greatly boost the electron–hole separation efficiency, but also effectively convert the in-situ photogenerated inactive H2O2 into reactive oxygen-related radicals via Fenton reactions to participate in the photocatalytic IPA oxidation. The enhanced photocatalytic activity for IPA oxidation is also observed over another Fe(III) implanted porphyrinic metal organic framework (Fe@PCN-222), suggesting the generality of this strategy.

Original language	English (US)
Pages (from-to)	60-68
Number of pages	9
Journal	Applied Catalysis B: Environmental
Volume	224
DOIs	https://doi.org/10.1016/j.apcatb.2017.10.033
State	Published - May 1 2018
Externally published	Yes

Bibliographical note

Generated from Scopus record by KAUST IRTS on 2022-09-15

ASJC Scopus subject areas

General Environmental Science
Catalysis
Process Chemistry and Technology

Access to Document

10.1016/j.apcatb.2017.10.033

Cite this

@article{4af24e45252d40978fc571d1db2e7f01,

title = "Implantation of Iron(III) in porphyrinic metal organic frameworks for highly improved photocatalytic performance",

abstract = "Herein a simple approach is proposed to greatly improve the photocatalytic performance of a porphyrinic metal organic framework (PCN-224) by implantation of coordinatively unsaturated Fe(III) sites into the porphyrin unit. Taking the photooxidation of isopropanol (IPA) as a model reaction, the newly developed Fe@PCN-224 exhibits significantly enhanced photocatalytic activity, which is equivalent to an 8.9-fold improvement in acetone evolution rate and 9.3-fold enhancements in CO2 generation rate compared with the PCN-224. Mechanism investigation reveals that the presence of Fe(III) sites in the PCN-224 can not only greatly boost the electron–hole separation efficiency, but also effectively convert the in-situ photogenerated inactive H2O2 into reactive oxygen-related radicals via Fenton reactions to participate in the photocatalytic IPA oxidation. The enhanced photocatalytic activity for IPA oxidation is also observed over another Fe(III) implanted porphyrinic metal organic framework (Fe@PCN-222), suggesting the generality of this strategy.",

author = "Li Shi and Liuqing Yang and Huabin Zhang and Kun Chang and Guixia Zhao and Tetsuya Kako and Jinhua Ye",

note = "Generated from Scopus record by KAUST IRTS on 2022-09-15",

year = "2018",

month = may,

day = "1",

doi = "10.1016/j.apcatb.2017.10.033",

language = "English (US)",

volume = "224",

pages = "60--68",

journal = "Applied Catalysis B: Environmental",

issn = "0926-3373",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Implantation of Iron(III) in porphyrinic metal organic frameworks for highly improved photocatalytic performance

AU - Shi, Li

AU - Yang, Liuqing

AU - Zhang, Huabin

AU - Chang, Kun

AU - Zhao, Guixia

AU - Kako, Tetsuya

AU - Ye, Jinhua

N1 - Generated from Scopus record by KAUST IRTS on 2022-09-15

PY - 2018/5/1

Y1 - 2018/5/1

N2 - Herein a simple approach is proposed to greatly improve the photocatalytic performance of a porphyrinic metal organic framework (PCN-224) by implantation of coordinatively unsaturated Fe(III) sites into the porphyrin unit. Taking the photooxidation of isopropanol (IPA) as a model reaction, the newly developed Fe@PCN-224 exhibits significantly enhanced photocatalytic activity, which is equivalent to an 8.9-fold improvement in acetone evolution rate and 9.3-fold enhancements in CO2 generation rate compared with the PCN-224. Mechanism investigation reveals that the presence of Fe(III) sites in the PCN-224 can not only greatly boost the electron–hole separation efficiency, but also effectively convert the in-situ photogenerated inactive H2O2 into reactive oxygen-related radicals via Fenton reactions to participate in the photocatalytic IPA oxidation. The enhanced photocatalytic activity for IPA oxidation is also observed over another Fe(III) implanted porphyrinic metal organic framework (Fe@PCN-222), suggesting the generality of this strategy.

AB - Herein a simple approach is proposed to greatly improve the photocatalytic performance of a porphyrinic metal organic framework (PCN-224) by implantation of coordinatively unsaturated Fe(III) sites into the porphyrin unit. Taking the photooxidation of isopropanol (IPA) as a model reaction, the newly developed Fe@PCN-224 exhibits significantly enhanced photocatalytic activity, which is equivalent to an 8.9-fold improvement in acetone evolution rate and 9.3-fold enhancements in CO2 generation rate compared with the PCN-224. Mechanism investigation reveals that the presence of Fe(III) sites in the PCN-224 can not only greatly boost the electron–hole separation efficiency, but also effectively convert the in-situ photogenerated inactive H2O2 into reactive oxygen-related radicals via Fenton reactions to participate in the photocatalytic IPA oxidation. The enhanced photocatalytic activity for IPA oxidation is also observed over another Fe(III) implanted porphyrinic metal organic framework (Fe@PCN-222), suggesting the generality of this strategy.

UR - https://linkinghub.elsevier.com/retrieve/pii/S0926337317310068

UR - http://www.scopus.com/inward/record.url?scp=85032653075&partnerID=8YFLogxK

U2 - 10.1016/j.apcatb.2017.10.033

DO - 10.1016/j.apcatb.2017.10.033

M3 - Article

SN - 0926-3373

VL - 224

SP - 60

EP - 68

JO - Applied Catalysis B: Environmental

JF - Applied Catalysis B: Environmental

ER -

Implantation of Iron(III) in porphyrinic metal organic frameworks for highly improved photocatalytic performance

Abstract

Bibliographical note

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this