Hybrid metal-organic framework nanomaterials with enhanced carbon dioxide and methane adsorption enthalpy by incorporation of carbon nanotubes

Zixi Kang; Ming Xue; Daliang Zhang; Lili Fan; Ying Pan; Shilun Qiu

doi:10.1016/j.inoche.2015.06.007

Hybrid metal-organic framework nanomaterials with enhanced carbon dioxide and methane adsorption enthalpy by incorporation of carbon nanotubes

Zixi Kang, Ming Xue, Daliang Zhang, Lili Fan, Ying Pan, Shilun Qiu

Research output: Contribution to journal › Article › peer-review

40 Scopus citations

Abstract

Abstract Two hybrid materials composed of metal-organic framework (JUC-32) nanoparticles and carboxyl-modified multi-wall carbon nanotubes (MWCNTs) were synthesised successfully in situ and characterized by TEM, PXRD, and TGA. The gas adsorption properties of these two hybrid materials were compared with the original JUC-32 material and a physical mixture of JUC-32 and MWCNTs. The results indicated that the composite materials absorbed larger amounts of CO2 and CH4 per specific surface area than the original materials, and that the adsorption enthalpies of CO2 and CH4 had significantly increased.

Original language	English (US)
Pages (from-to)	79-83
Number of pages	5
Journal	INORGANIC CHEMISTRY COMMUNICATIONS
Volume	58
DOIs	https://doi.org/10.1016/j.inoche.2015.06.007
State	Published - 2015
Externally published	Yes

Bibliographical note

KAUST Repository Item: Exported on 2021-11-01
Acknowledged KAUST grant number(s): CRG-1-2012-LAI-009
Acknowledgements: This work was supported by the National Natural Science Foundation of China (21390394), the National Basic Research Program of China (2012CB821700), NSFC (21261130584, 21201076, 21101072), 111 project (B07016), and Award Project of KAUST (CRG-1-2012-LAI-009).
This publication acknowledges KAUST support, but has no KAUST affiliated authors.

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@article{b81b67bf805d48669f545ed0a6c3dda4,

title = "Hybrid metal-organic framework nanomaterials with enhanced carbon dioxide and methane adsorption enthalpy by incorporation of carbon nanotubes",

abstract = "Abstract Two hybrid materials composed of metal-organic framework (JUC-32) nanoparticles and carboxyl-modified multi-wall carbon nanotubes (MWCNTs) were synthesised successfully in situ and characterized by TEM, PXRD, and TGA. The gas adsorption properties of these two hybrid materials were compared with the original JUC-32 material and a physical mixture of JUC-32 and MWCNTs. The results indicated that the composite materials absorbed larger amounts of CO2 and CH4 per specific surface area than the original materials, and that the adsorption enthalpies of CO2 and CH4 had significantly increased.",

author = "Zixi Kang and Ming Xue and Daliang Zhang and Lili Fan and Ying Pan and Shilun Qiu",

note = "KAUST Repository Item: Exported on 2021-11-01 Acknowledged KAUST grant number(s): CRG-1-2012-LAI-009 Acknowledgements: This work was supported by the National Natural Science Foundation of China (21390394), the National Basic Research Program of China (2012CB821700), NSFC (21261130584, 21201076, 21101072), 111 project (B07016), and Award Project of KAUST (CRG-1-2012-LAI-009). This publication acknowledges KAUST support, but has no KAUST affiliated authors.",

year = "2015",

doi = "10.1016/j.inoche.2015.06.007",

language = "English (US)",

volume = "58",

pages = "79--83",

journal = "INORGANIC CHEMISTRY COMMUNICATIONS",

issn = "1879-0259",

publisher = "Elsevier",

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TY - JOUR

T1 - Hybrid metal-organic framework nanomaterials with enhanced carbon dioxide and methane adsorption enthalpy by incorporation of carbon nanotubes

AU - Kang, Zixi

AU - Xue, Ming

AU - Zhang, Daliang

AU - Fan, Lili

AU - Pan, Ying

AU - Qiu, Shilun

N1 - KAUST Repository Item: Exported on 2021-11-01 Acknowledged KAUST grant number(s): CRG-1-2012-LAI-009 Acknowledgements: This work was supported by the National Natural Science Foundation of China (21390394), the National Basic Research Program of China (2012CB821700), NSFC (21261130584, 21201076, 21101072), 111 project (B07016), and Award Project of KAUST (CRG-1-2012-LAI-009). This publication acknowledges KAUST support, but has no KAUST affiliated authors.

PY - 2015

Y1 - 2015

N2 - Abstract Two hybrid materials composed of metal-organic framework (JUC-32) nanoparticles and carboxyl-modified multi-wall carbon nanotubes (MWCNTs) were synthesised successfully in situ and characterized by TEM, PXRD, and TGA. The gas adsorption properties of these two hybrid materials were compared with the original JUC-32 material and a physical mixture of JUC-32 and MWCNTs. The results indicated that the composite materials absorbed larger amounts of CO2 and CH4 per specific surface area than the original materials, and that the adsorption enthalpies of CO2 and CH4 had significantly increased.

AB - Abstract Two hybrid materials composed of metal-organic framework (JUC-32) nanoparticles and carboxyl-modified multi-wall carbon nanotubes (MWCNTs) were synthesised successfully in situ and characterized by TEM, PXRD, and TGA. The gas adsorption properties of these two hybrid materials were compared with the original JUC-32 material and a physical mixture of JUC-32 and MWCNTs. The results indicated that the composite materials absorbed larger amounts of CO2 and CH4 per specific surface area than the original materials, and that the adsorption enthalpies of CO2 and CH4 had significantly increased.

UR - http://hdl.handle.net/10754/672995

UR - https://linkinghub.elsevier.com/retrieve/pii/S1387700315002282

UR - http://www.scopus.com/inward/record.url?scp=84931260117&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2015.06.007

DO - 10.1016/j.inoche.2015.06.007

M3 - Article

SN - 1879-0259

VL - 58

SP - 79

EP - 83

JO - INORGANIC CHEMISTRY COMMUNICATIONS

JF - INORGANIC CHEMISTRY COMMUNICATIONS

ER -

Hybrid metal-organic framework nanomaterials with enhanced carbon dioxide and methane adsorption enthalpy by incorporation of carbon nanotubes

Abstract

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