From olefin metathesis catalyst to alcohol racemization catalyst in one step

Simone Manzini; César A. Urbina-Blanco; Albert Poater; Alexandra M.Z. Slawin; Luigi Cavallo; Steven P. Nolan

doi:10.1002/anie.201106915

From olefin metathesis catalyst to alcohol racemization catalyst in one step

Simone Manzini^*, César A. Urbina-Blanco, Albert Poater, Alexandra M.Z. Slawin, Luigi Cavallo, Steven P. Nolan

^*Corresponding author for this work

Physical Sciences and Engineering

Research output: Contribution to journal › Article › peer-review

56 Scopus citations

Abstract

Easy as π: An unusual indenylidene to Î·⁵- indenyl rearrangement of a ruthenium catalyst has been observed. The resulting complex is the formal decomposition product of an olefin metathesis precatalyst that displays exceptional activity in the racemization of chiral alcohols at very low catalyst loadings.

Original language	English (US)
Pages (from-to)	1042-1045
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	51
Issue number	4
DOIs	https://doi.org/10.1002/anie.201106915
State	Published - Jan 23 2012

Keywords

alcohols
computational chemistry
rearrangement
ruthenium
structure elucidation

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.201106915

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abstract = "Easy as π: An unusual indenylidene to {\^I}·5- indenyl rearrangement of a ruthenium catalyst has been observed. The resulting complex is the formal decomposition product of an olefin metathesis precatalyst that displays exceptional activity in the racemization of chiral alcohols at very low catalyst loadings.",

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AU - Manzini, Simone

AU - Urbina-Blanco, César A.

AU - Poater, Albert

AU - Slawin, Alexandra M.Z.

AU - Cavallo, Luigi

AU - Nolan, Steven P.

PY - 2012/1/23

Y1 - 2012/1/23

N2 - Easy as π: An unusual indenylidene to Î·5- indenyl rearrangement of a ruthenium catalyst has been observed. The resulting complex is the formal decomposition product of an olefin metathesis precatalyst that displays exceptional activity in the racemization of chiral alcohols at very low catalyst loadings.

AB - Easy as π: An unusual indenylidene to Î·5- indenyl rearrangement of a ruthenium catalyst has been observed. The resulting complex is the formal decomposition product of an olefin metathesis precatalyst that displays exceptional activity in the racemization of chiral alcohols at very low catalyst loadings.

KW - alcohols

KW - computational chemistry

KW - rearrangement

KW - ruthenium

KW - structure elucidation

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U2 - 10.1002/anie.201106915

DO - 10.1002/anie.201106915

M3 - Article

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ER -

From olefin metathesis catalyst to alcohol racemization catalyst in one step

Abstract

Keywords

ASJC Scopus subject areas

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