Hexakis{μ2-4-[2-(diisopropyl-amino)ethyl-amino] pent-3-en-2-onato-k3 N,O:O}tricalcium(II) hexane solvate

P. Richard*, M. Eleter, L. G. Hubert-Pfalzgraf, S. Daniele

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review


The title compound, [Ca3(C13H25N2O)6]·C6H14, is a trinuclear complex with all Ca atoms presenting octa-hedral coordination. The central Ca atom (as well as the hexane solvent mol-ecule) is located on a crystallographic twofold rotation axis and is coordinated by six bridging O atoms, with Ca - O distances ranging from 2.344 (1) to 2.351 (1) Å. The terminal Ca atoms are coordinated by three bridging O atoms, with Ca - O distances ranging from 2.311 (1) to 2.335 (1) Å, and three N atoms of the Β-ketoiminate ligands, with Ca - N distances ranging from 2.432 (1) to 2.452 (1) Å. One of the diisopropylamino groups is disordered over two positions, with site occipancy factors of ca 0.54 and 0.46.

Original languageEnglish (US)
Pages (from-to)m2049-m2050
JournalActa Crystallographica Section E: Structure Reports Online
Issue number8
StatePublished - Jul 31 2007
Externally publishedYes

ASJC Scopus subject areas

  • General Chemistry
  • General Materials Science
  • Condensed Matter Physics


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