Fused aromatic networks as a new class of gas hydrate inhibitors

Hyuk Jun Noh, Dongyoung Lee, Woojin Go, Gyucheol Choi, Yoon Kwang Im, Javeed Mahmood, Yongwon Seo, Jong Beom Baek

Research output: Contribution to journalArticlepeer-review

9 Scopus citations

Abstract

Fused aromatic networks (FANs) are attracting considerable interest in the scientific community because of their intriguing electronic properties and superior physiochemical stability due to their fully fused aromatic systems. Here, a three-dimensional (3D) cage-like organic network (3D-CON) and a vertical two-dimensional (2D) layered ladder structure (designated as V2D-BBL structure) were studied as materials for gas hydrate inhibitors because of their outstanding stability in high-pressure/low-temperature and periodically incorporated molecular building blocks. The V2D-BBL structure demonstrated remarkable performance, inhibiting the formation of both methane (CH4) and carbon dioxide (CO2) hydrates, comparable to conventional lactam-based polymers. It was determined that the designed perinone moiety in the V2D-BBL structure enables synergistic interactions with the host (water) and guest (CH4) molecules involved in hydrate nucleation. Given their pre-designability and inherent stability, the FANs hold enormous potential as gas hydrate inhibitors for industrial applications.
Original languageEnglish (US)
Pages (from-to)133691
JournalChemical Engineering Journal
DOIs
StatePublished - Nov 2021

Bibliographical note

KAUST Repository Item: Exported on 2022-01-27
Acknowledgements: This research was supported by the Creative Research Initiative (CRI, 2014R1A3A2069102), BK21 Plus (5120200413798), Science Research Center (SRC, 2016R1A5A1009405), and Mid-career Research (2021R1A2C2005856) programs through the National Research Foundation (NRF) of Korea, and the U-K Brand Project (2.210048.01) of UNIST. The authors acknowledge computational resources from the UNIST Supercomputing Center.

ASJC Scopus subject areas

  • Environmental Chemistry
  • General Chemical Engineering
  • General Chemistry
  • Industrial and Manufacturing Engineering

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