TY - JOUR
T1 - Hexakis{μ2-4-[2-(diisopropyl-amino)ethyl-amino] pent-3-en-2-onato-k3 N,O:O}tricalcium(II) hexane solvate
AU - Richard, P.
AU - Eleter, M.
AU - Hubert-Pfalzgraf, L. G.
AU - Daniele, S.
PY - 2007/7/31
Y1 - 2007/7/31
N2 - The title compound, [Ca3(C13H25N2O)6]·C6H14, is a trinuclear complex with all Ca atoms presenting octa-hedral coordination. The central Ca atom (as well as the hexane solvent mol-ecule) is located on a crystallographic twofold rotation axis and is coordinated by six bridging O atoms, with Ca - O distances ranging from 2.344 (1) to 2.351 (1) Å. The terminal Ca atoms are coordinated by three bridging O atoms, with Ca - O distances ranging from 2.311 (1) to 2.335 (1) Å, and three N atoms of the Β-ketoiminate ligands, with Ca - N distances ranging from 2.432 (1) to 2.452 (1) Å. One of the diisopropylamino groups is disordered over two positions, with site occipancy factors of ca 0.54 and 0.46.
AB - The title compound, [Ca3(C13H25N2O)6]·C6H14, is a trinuclear complex with all Ca atoms presenting octa-hedral coordination. The central Ca atom (as well as the hexane solvent mol-ecule) is located on a crystallographic twofold rotation axis and is coordinated by six bridging O atoms, with Ca - O distances ranging from 2.344 (1) to 2.351 (1) Å. The terminal Ca atoms are coordinated by three bridging O atoms, with Ca - O distances ranging from 2.311 (1) to 2.335 (1) Å, and three N atoms of the Β-ketoiminate ligands, with Ca - N distances ranging from 2.432 (1) to 2.452 (1) Å. One of the diisopropylamino groups is disordered over two positions, with site occipancy factors of ca 0.54 and 0.46.
UR - http://www.scopus.com/inward/record.url?scp=34547733552&partnerID=8YFLogxK
U2 - 10.1107/S1600536807031789
DO - 10.1107/S1600536807031789
M3 - Article
AN - SCOPUS:34547733552
SN - 1600-5368
VL - 63
SP - m2049-m2050
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 8
ER -