Hydrated alkali metal and ammonium salts of the [P2Se 6]4- anion

Alexander Rothenberger; Christos D. Malliaka; Mercouri G. Kanatzidis

doi:10.1002/zaac.200900184

Hydrated alkali metal and ammonium salts of the [P₂Se ₆]^4- anion

Alexander Rothenberger, Christos D. Malliaka, Mercouri G. Kanatzidis

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

The synthesis and structures of the five new compounds [Na ₄(P₂Se₆)(H₂O)₆], [M ₄(P₂Se₆)(H₂O)₄] (M = K, Rb, Cs) and [(NH₄)₄(P₂Se₆)(H ₂O)₂] are reported. The salts were obtained from reactions of metal carbonates with P₄Se₁₀ in water and in ambient atmosphere. During the heterogeneous reactions, the selenophosphate salts, CO₂ and elemental selenium is formed together with the [P ₂O₆]^4- ion and most likely other phosphate/selenophosphate derivatives. The ethane-like [P₂Se6] ^4- anion was characterized in solution by ³¹P NMR spectroscopy showing an ABX pattern.

Original language	English (US)
Pages (from-to)	1374-1379
Number of pages	6
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	635
Issue number	9-10
DOIs	https://doi.org/10.1002/zaac.200900184
State	Published - Jul 2009
Externally published	Yes

Keywords

Alkali metals
Anions
Phosphorus
Selenium
X-ray diffraction

ASJC Scopus subject areas

Inorganic Chemistry

Access to Document

10.1002/zaac.200900184

Cite this

@article{315ca45f4b1a436c888f1a8ba23078d7,

title = "Hydrated alkali metal and ammonium salts of the [P2Se 6]4- anion",

abstract = "The synthesis and structures of the five new compounds [Na 4(P2Se6)(H2O)6], [M 4(P2Se6)(H2O)4] (M = K, Rb, Cs) and [(NH4)4(P2Se6)(H 2O)2] are reported. The salts were obtained from reactions of metal carbonates with P4Se10 in water and in ambient atmosphere. During the heterogeneous reactions, the selenophosphate salts, CO2 and elemental selenium is formed together with the [P 2O6]4- ion and most likely other phosphate/selenophosphate derivatives. The ethane-like [P2Se6] 4- anion was characterized in solution by 31P NMR spectroscopy showing an ABX pattern.",

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author = "Alexander Rothenberger and Malliaka, {Christos D.} and Kanatzidis, {Mercouri G.}",

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T1 - Hydrated alkali metal and ammonium salts of the [P2Se 6]4- anion

AU - Rothenberger, Alexander

AU - Malliaka, Christos D.

AU - Kanatzidis, Mercouri G.

PY - 2009/7

Y1 - 2009/7

N2 - The synthesis and structures of the five new compounds [Na 4(P2Se6)(H2O)6], [M 4(P2Se6)(H2O)4] (M = K, Rb, Cs) and [(NH4)4(P2Se6)(H 2O)2] are reported. The salts were obtained from reactions of metal carbonates with P4Se10 in water and in ambient atmosphere. During the heterogeneous reactions, the selenophosphate salts, CO2 and elemental selenium is formed together with the [P 2O6]4- ion and most likely other phosphate/selenophosphate derivatives. The ethane-like [P2Se6] 4- anion was characterized in solution by 31P NMR spectroscopy showing an ABX pattern.

AB - The synthesis and structures of the five new compounds [Na 4(P2Se6)(H2O)6], [M 4(P2Se6)(H2O)4] (M = K, Rb, Cs) and [(NH4)4(P2Se6)(H 2O)2] are reported. The salts were obtained from reactions of metal carbonates with P4Se10 in water and in ambient atmosphere. During the heterogeneous reactions, the selenophosphate salts, CO2 and elemental selenium is formed together with the [P 2O6]4- ion and most likely other phosphate/selenophosphate derivatives. The ethane-like [P2Se6] 4- anion was characterized in solution by 31P NMR spectroscopy showing an ABX pattern.

KW - Alkali metals

KW - Anions

KW - Phosphorus

KW - Selenium

KW - X-ray diffraction

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DO - 10.1002/zaac.200900184

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