Fused pyrrolo[3,2-d:4,5-d′]bisthiazole-containing polymers for using in high-performance organic bulk heterojunction solar cells

Ruidong Xia; Mohammed Al-Hashimi; Wing C. Tsoi; Martin Heeney; Donal D.C. Bradley; Jenny Nelson

doi:10.1016/j.solmat.2011.09.027

Fused pyrrolo[3,2-d:4,5-d′]bisthiazole-containing polymers for using in high-performance organic bulk heterojunction solar cells

Ruidong Xia, Mohammed Al-Hashimi, Wing C. Tsoi, Martin Heeney, Donal D.C. Bradley, Jenny Nelson

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

We report a series of fused pyrrolo[3,2-d:4,5-d′]bisthiazole (PBTz)-containing polymers as OPV donor materials, which exhibit a combination of small optical band gap, good solubility and relatively high molecular weight. The performance of the organic photovoltaic cells (OPV) made using the PBTz-containing polymers is studied. The highest performance was obtained with the polymer exhibiting the strongest crystallinity in the blend film, a PBTz-fused bithiophene polymer. Blend devices made from this polymer with PC70BM delivered a short-circuit current density of up to 9.4 mA cm-2, an open-circuit voltage of 0.61 V, a fill factor of 53% and a power conversion efficiency of 3%. © 2011 Elsevier B.V. All rights reserved.

Original language	English (US)
Journal	Solar Energy Materials and Solar Cells
Volume	96
Issue number	1
DOIs	https://doi.org/10.1016/j.solmat.2011.09.027
State	Published - Jan 1 2012
Externally published	Yes

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title = "Fused pyrrolo[3,2-d:4,5-d′]bisthiazole-containing polymers for using in high-performance organic bulk heterojunction solar cells",

abstract = "We report a series of fused pyrrolo[3,2-d:4,5-d′]bisthiazole (PBTz)-containing polymers as OPV donor materials, which exhibit a combination of small optical band gap, good solubility and relatively high molecular weight. The performance of the organic photovoltaic cells (OPV) made using the PBTz-containing polymers is studied. The highest performance was obtained with the polymer exhibiting the strongest crystallinity in the blend film, a PBTz-fused bithiophene polymer. Blend devices made from this polymer with PC70BM delivered a short-circuit current density of up to 9.4 mA cm-2, an open-circuit voltage of 0.61 V, a fill factor of 53% and a power conversion efficiency of 3%. {\textcopyright} 2011 Elsevier B.V. All rights reserved.",

author = "Ruidong Xia and Mohammed Al-Hashimi and Tsoi, {Wing C.} and Martin Heeney and Bradley, {Donal D.C.} and Jenny Nelson",

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year = "2012",

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doi = "10.1016/j.solmat.2011.09.027",

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T1 - Fused pyrrolo[3,2-d:4,5-d′]bisthiazole-containing polymers for using in high-performance organic bulk heterojunction solar cells

AU - Xia, Ruidong

AU - Al-Hashimi, Mohammed

AU - Tsoi, Wing C.

AU - Heeney, Martin

AU - Bradley, Donal D.C.

AU - Nelson, Jenny

N1 - Generated from Scopus record by KAUST IRTS on 2019-11-27

PY - 2012/1/1

Y1 - 2012/1/1

N2 - We report a series of fused pyrrolo[3,2-d:4,5-d′]bisthiazole (PBTz)-containing polymers as OPV donor materials, which exhibit a combination of small optical band gap, good solubility and relatively high molecular weight. The performance of the organic photovoltaic cells (OPV) made using the PBTz-containing polymers is studied. The highest performance was obtained with the polymer exhibiting the strongest crystallinity in the blend film, a PBTz-fused bithiophene polymer. Blend devices made from this polymer with PC70BM delivered a short-circuit current density of up to 9.4 mA cm-2, an open-circuit voltage of 0.61 V, a fill factor of 53% and a power conversion efficiency of 3%. © 2011 Elsevier B.V. All rights reserved.

AB - We report a series of fused pyrrolo[3,2-d:4,5-d′]bisthiazole (PBTz)-containing polymers as OPV donor materials, which exhibit a combination of small optical band gap, good solubility and relatively high molecular weight. The performance of the organic photovoltaic cells (OPV) made using the PBTz-containing polymers is studied. The highest performance was obtained with the polymer exhibiting the strongest crystallinity in the blend film, a PBTz-fused bithiophene polymer. Blend devices made from this polymer with PC70BM delivered a short-circuit current density of up to 9.4 mA cm-2, an open-circuit voltage of 0.61 V, a fill factor of 53% and a power conversion efficiency of 3%. © 2011 Elsevier B.V. All rights reserved.

UR - https://linkinghub.elsevier.com/retrieve/pii/S0927024811005137

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DO - 10.1016/j.solmat.2011.09.027

M3 - Article

SN - 0927-0248

VL - 96

JO - Solar Energy Materials and Solar Cells

JF - Solar Energy Materials and Solar Cells

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ER -

Fused pyrrolo[3,2-d:4,5-d′]bisthiazole-containing polymers for using in high-performance organic bulk heterojunction solar cells

Abstract

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