Hexakis{μ2-4-[2-(diisopropyl-amino)ethyl-amino] pent-3-en-2-onato-k3 N,O:O}tricalcium(II) hexane solvate

P. Richard; M. Eleter; L. G. Hubert-Pfalzgraf; S. Daniele

doi:10.1107/S1600536807031789

Hexakis{μ₂-4-[2-(diisopropyl-amino)ethyl-amino] pent-3-en-2-onato-k³ N,O:O}tricalcium(II) hexane solvate

P. Richard^*, M. Eleter, L. G. Hubert-Pfalzgraf, S. Daniele

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

The title compound, [Ca3(C13H25N2O)6]·C6H14, is a trinuclear complex with all Ca atoms presenting octa-hedral coordination. The central Ca atom (as well as the hexane solvent mol-ecule) is located on a crystallographic twofold rotation axis and is coordinated by six bridging O atoms, with Ca - O distances ranging from 2.344 (1) to 2.351 (1) Å. The terminal Ca atoms are coordinated by three bridging O atoms, with Ca - O distances ranging from 2.311 (1) to 2.335 (1) Å, and three N atoms of the Β-ketoiminate ligands, with Ca - N distances ranging from 2.432 (1) to 2.452 (1) Å. One of the diisopropylamino groups is disordered over two positions, with site occipancy factors of ca 0.54 and 0.46.

Original language	English (US)
Pages (from-to)	m2049-m2050
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	63
Issue number	8
DOIs	https://doi.org/10.1107/S1600536807031789
State	Published - Jul 31 2007
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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@article{350bf46593ed483fba768bee4810547b,

title = "Hexakis{μ2-4-[2-(diisopropyl-amino)ethyl-amino] pent-3-en-2-onato-k3 N,O:O}tricalcium(II) hexane solvate",

abstract = "The title compound, [Ca3(C13H25N2O)6]·C6H14, is a trinuclear complex with all Ca atoms presenting octa-hedral coordination. The central Ca atom (as well as the hexane solvent mol-ecule) is located on a crystallographic twofold rotation axis and is coordinated by six bridging O atoms, with Ca - O distances ranging from 2.344 (1) to 2.351 (1) {\AA}. The terminal Ca atoms are coordinated by three bridging O atoms, with Ca - O distances ranging from 2.311 (1) to 2.335 (1) {\AA}, and three N atoms of the Β-ketoiminate ligands, with Ca - N distances ranging from 2.432 (1) to 2.452 (1) {\AA}. One of the diisopropylamino groups is disordered over two positions, with site occipancy factors of ca 0.54 and 0.46.",

author = "P. Richard and M. Eleter and Hubert-Pfalzgraf, {L. G.} and S. Daniele",

year = "2007",

month = jul,

day = "31",

doi = "10.1107/S1600536807031789",

language = "English (US)",

volume = "63",

pages = "m2049--m2050",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "8",

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TY - JOUR

T1 - Hexakis{μ2-4-[2-(diisopropyl-amino)ethyl-amino] pent-3-en-2-onato-k3 N,O:O}tricalcium(II) hexane solvate

AU - Richard, P.

AU - Eleter, M.

AU - Hubert-Pfalzgraf, L. G.

AU - Daniele, S.

PY - 2007/7/31

Y1 - 2007/7/31

N2 - The title compound, [Ca3(C13H25N2O)6]·C6H14, is a trinuclear complex with all Ca atoms presenting octa-hedral coordination. The central Ca atom (as well as the hexane solvent mol-ecule) is located on a crystallographic twofold rotation axis and is coordinated by six bridging O atoms, with Ca - O distances ranging from 2.344 (1) to 2.351 (1) Å. The terminal Ca atoms are coordinated by three bridging O atoms, with Ca - O distances ranging from 2.311 (1) to 2.335 (1) Å, and three N atoms of the Β-ketoiminate ligands, with Ca - N distances ranging from 2.432 (1) to 2.452 (1) Å. One of the diisopropylamino groups is disordered over two positions, with site occipancy factors of ca 0.54 and 0.46.

AB - The title compound, [Ca3(C13H25N2O)6]·C6H14, is a trinuclear complex with all Ca atoms presenting octa-hedral coordination. The central Ca atom (as well as the hexane solvent mol-ecule) is located on a crystallographic twofold rotation axis and is coordinated by six bridging O atoms, with Ca - O distances ranging from 2.344 (1) to 2.351 (1) Å. The terminal Ca atoms are coordinated by three bridging O atoms, with Ca - O distances ranging from 2.311 (1) to 2.335 (1) Å, and three N atoms of the Β-ketoiminate ligands, with Ca - N distances ranging from 2.432 (1) to 2.452 (1) Å. One of the diisopropylamino groups is disordered over two positions, with site occipancy factors of ca 0.54 and 0.46.

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U2 - 10.1107/S1600536807031789

DO - 10.1107/S1600536807031789

M3 - Article

AN - SCOPUS:34547733552

SN - 1600-5368

VL - 63

SP - m2049-m2050

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 8

ER -

Hexakis{μ₂-4-[2-(diisopropyl-amino)ethyl-amino] pent-3-en-2-onato-k³ N,O:O}tricalcium(II) hexane solvate

Abstract

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