High-temperature generalized synthesis of stable ordered mesoporous silica-based materials by using fluorocarbon-hydrocarbon surfactant mixtures

Yu Han; Defeng Li; Lan Zhao; Jiangwei Song; Xiaoyu Yang; Nan Li; Yan Di; Caijin Li; Shuo Wu; Xianzhu Xu; Xiangju Meng; Kaifeng Lin; Feng Shou Xiao

doi:10.1002/anie.200351466

High-temperature generalized synthesis of stable ordered mesoporous silica-based materials by using fluorocarbon-hydrocarbon surfactant mixtures

Yu Han, Defeng Li, Lan Zhao, Jiangwei Song, Xiaoyu Yang, Nan Li, Yan Di, Caijin Li, Shuo Wu, Xianzhu Xu, Xiangju Meng, Kaifeng Lin, Feng Shou Xiao^*

^*Corresponding author for this work

Physical Sciences and Engineering

Research output: Contribution to journal › Article › peer-review

157 Scopus citations

Abstract

Highly ordered mesoporous silica materials are hydrothermally synthesized at high temperature by using fluorocarbon-hydrocarbon surfactant mixtures as templates. Because of the high temperature of the synthesis, the obtained materials show complete silica condensation, which give rise to ultra-stabile structures. JLU-20 for example (see TEM image of calcined JLU-20) has a fully condensed mesopore wall with a very high Q⁴/Q³ ratio of 6.5.

Original language	English (US)
Pages (from-to)	3633-3637
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	42
Issue number	31
DOIs	https://doi.org/10.1002/anie.200351466
State	Published - Aug 11 2003

Keywords

Fluorinated ligands
High-temperature chemistry
Mesoporous materials
Silicates
Surfactants

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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10.1002/anie.200351466

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Han, Y., Li, D., Zhao, L., Song, J., Yang, X., Li, N., Di, Y., Li, C., Wu, S., Xu, X., Meng, X., Lin, K., & Xiao, F. S. (2003). High-temperature generalized synthesis of stable ordered mesoporous silica-based materials by using fluorocarbon-hydrocarbon surfactant mixtures. Angewandte Chemie - International Edition, 42(31), 3633-3637. https://doi.org/10.1002/anie.200351466

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title = "High-temperature generalized synthesis of stable ordered mesoporous silica-based materials by using fluorocarbon-hydrocarbon surfactant mixtures",

abstract = "Highly ordered mesoporous silica materials are hydrothermally synthesized at high temperature by using fluorocarbon-hydrocarbon surfactant mixtures as templates. Because of the high temperature of the synthesis, the obtained materials show complete silica condensation, which give rise to ultra-stabile structures. JLU-20 for example (see TEM image of calcined JLU-20) has a fully condensed mesopore wall with a very high Q4/Q3 ratio of 6.5.",

keywords = "Fluorinated ligands, High-temperature chemistry, Mesoporous materials, Silicates, Surfactants",

author = "Yu Han and Defeng Li and Lan Zhao and Jiangwei Song and Xiaoyu Yang and Nan Li and Yan Di and Caijin Li and Shuo Wu and Xianzhu Xu and Xiangju Meng and Kaifeng Lin and Xiao, {Feng Shou}",

year = "2003",

month = aug,

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doi = "10.1002/anie.200351466",

language = "English (US)",

volume = "42",

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Han, Y, Li, D, Zhao, L, Song, J, Yang, X, Li, N, Di, Y, Li, C, Wu, S, Xu, X, Meng, X, Lin, K & Xiao, FS 2003, 'High-temperature generalized synthesis of stable ordered mesoporous silica-based materials by using fluorocarbon-hydrocarbon surfactant mixtures', Angewandte Chemie - International Edition, vol. 42, no. 31, pp. 3633-3637. https://doi.org/10.1002/anie.200351466

TY - JOUR

T1 - High-temperature generalized synthesis of stable ordered mesoporous silica-based materials by using fluorocarbon-hydrocarbon surfactant mixtures

AU - Han, Yu

AU - Li, Defeng

AU - Zhao, Lan

AU - Song, Jiangwei

AU - Yang, Xiaoyu

AU - Li, Nan

AU - Di, Yan

AU - Li, Caijin

AU - Wu, Shuo

AU - Xu, Xianzhu

AU - Meng, Xiangju

AU - Lin, Kaifeng

AU - Xiao, Feng Shou

PY - 2003/8/11

Y1 - 2003/8/11

N2 - Highly ordered mesoporous silica materials are hydrothermally synthesized at high temperature by using fluorocarbon-hydrocarbon surfactant mixtures as templates. Because of the high temperature of the synthesis, the obtained materials show complete silica condensation, which give rise to ultra-stabile structures. JLU-20 for example (see TEM image of calcined JLU-20) has a fully condensed mesopore wall with a very high Q4/Q3 ratio of 6.5.

AB - Highly ordered mesoporous silica materials are hydrothermally synthesized at high temperature by using fluorocarbon-hydrocarbon surfactant mixtures as templates. Because of the high temperature of the synthesis, the obtained materials show complete silica condensation, which give rise to ultra-stabile structures. JLU-20 for example (see TEM image of calcined JLU-20) has a fully condensed mesopore wall with a very high Q4/Q3 ratio of 6.5.

KW - Fluorinated ligands

KW - High-temperature chemistry

KW - Mesoporous materials

KW - Silicates

KW - Surfactants

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U2 - 10.1002/anie.200351466

DO - 10.1002/anie.200351466

M3 - Article

C2 - 12916034

AN - SCOPUS:0041968426

SN - 1433-7851

VL - 42

SP - 3633

EP - 3637

JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 31

ER -

High-temperature generalized synthesis of stable ordered mesoporous silica-based materials by using fluorocarbon-hydrocarbon surfactant mixtures

Abstract

Keywords

ASJC Scopus subject areas

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