TY - JOUR
T1 - Functional Group Interconversion: Decarbonylative Borylation of Esters for the Synthesis of Organoboronates
AU - Guo, Lin
AU - Rueping, Magnus
N1 - KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: L.G. was supported by the China Scholarship Council.
PY - 2016/10/11
Y1 - 2016/10/11
N2 - A new and efficient nickel-catalyzed decarbonylative borylation reaction of carboxylic acid esters with bis(pinacolato)-diboron has been developed. This transformation allows access to structurally diverse aryl as well as alkenyl and alkyl boronate esters with high reactivity, broad substrate scope, and excellent functional-group tolerance. Further experiments show that this protocol can be carried out on a gram scale and applied to orthogonal synthetic strategies.
AB - A new and efficient nickel-catalyzed decarbonylative borylation reaction of carboxylic acid esters with bis(pinacolato)-diboron has been developed. This transformation allows access to structurally diverse aryl as well as alkenyl and alkyl boronate esters with high reactivity, broad substrate scope, and excellent functional-group tolerance. Further experiments show that this protocol can be carried out on a gram scale and applied to orthogonal synthetic strategies.
UR - http://hdl.handle.net/10754/622118
UR - http://onlinelibrary.wiley.com/doi/10.1002/chem.201604504/abstract
UR - http://www.scopus.com/inward/record.url?scp=84994669282&partnerID=8YFLogxK
U2 - 10.1002/chem.201604504
DO - 10.1002/chem.201604504
M3 - Article
C2 - 27717095
SN - 0947-6539
VL - 22
SP - 16787
EP - 16790
JO - Chemistry - A European Journal
JF - Chemistry - A European Journal
IS - 47
ER -