Group 4 Transition-Metal Complexes of an Aniline–Carbene–Phenol Ligand

Emmanuelle Despagnet-Ayoub, Lawrence M. Henling, Jay A. Labinger, John E. Bercaw

Research output: Contribution to journalArticlepeer-review

32 Scopus citations

Abstract

Attempts to install a tridentate aniline-NHC-phenol (NCO) ligand on titanium and zirconium led instead to complexes resulting from unexpected rearrangement pathways that illustrate common behavior in carbene-early- transition-metal chemistry. © 2013 American Chemical Society.
Original languageEnglish (US)
Pages (from-to)2934-2938
Number of pages5
JournalOrganometallics
Volume32
Issue number10
DOIs
StatePublished - May 9 2013
Externally publishedYes

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: This work was supported by a KAUST Center-In-Development Grant to King Fahd University of Petroleum and Minerals (Dhahran, Saudi Arabia) and the USDOE Office of Basic Energy Sciences (Grant No. DE-FG03-85ER13431). The Bruker KAPPA APEXII X-ray diffractometer was purchased via an NSF CRIF:MU award to the California Institute of Technology (CHE-0639094).
This publication acknowledges KAUST support, but has no KAUST affiliated authors.

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