Group 4 Transition-Metal Complexes of an Aniline–Carbene–Phenol Ligand

Emmanuelle Despagnet-Ayoub; Lawrence M. Henling; Jay A. Labinger; John E. Bercaw

doi:10.1021/om4001567

Group 4 Transition-Metal Complexes of an Aniline–Carbene–Phenol Ligand

Emmanuelle Despagnet-Ayoub, Lawrence M. Henling, Jay A. Labinger, John E. Bercaw

Research output: Contribution to journal › Article › peer-review

33 Scopus citations

Abstract

Attempts to install a tridentate aniline-NHC-phenol (NCO) ligand on titanium and zirconium led instead to complexes resulting from unexpected rearrangement pathways that illustrate common behavior in carbene-early- transition-metal chemistry. © 2013 American Chemical Society.

Original language	English (US)
Pages (from-to)	2934-2938
Number of pages	5
Journal	Organometallics
Volume	32
Issue number	10
DOIs	https://doi.org/10.1021/om4001567
State	Published - May 9 2013
Externally published	Yes

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: This work was supported by a KAUST Center-In-Development Grant to King Fahd University of Petroleum and Minerals (Dhahran, Saudi Arabia) and the USDOE Office of Basic Energy Sciences (Grant No. DE-FG03-85ER13431). The Bruker KAPPA APEXII X-ray diffractometer was purchased via an NSF CRIF:MU award to the California Institute of Technology (CHE-0639094).
This publication acknowledges KAUST support, but has no KAUST affiliated authors.

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title = "Group 4 Transition-Metal Complexes of an Aniline–Carbene–Phenol Ligand",

abstract = "Attempts to install a tridentate aniline-NHC-phenol (NCO) ligand on titanium and zirconium led instead to complexes resulting from unexpected rearrangement pathways that illustrate common behavior in carbene-early- transition-metal chemistry. {\textcopyright} 2013 American Chemical Society.",

author = "Emmanuelle Despagnet-Ayoub and Henling, {Lawrence M.} and Labinger, {Jay A.} and Bercaw, {John E.}",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: This work was supported by a KAUST Center-In-Development Grant to King Fahd University of Petroleum and Minerals (Dhahran, Saudi Arabia) and the USDOE Office of Basic Energy Sciences (Grant No. DE-FG03-85ER13431). The Bruker KAPPA APEXII X-ray diffractometer was purchased via an NSF CRIF:MU award to the California Institute of Technology (CHE-0639094). This publication acknowledges KAUST support, but has no KAUST affiliated authors.",

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doi = "10.1021/om4001567",

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AU - Labinger, Jay A.

AU - Bercaw, John E.

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: This work was supported by a KAUST Center-In-Development Grant to King Fahd University of Petroleum and Minerals (Dhahran, Saudi Arabia) and the USDOE Office of Basic Energy Sciences (Grant No. DE-FG03-85ER13431). The Bruker KAPPA APEXII X-ray diffractometer was purchased via an NSF CRIF:MU award to the California Institute of Technology (CHE-0639094). This publication acknowledges KAUST support, but has no KAUST affiliated authors.

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N2 - Attempts to install a tridentate aniline-NHC-phenol (NCO) ligand on titanium and zirconium led instead to complexes resulting from unexpected rearrangement pathways that illustrate common behavior in carbene-early- transition-metal chemistry. © 2013 American Chemical Society.

AB - Attempts to install a tridentate aniline-NHC-phenol (NCO) ligand on titanium and zirconium led instead to complexes resulting from unexpected rearrangement pathways that illustrate common behavior in carbene-early- transition-metal chemistry. © 2013 American Chemical Society.

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Group 4 Transition-Metal Complexes of an Aniline–Carbene–Phenol Ligand

Abstract

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