The synthesis and characterisation of [Ru(H)(η5-3- phenylindenyl)(iBu-Phoban)2] 4 is reported ( iBu-Phoban = 9-isobutyl-9-phosphabicyclo-[3.3.1]-nonane). 4 is obtained via alcoholysis of metathesis pre-catalyst M11, in a process that was previously thought to be limited to analogous complex [RuCl 2(PPh3)2(3-phenylindenylidene)] (M 10). This journal is © The Royal Society of Chemistry.
|Original language||English (US)|
|State||Published - 2014|
Bibliographical noteKAUST Repository Item: Exported on 2020-10-01
Acknowledgements: Research leading to these results has received funding from the European Community's Seventh Framework Programme (FP7/ 2007-2013) under grant agreement no. CP-FP 211468-2 EUMET. SPN thanks the ERC for Advanced Investigator Award 'FUNCAT'. SPN is a Royal Society Wolfson Research Merit Award holder. LC thanks BSC (QCM-2010-2-0020), and the HPC team of Enea for using the ENEA-GRID and the HPC facilities CRESCO in Portici (Italy) for access to remarkable computational resources. AP thanks the Spanish MICINN for a Ramon y Cajal contract (RYC-2009-04170) and Generalitat de Catalunya for a BE-DGR fellowship. We thank Umicore for gifts of materials and ligands.
ASJC Scopus subject areas
- Materials Chemistry
- Surfaces, Coatings and Films
- Metals and Alloys
- Ceramics and Composites
- Electronic, Optical and Magnetic Materials
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CCDC 976892: Experimental Crystal Structure Determination : Hydrido-(eta^5^-3-phenylindenyl)-bis(9-isobutyl-9-phosphabicyclo[3.3.1]nonane)-ruthenium
Manzini, S. (Creator), Nelson, D. J. (Creator), Lebl, T. (Creator), Poater, A. (Creator), Cavallo, L. (Creator), Slawin, A. M. Z. (Creator), Nolan, S. P. (Creator), Manzini, S. (Creator), Nelson, D. J. (Creator), Lebl, T. (Creator), Poater, A. (Creator), Slawin, A. M. Z. (Creator) & Nolan, S. P. (Creator), Cambridge Crystallographic Data Centre, Mar 28 2014
DOI: 10.5517/cc11sjn0, http://hdl.handle.net/10754/624295