[H4tren]3/2·(Al6F24)·3H2O, the most condensed fluoride in the Al(OH)3-tren-HFaq.-ethanol system

K. Adil; J. Marrot; M. Leblanc; V. Maisonneuve

doi:10.1016/j.solidstatesciences.2007.03.024

[H₄tren]_3/2·(Al₆F₂₄)·3H₂O, the most condensed fluoride in the Al(OH)₃-tren-HF_aq.-ethanol system

K. Adil, J. Marrot, M. Leblanc, V. Maisonneuve^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

The most condensed crystalline fluoride that appears in the Al(OH)₃-tren-HF_aq.-ethanol system at 190 °C is found to be [H₄tren]_3/2·(Al₆F₂₄)·3H₂O. The structure is monoclinic, P2₁/c, with a = 21.939(1) Å, b = 6.7180(2) Å, c = 23.329(1) Å, β = 111.324(2)°. _∞(Al₆F₂₄) chains result from the connection of (Al₇F₃₀)^9- polyanions by opposite AlF₆ octahedra. Hydrogen bonds are established between the _∞(Al₆F₂₄) chains and ordered or disordered [H₄tren]⁴⁺ cations and water molecules.

Original language	English (US)
Pages (from-to)	531-534
Number of pages	4
Journal	Solid State Sciences
Volume	9
Issue number	6
DOIs	https://doi.org/10.1016/j.solidstatesciences.2007.03.024
State	Published - Jun 2007
Externally published	Yes

Keywords

Fluoride
Tris-2-(aminoethyl)amine
X-ray diffraction

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

Access to Document

10.1016/j.solidstatesciences.2007.03.024

Cite this

@article{000d1961bc5a46b69b3bfd1a1e8caf37,

title = "[H4tren]3/2·(Al6F24)·3H2O, the most condensed fluoride in the Al(OH)3-tren-HFaq.-ethanol system",

abstract = "The most condensed crystalline fluoride that appears in the Al(OH)3-tren-HFaq.-ethanol system at 190 °C is found to be [H4tren]3/2·(Al6F24)·3H2O. The structure is monoclinic, P21/c, with a = 21.939(1) {\AA}, b = 6.7180(2) {\AA}, c = 23.329(1) {\AA}, β = 111.324(2)°. ∞(Al6F24) chains result from the connection of (Al7F30)9- polyanions by opposite AlF6 octahedra. Hydrogen bonds are established between the ∞(Al6F24) chains and ordered or disordered [H4tren]4+ cations and water molecules.",

keywords = "Fluoride, Tris-2-(aminoethyl)amine, X-ray diffraction",

author = "K. Adil and J. Marrot and M. Leblanc and V. Maisonneuve",

year = "2007",

month = jun,

doi = "10.1016/j.solidstatesciences.2007.03.024",

language = "English (US)",

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pages = "531--534",

journal = "Solid State Sciences",

issn = "1293-2558",

publisher = "Elsevier Masson s.r.l.",

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T1 - [H4tren]3/2·(Al6F24)·3H2O, the most condensed fluoride in the Al(OH)3-tren-HFaq.-ethanol system

AU - Adil, K.

AU - Marrot, J.

AU - Leblanc, M.

AU - Maisonneuve, V.

PY - 2007/6

Y1 - 2007/6

N2 - The most condensed crystalline fluoride that appears in the Al(OH)3-tren-HFaq.-ethanol system at 190 °C is found to be [H4tren]3/2·(Al6F24)·3H2O. The structure is monoclinic, P21/c, with a = 21.939(1) Å, b = 6.7180(2) Å, c = 23.329(1) Å, β = 111.324(2)°. ∞(Al6F24) chains result from the connection of (Al7F30)9- polyanions by opposite AlF6 octahedra. Hydrogen bonds are established between the ∞(Al6F24) chains and ordered or disordered [H4tren]4+ cations and water molecules.

AB - The most condensed crystalline fluoride that appears in the Al(OH)3-tren-HFaq.-ethanol system at 190 °C is found to be [H4tren]3/2·(Al6F24)·3H2O. The structure is monoclinic, P21/c, with a = 21.939(1) Å, b = 6.7180(2) Å, c = 23.329(1) Å, β = 111.324(2)°. ∞(Al6F24) chains result from the connection of (Al7F30)9- polyanions by opposite AlF6 octahedra. Hydrogen bonds are established between the ∞(Al6F24) chains and ordered or disordered [H4tren]4+ cations and water molecules.

KW - Fluoride

KW - Tris-2-(aminoethyl)amine

KW - X-ray diffraction

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