H-shaped oligothiophenes with low band gaps and amphoteric redox properties

Jing Luo; Kuo-Wei Huang; Hemi Qu; Xiaojie Zhang; Lijun Zhu; Hardysze Chan; Chunyan Chi

doi:10.1021/ol102456c

H-shaped oligothiophenes with low band gaps and amphoteric redox properties

Jing Luo, Kuo-Wei Huang, Hemi Qu, Xiaojie Zhang, Lijun Zhu, Hardysze Chan, Chunyan Chi

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

H-shaped bridged oligothiophenes HT-1 and HT-2 were synthesized by two different approaches. Different from normal oligothiophenes, HT-1 and HT-2 showed low band gaps and amphoteric redox behaviors due to intramolecular charge transfer, which is further supported by time-dependent DFT calculations. © 2010 American Chemical Society.

Original language	English (US)
Pages (from-to)	5660-5663
Number of pages	4
Journal	Organic Letters
Volume	12
Issue number	24
DOIs	https://doi.org/10.1021/ol102456c
State	Published - Dec 17 2010

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: We acknowledge financial support from AcRF Tier 1 FRC grants R-143-000-444-112, R-143-000-412-112, and R-143-000-370-112 to C.C. and from KAUST baseline funding to K.-W.H.

ASJC Scopus subject areas

Biochemistry
Organic Chemistry
Physical and Theoretical Chemistry

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10.1021/ol102456c

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title = "H-shaped oligothiophenes with low band gaps and amphoteric redox properties",

abstract = "H-shaped bridged oligothiophenes HT-1 and HT-2 were synthesized by two different approaches. Different from normal oligothiophenes, HT-1 and HT-2 showed low band gaps and amphoteric redox behaviors due to intramolecular charge transfer, which is further supported by time-dependent DFT calculations. {\textcopyright} 2010 American Chemical Society.",

author = "Jing Luo and Kuo-Wei Huang and Hemi Qu and Xiaojie Zhang and Lijun Zhu and Hardysze Chan and Chunyan Chi",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: We acknowledge financial support from AcRF Tier 1 FRC grants R-143-000-444-112, R-143-000-412-112, and R-143-000-370-112 to C.C. and from KAUST baseline funding to K.-W.H.",

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T1 - H-shaped oligothiophenes with low band gaps and amphoteric redox properties

AU - Luo, Jing

AU - Huang, Kuo-Wei

AU - Qu, Hemi

AU - Zhang, Xiaojie

AU - Zhu, Lijun

AU - Chan, Hardysze

AU - Chi, Chunyan

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: We acknowledge financial support from AcRF Tier 1 FRC grants R-143-000-444-112, R-143-000-412-112, and R-143-000-370-112 to C.C. and from KAUST baseline funding to K.-W.H.

PY - 2010/12/17

Y1 - 2010/12/17

N2 - H-shaped bridged oligothiophenes HT-1 and HT-2 were synthesized by two different approaches. Different from normal oligothiophenes, HT-1 and HT-2 showed low band gaps and amphoteric redox behaviors due to intramolecular charge transfer, which is further supported by time-dependent DFT calculations. © 2010 American Chemical Society.

AB - H-shaped bridged oligothiophenes HT-1 and HT-2 were synthesized by two different approaches. Different from normal oligothiophenes, HT-1 and HT-2 showed low band gaps and amphoteric redox behaviors due to intramolecular charge transfer, which is further supported by time-dependent DFT calculations. © 2010 American Chemical Society.

UR - http://hdl.handle.net/10754/561585

UR - https://pubs.acs.org/doi/10.1021/ol102456c

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JO - Organic Letters

JF - Organic Letters

IS - 24

ER -

H-shaped oligothiophenes with low band gaps and amphoteric redox properties

Abstract

Bibliographical note

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