Homogeneous catalysis in water Part II. Synthesis and characterization of ruthenium water-soluble complexes

E. Fache; C. Santini; F. Senocq; J. M. Basset

doi:10.1016/0304-5102(92)85010-D

Homogeneous catalysis in water Part II. Synthesis and characterization of ruthenium water-soluble complexes

E. Fache, C. Santini, F. Senocq, J. M. Basset^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

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Abstract

Seven water-soluble complexes of ruthenium and TPPTS have been prepared and characterized (TPPTS is the trisodium salt of the tri(m-sulfophenyl)phosphine):[RuCl₂(TPPTS)₂]₂ 1, RuHCl(TPPTS)₃ 2, RuH(OAc)(TPPS)₃ 3, RuH₂(TPPTS)₄ 4, RuHI(TPPTS)₃ 5, RuCl₂(CO)₂(TPPTS)₂ 6 and [Ru(OAc)(CO)₂(TPPTS)]₂ 7. Spectroscopic investigations have shown that in solution they have the same structures as their organosoluble analogues containing the ligand PPh₃.

Original language	English (US)
Pages (from-to)	331-336
Number of pages	6
Journal	Journal of molecular catalysis
Volume	72
Issue number	3
DOIs	https://doi.org/10.1016/0304-5102(92)85010-D
State	Published - Mar 15 1992
Externally published	Yes

ASJC Scopus subject areas

General Engineering

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title = "Homogeneous catalysis in water Part II. Synthesis and characterization of ruthenium water-soluble complexes",

abstract = "Seven water-soluble complexes of ruthenium and TPPTS have been prepared and characterized (TPPTS is the trisodium salt of the tri(m-sulfophenyl)phosphine):[RuCl2(TPPTS)2]2 1, RuHCl(TPPTS)3 2, RuH(OAc)(TPPS)3 3, RuH2(TPPTS)4 4, RuHI(TPPTS)3 5, RuCl2(CO)2(TPPTS)2 6 and [Ru(OAc)(CO)2(TPPTS)]2 7. Spectroscopic investigations have shown that in solution they have the same structures as their organosoluble analogues containing the ligand PPh3.",

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year = "1992",

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T1 - Homogeneous catalysis in water Part II. Synthesis and characterization of ruthenium water-soluble complexes

AU - Fache, E.

AU - Santini, C.

AU - Senocq, F.

AU - Basset, J. M.

PY - 1992/3/15

Y1 - 1992/3/15

N2 - Seven water-soluble complexes of ruthenium and TPPTS have been prepared and characterized (TPPTS is the trisodium salt of the tri(m-sulfophenyl)phosphine):[RuCl2(TPPTS)2]2 1, RuHCl(TPPTS)3 2, RuH(OAc)(TPPS)3 3, RuH2(TPPTS)4 4, RuHI(TPPTS)3 5, RuCl2(CO)2(TPPTS)2 6 and [Ru(OAc)(CO)2(TPPTS)]2 7. Spectroscopic investigations have shown that in solution they have the same structures as their organosoluble analogues containing the ligand PPh3.

AB - Seven water-soluble complexes of ruthenium and TPPTS have been prepared and characterized (TPPTS is the trisodium salt of the tri(m-sulfophenyl)phosphine):[RuCl2(TPPTS)2]2 1, RuHCl(TPPTS)3 2, RuH(OAc)(TPPS)3 3, RuH2(TPPTS)4 4, RuHI(TPPTS)3 5, RuCl2(CO)2(TPPTS)2 6 and [Ru(OAc)(CO)2(TPPTS)]2 7. Spectroscopic investigations have shown that in solution they have the same structures as their organosoluble analogues containing the ligand PPh3.

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U2 - 10.1016/0304-5102(92)85010-D

DO - 10.1016/0304-5102(92)85010-D

M3 - Article

AN - SCOPUS:0026831312

SN - 0304-5102

VL - 72

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JO - Journal of molecular catalysis

JF - Journal of molecular catalysis

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ER -

Homogeneous catalysis in water Part II. Synthesis and characterization of ruthenium water-soluble complexes

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