Hydrogen bonded H3O+, H2O, HF, F- in fluoride metalates (Al, Cr, Fe, Zr, Ta) templated with tren (tris-(2-aminoethyl)amine)

Karim Adil; Mohamed Ali Saada; Amor Ben Ali; Monique Body; Minh Trung Dang; Annie Hémon-Ribaud; Marc Leblanc; Vincent Maisonneuve

doi:10.1016/j.jfluchem.2006.10.015

Hydrogen bonded H₃O⁺, H₂O, HF, F^- in fluoride metalates (Al, Cr, Fe, Zr, Ta) templated with tren (tris-(2-aminoethyl)amine)

Karim Adil, Mohamed Ali Saada, Amor Ben Ali, Monique Body, Minh Trung Dang, Annie Hémon-Ribaud, Marc Leblanc, Vincent Maisonneuve^*

^*Corresponding author for this work

Research output: Contribution to journal › Review article › peer-review

19 Scopus citations

Abstract

The environment of H₃O⁺, H₂O, HF and F^- species (non-bonded to metals) is considered in fluoride metalates which crystallise from the (Al(OH)₃, Cr(OH)₃, FeF₃, ZrF₄, Ta₂O₅)-tren-HF_aq·-ethanol systems (microwave heating at 190 °C during 1 h). The presence of (H₃O)(H₂O)₆⁺ clusters or H₃O⁺ cations, of isolated or associated H₂O molecules, of (HF₂)^- and F^- anions is evidenced. The thermal stability of the solids depends strongly on the nature of the hydrogen-bonded species associated with the preceding cations or anions and on the formation of water ribbons or layers.

Original language	English (US)
Pages (from-to)	404-412
Number of pages	9
Journal	Journal of Fluorine Chemistry
Volume	128
Issue number	4
DOIs	https://doi.org/10.1016/j.jfluchem.2006.10.015
State	Published - Apr 2007
Externally published	Yes

Keywords

Hybrid fluorides
Hydrogen bond
Hydrothermal synthesis
Microwave heating
Water cluster

ASJC Scopus subject areas

Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Environmental Chemistry
Organic Chemistry

Access to Document

10.1016/j.jfluchem.2006.10.015

Cite this

@article{07ba8f5d76dc4d47aa2db41e168e74a4,

title = "Hydrogen bonded H3O+, H2O, HF, F- in fluoride metalates (Al, Cr, Fe, Zr, Ta) templated with tren (tris-(2-aminoethyl)amine)",

abstract = "The environment of H3O+, H2O, HF and F- species (non-bonded to metals) is considered in fluoride metalates which crystallise from the (Al(OH)3, Cr(OH)3, FeF3, ZrF4, Ta2O5)-tren-HFaq·-ethanol systems (microwave heating at 190 °C during 1 h). The presence of (H3O)(H2O)6+ clusters or H3O+ cations, of isolated or associated H2O molecules, of (HF2)- and F- anions is evidenced. The thermal stability of the solids depends strongly on the nature of the hydrogen-bonded species associated with the preceding cations or anions and on the formation of water ribbons or layers.",

keywords = "Hybrid fluorides, Hydrogen bond, Hydrothermal synthesis, Microwave heating, Water cluster",

author = "Karim Adil and Saada, {Mohamed Ali} and Ali, {Amor Ben} and Monique Body and Dang, {Minh Trung} and Annie H{\'e}mon-Ribaud and Marc Leblanc and Vincent Maisonneuve",

year = "2007",

month = apr,

doi = "10.1016/j.jfluchem.2006.10.015",

language = "English (US)",

volume = "128",

pages = "404--412",

journal = "Journal of Fluorine Chemistry",

issn = "0022-1139",

publisher = "Elsevier",

number = "4",

}

TY - JOUR

T1 - Hydrogen bonded H3O+, H2O, HF, F- in fluoride metalates (Al, Cr, Fe, Zr, Ta) templated with tren (tris-(2-aminoethyl)amine)

AU - Adil, Karim

AU - Saada, Mohamed Ali

AU - Ali, Amor Ben

AU - Body, Monique

AU - Dang, Minh Trung

AU - Hémon-Ribaud, Annie

AU - Leblanc, Marc

AU - Maisonneuve, Vincent

PY - 2007/4

Y1 - 2007/4

N2 - The environment of H3O+, H2O, HF and F- species (non-bonded to metals) is considered in fluoride metalates which crystallise from the (Al(OH)3, Cr(OH)3, FeF3, ZrF4, Ta2O5)-tren-HFaq·-ethanol systems (microwave heating at 190 °C during 1 h). The presence of (H3O)(H2O)6+ clusters or H3O+ cations, of isolated or associated H2O molecules, of (HF2)- and F- anions is evidenced. The thermal stability of the solids depends strongly on the nature of the hydrogen-bonded species associated with the preceding cations or anions and on the formation of water ribbons or layers.

AB - The environment of H3O+, H2O, HF and F- species (non-bonded to metals) is considered in fluoride metalates which crystallise from the (Al(OH)3, Cr(OH)3, FeF3, ZrF4, Ta2O5)-tren-HFaq·-ethanol systems (microwave heating at 190 °C during 1 h). The presence of (H3O)(H2O)6+ clusters or H3O+ cations, of isolated or associated H2O molecules, of (HF2)- and F- anions is evidenced. The thermal stability of the solids depends strongly on the nature of the hydrogen-bonded species associated with the preceding cations or anions and on the formation of water ribbons or layers.

KW - Hybrid fluorides

KW - Hydrogen bond

KW - Hydrothermal synthesis

KW - Microwave heating

KW - Water cluster

UR - http://www.scopus.com/inward/record.url?scp=33947370950&partnerID=8YFLogxK

U2 - 10.1016/j.jfluchem.2006.10.015

DO - 10.1016/j.jfluchem.2006.10.015

M3 - Review article

AN - SCOPUS:33947370950

SN - 0022-1139

VL - 128

SP - 404

EP - 412

JO - Journal of Fluorine Chemistry

JF - Journal of Fluorine Chemistry

IS - 4

ER -