Host–Guest Chirality Interplay: A Mutually Induced Formation of a Chiral ZMOF and Its Double-Helix Polymer Guests

Xiaolong Luo; Yu Cao; Tao Wang; Guanghua Li; Jiangang Li; Yonggang Yang; Zhongxuan Xu; Jian Zhang; Qisheng Huo; Yunling Liu; Mohamed Eddaoudi

doi:10.1021/jacs.5b12516

Host–Guest Chirality Interplay: A Mutually Induced Formation of a Chiral ZMOF and Its Double-Helix Polymer Guests

Xiaolong Luo, Yu Cao, Tao Wang, Guanghua Li, Jiangang Li, Yonggang Yang, Zhongxuan Xu, Jian Zhang, Qisheng Huo, Yunling Liu, Mohamed Eddaoudi

Research output: Contribution to journal › Article › peer-review

122 Scopus citations

Abstract

A novel homochiral zeolite-like metal-organic framework (ZMOF), [(Cu4I4) (dabco)2]·[Cu2(bbimb)]·3DMF (JLU-Liu23, dabco =1,4-diazabicyclo[2.2.2]-octane, H2bbimb =1,3-bis(2-benzimidazol)benzene, DMF = N,N-dimethylformamide), has been successfully constructed to host unprecedented DNA-like [Cu2(bbimb)]n polymers with double-helicity. The host-guest chirality interplay permitted the induced formation of an unusual gyroid MOF with homochirality and helical channels in the framework for the first time, JLU-Liu23. Importantly, the enantiomeric pairs (23P, 23M) can be promoted and isolated in the presence of appropriate chiral inducing agents, affording enantioselective separation of chiral molecules as well as small gas molecules. © 2016 American Chemical Society.

Original language	English (US)
Pages (from-to)	786-789
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	138
Issue number	3
DOIs	https://doi.org/10.1021/jacs.5b12516
State	Published - Jan 14 2016

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: The authors gratefully acknowledge the financial support of the Natural Science Foundation of China (nos. 21373095, 21371067, and 21171064).

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10.1021/jacs.5b12516

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@article{3786e14805a540d4ba4661bb6fb6a54a,

title = "Host–Guest Chirality Interplay: A Mutually Induced Formation of a Chiral ZMOF and Its Double-Helix Polymer Guests",

abstract = "A novel homochiral zeolite-like metal-organic framework (ZMOF), [(Cu4I4) (dabco)2]·[Cu2(bbimb)]·3DMF (JLU-Liu23, dabco =1,4-diazabicyclo[2.2.2]-octane, H2bbimb =1,3-bis(2-benzimidazol)benzene, DMF = N,N-dimethylformamide), has been successfully constructed to host unprecedented DNA-like [Cu2(bbimb)]n polymers with double-helicity. The host-guest chirality interplay permitted the induced formation of an unusual gyroid MOF with homochirality and helical channels in the framework for the first time, JLU-Liu23. Importantly, the enantiomeric pairs (23P, 23M) can be promoted and isolated in the presence of appropriate chiral inducing agents, affording enantioselective separation of chiral molecules as well as small gas molecules. {\textcopyright} 2016 American Chemical Society.",

author = "Xiaolong Luo and Yu Cao and Tao Wang and Guanghua Li and Jiangang Li and Yonggang Yang and Zhongxuan Xu and Jian Zhang and Qisheng Huo and Yunling Liu and Mohamed Eddaoudi",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: The authors gratefully acknowledge the financial support of the Natural Science Foundation of China (nos. 21373095, 21371067, and 21171064).",

year = "2016",

month = jan,

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doi = "10.1021/jacs.5b12516",

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T1 - Host–Guest Chirality Interplay: A Mutually Induced Formation of a Chiral ZMOF and Its Double-Helix Polymer Guests

AU - Luo, Xiaolong

AU - Cao, Yu

AU - Wang, Tao

AU - Li, Guanghua

AU - Li, Jiangang

AU - Yang, Yonggang

AU - Xu, Zhongxuan

AU - Zhang, Jian

AU - Huo, Qisheng

AU - Liu, Yunling

AU - Eddaoudi, Mohamed

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: The authors gratefully acknowledge the financial support of the Natural Science Foundation of China (nos. 21373095, 21371067, and 21171064).

PY - 2016/1/14

Y1 - 2016/1/14

N2 - A novel homochiral zeolite-like metal-organic framework (ZMOF), [(Cu4I4) (dabco)2]·[Cu2(bbimb)]·3DMF (JLU-Liu23, dabco =1,4-diazabicyclo[2.2.2]-octane, H2bbimb =1,3-bis(2-benzimidazol)benzene, DMF = N,N-dimethylformamide), has been successfully constructed to host unprecedented DNA-like [Cu2(bbimb)]n polymers with double-helicity. The host-guest chirality interplay permitted the induced formation of an unusual gyroid MOF with homochirality and helical channels in the framework for the first time, JLU-Liu23. Importantly, the enantiomeric pairs (23P, 23M) can be promoted and isolated in the presence of appropriate chiral inducing agents, affording enantioselective separation of chiral molecules as well as small gas molecules. © 2016 American Chemical Society.

AB - A novel homochiral zeolite-like metal-organic framework (ZMOF), [(Cu4I4) (dabco)2]·[Cu2(bbimb)]·3DMF (JLU-Liu23, dabco =1,4-diazabicyclo[2.2.2]-octane, H2bbimb =1,3-bis(2-benzimidazol)benzene, DMF = N,N-dimethylformamide), has been successfully constructed to host unprecedented DNA-like [Cu2(bbimb)]n polymers with double-helicity. The host-guest chirality interplay permitted the induced formation of an unusual gyroid MOF with homochirality and helical channels in the framework for the first time, JLU-Liu23. Importantly, the enantiomeric pairs (23P, 23M) can be promoted and isolated in the presence of appropriate chiral inducing agents, affording enantioselective separation of chiral molecules as well as small gas molecules. © 2016 American Chemical Society.

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U2 - 10.1021/jacs.5b12516

DO - 10.1021/jacs.5b12516

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

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ER -

Host–Guest Chirality Interplay: A Mutually Induced Formation of a Chiral ZMOF and Its Double-Helix Polymer Guests

Abstract

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CCDC 1410366: Experimental Crystal Structure Determination : catena-[tetrakis(mu-iodo)-bis(mu-1,4-diazabicyclo[2.2.2]octane)-tetra-copper (mu-2,2'-(1,3-phenylene)bis(benzimidazol-1-yl))-di-copper N,N-dimethylformamide solvate]

CCDC 1410365: Experimental Crystal Structure Determination : catena-[tetrakis(mu-iodo)-bis(mu-1,4-diazabicyclo[2.2.2]octane)-tetra-copper (mu-2,2'-(1,3-phenylene)bis(benzimidazol-1-yl))-di-copper N,N-dimethylformamide solvate]

CCDC 1410364: Experimental Crystal Structure Determination : catena-[tetrakis(mu-iodo)-bis(mu-1,4-diazabicyclo[2.2.2]octane)-tetra-copper (mu-2,2'-(1,3-phenylene)bis(benzimidazol-1-yl))-di-copper N,N-dimethylformamide solvate]

Cite this

Host–Guest Chirality Interplay: A Mutually Induced Formation of a Chiral ZMOF and Its Double-Helix Polymer Guests

Abstract

Bibliographical note

Access to Document

Other files and links

Fingerprint

Datasets

CCDC 1410366: Experimental Crystal Structure Determination : catena-[tetrakis(mu-iodo)-bis(mu-1,4-diazabicyclo[2.2.2]octane)-tetra-copper (mu-2,2'-(1,3-phenylene)bis(benzimidazol-1-yl))-di-copper N,N-dimethylformamide solvate]

CCDC 1410365: Experimental Crystal Structure Determination : catena-[tetrakis(mu-iodo)-bis(mu-1,4-diazabicyclo[2.2.2]octane)-tetra-copper (mu-2,2'-(1,3-phenylene)bis(benzimidazol-1-yl))-di-copper N,N-dimethylformamide solvate]

CCDC 1410364: Experimental Crystal Structure Determination : catena-[tetrakis(mu-iodo)-bis(mu-1,4-diazabicyclo[2.2.2]octane)-tetra-copper (mu-2,2'-(1,3-phenylene)bis(benzimidazol-1-yl))-di-copper N,N-dimethylformamide solvate]

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