Hollow nanoporous covalent triazine frameworks via acid vapor-assisted solid phase synthesis for enhanced visible light photoactivity

Wei Huang; Zi Jun Wang; Beatriz Chiyin Ma; Saman Ghasimi; Dominik Gehrig; Frédéric Laquai; Katharina Landfester; Kai A. I. Zhang

doi:10.1039/C6TA01828A

Hollow nanoporous covalent triazine frameworks via acid vapor-assisted solid phase synthesis for enhanced visible light photoactivity

Wei Huang, Zi Jun Wang, Beatriz Chiyin Ma, Saman Ghasimi, Dominik Gehrig, Frédéric Laquai, Katharina Landfester, Kai A. I. Zhang

Research output: Contribution to journal › Article › peer-review

113 Scopus citations

Abstract

Herein, we report a novel trifluoromethanesulfonic acid vapor-assisted solid phase synthetic method to construct nanoporous covalent triazine frameworks with highly ordered hollow interconnected pores under mild reaction conditions. This unique solid state synthetic route allows not only the avoidance of undesired side reactions caused by traditional high temperature synthesis, but also the maintaining of defined and precise optical and electronic properties of the nonporous triazine frameworks. Promising photocatalytic activity of the polytriazine networks was demonstrated in the photoreduction reaction of 4-nitrophenol into 4-aminophenol under visible light irradiation.

Original language	English (US)
Pages (from-to)	7555-7559
Number of pages	5
Journal	J. Mater. Chem. A
Volume	4
Issue number	20
DOIs	https://doi.org/10.1039/C6TA01828A
State	Published - 2016

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: The authors thank the Max Planck Society for the financial
support. W. H. thanks the China Scholarship Council (CSC)
(No. 201406240010) for the scholarship. Z. J. W. thanks the
fellowship by the Excellence Initiative (DFG/GSC 266) of the
graduate school of excellence “MAINZ” (Materials Science in
Mainz). B. C. M. acknowledges the financial support from
DAAD, CAPES and CNPq. D. G thanks the Fonds der
Chemischen Industrie (FCI) for the Kekule scholarship.

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10.1039/C6TA01828A

https://repository.kaust.edu.sa/bitstream/10754/608587/1/c6ta01828a.pdf

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title = "Hollow nanoporous covalent triazine frameworks via acid vapor-assisted solid phase synthesis for enhanced visible light photoactivity",

abstract = "Herein, we report a novel trifluoromethanesulfonic acid vapor-assisted solid phase synthetic method to construct nanoporous covalent triazine frameworks with highly ordered hollow interconnected pores under mild reaction conditions. This unique solid state synthetic route allows not only the avoidance of undesired side reactions caused by traditional high temperature synthesis, but also the maintaining of defined and precise optical and electronic properties of the nonporous triazine frameworks. Promising photocatalytic activity of the polytriazine networks was demonstrated in the photoreduction reaction of 4-nitrophenol into 4-aminophenol under visible light irradiation.",

author = "Wei Huang and Wang, {Zi Jun} and Ma, {Beatriz Chiyin} and Saman Ghasimi and Dominik Gehrig and Fr{\'e}d{\'e}ric Laquai and Katharina Landfester and Zhang, {Kai A. I.}",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: The authors thank the Max Planck Society for the financial support. W. H. thanks the China Scholarship Council (CSC) (No. 201406240010) for the scholarship. Z. J. W. thanks the fellowship by the Excellence Initiative (DFG/GSC 266) of the graduate school of excellence “MAINZ” (Materials Science in Mainz). B. C. M. acknowledges the financial support from DAAD, CAPES and CNPq. D. G thanks the Fonds der Chemischen Industrie (FCI) for the Kekule scholarship.",

year = "2016",

doi = "10.1039/C6TA01828A",

language = "English (US)",

volume = "4",

pages = "7555--7559",

journal = "J. Mater. Chem. A",

issn = "2050-7488",

publisher = "Royal Society of Chemistry",

number = "20",

}

TY - JOUR

T1 - Hollow nanoporous covalent triazine frameworks via acid vapor-assisted solid phase synthesis for enhanced visible light photoactivity

AU - Huang, Wei

AU - Wang, Zi Jun

AU - Ma, Beatriz Chiyin

AU - Ghasimi, Saman

AU - Gehrig, Dominik

AU - Laquai, Frédéric

AU - Landfester, Katharina

AU - Zhang, Kai A. I.

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: The authors thank the Max Planck Society for the financial support. W. H. thanks the China Scholarship Council (CSC) (No. 201406240010) for the scholarship. Z. J. W. thanks the fellowship by the Excellence Initiative (DFG/GSC 266) of the graduate school of excellence “MAINZ” (Materials Science in Mainz). B. C. M. acknowledges the financial support from DAAD, CAPES and CNPq. D. G thanks the Fonds der Chemischen Industrie (FCI) for the Kekule scholarship.

PY - 2016

Y1 - 2016

N2 - Herein, we report a novel trifluoromethanesulfonic acid vapor-assisted solid phase synthetic method to construct nanoporous covalent triazine frameworks with highly ordered hollow interconnected pores under mild reaction conditions. This unique solid state synthetic route allows not only the avoidance of undesired side reactions caused by traditional high temperature synthesis, but also the maintaining of defined and precise optical and electronic properties of the nonporous triazine frameworks. Promising photocatalytic activity of the polytriazine networks was demonstrated in the photoreduction reaction of 4-nitrophenol into 4-aminophenol under visible light irradiation.

AB - Herein, we report a novel trifluoromethanesulfonic acid vapor-assisted solid phase synthetic method to construct nanoporous covalent triazine frameworks with highly ordered hollow interconnected pores under mild reaction conditions. This unique solid state synthetic route allows not only the avoidance of undesired side reactions caused by traditional high temperature synthesis, but also the maintaining of defined and precise optical and electronic properties of the nonporous triazine frameworks. Promising photocatalytic activity of the polytriazine networks was demonstrated in the photoreduction reaction of 4-nitrophenol into 4-aminophenol under visible light irradiation.

UR - http://hdl.handle.net/10754/608587

UR - http://xlink.rsc.org/?DOI=C6TA01828A

UR - http://www.scopus.com/inward/record.url?scp=84969851210&partnerID=8YFLogxK

U2 - 10.1039/C6TA01828A

DO - 10.1039/C6TA01828A

M3 - Article

SN - 2050-7488

VL - 4

SP - 7555

EP - 7559

JO - J. Mater. Chem. A

JF - J. Mater. Chem. A

IS - 20

ER -

Hollow nanoporous covalent triazine frameworks via acid vapor-assisted solid phase synthesis for enhanced visible light photoactivity

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