TY - JOUR
T1 - From large 12-membered macrometallacycles to ionic (NHC)2M +Cl- type complexes of gold and silver by modulation of the N-substituent of amido-functionalized N-heterocyclic carbene (NHC) ligands
AU - Samantaray, Manoja K.
AU - Pang, Keliang
AU - Shaikh, Mobin M.
AU - Ghosh, Prasenjit
PY - 2008/5/19
Y1 - 2008/5/19
N2 - A series of structurally diverse gold and silver complexes extending from ionic (NHC)2M+Cl- (M = Au, Ag) type complexes to large 12-membered macrometallacycles have been prepared by the appropriate modification of the N-substituent of amido-functionalized N-heterocyclic carbenes. Specifically, the ionic, [1-(R)-3-{N-(t-butylacetamido)imidazol-2- ylidene}]2M+Cl-, (R = t-Bu, i-Pr; M = Au, Ag; 1b, 1c, 2b, 2c) complexes, were obtained in case of the N-t-butyl substituent of the amido-functionalized sidearm while 12-membered macrometallacycles, [1-(R)-3-{N-(2,6-dii-propylphenylacetamido)imidazol-2-ylidene}] 2M2, (R = t-Bu, i-Pr; M = Au, Ag; 3b, 3c, 4b, 4c) were obtained in case of the 2,6-dii-propylphenyl N-substituent. These structurally diverse complexes of gold and silver were, however, prepared employing a common synthetic pathway involving the reactions of the imidazolium chloride salts (1a, 2a, 3a, 4a) with Ag2O to give the silver complexes (1b, 2b, 3b, 4b) and which, when treated with (SMe2)AuCl, gave the gold complexes (1c, 2c, 3c, 4c). Detailed density functional theory studies of 1b, 1c, 2b, 2c, 3b, 3c, 4b, and 4c were carried out to gain insight about the structure, bonding, and the electronic properties of these complexes. The NHC-metal interaction in the ionic 1b, 1c, 2b, and 2c complexes is primarily composed of the interaction of the carbene lone pair with the empty p orbital of the metal (5p for Ag and 6p for Au) while the same in the macrometallacyclic 3b, 3c, 4b, and 4c complexes consisted of the interaction of the carbene lone pair with the empty s orbital of the metal (5s for Ag and 6s for Au). The observation of a low energy emission in about the 580-650 nm region has been tentatively assigned to originate from the presence of weak metallophilic interaction in these macrometallacyclic 3b, 3c, 4b, and 4c complexes.
AB - A series of structurally diverse gold and silver complexes extending from ionic (NHC)2M+Cl- (M = Au, Ag) type complexes to large 12-membered macrometallacycles have been prepared by the appropriate modification of the N-substituent of amido-functionalized N-heterocyclic carbenes. Specifically, the ionic, [1-(R)-3-{N-(t-butylacetamido)imidazol-2- ylidene}]2M+Cl-, (R = t-Bu, i-Pr; M = Au, Ag; 1b, 1c, 2b, 2c) complexes, were obtained in case of the N-t-butyl substituent of the amido-functionalized sidearm while 12-membered macrometallacycles, [1-(R)-3-{N-(2,6-dii-propylphenylacetamido)imidazol-2-ylidene}] 2M2, (R = t-Bu, i-Pr; M = Au, Ag; 3b, 3c, 4b, 4c) were obtained in case of the 2,6-dii-propylphenyl N-substituent. These structurally diverse complexes of gold and silver were, however, prepared employing a common synthetic pathway involving the reactions of the imidazolium chloride salts (1a, 2a, 3a, 4a) with Ag2O to give the silver complexes (1b, 2b, 3b, 4b) and which, when treated with (SMe2)AuCl, gave the gold complexes (1c, 2c, 3c, 4c). Detailed density functional theory studies of 1b, 1c, 2b, 2c, 3b, 3c, 4b, and 4c were carried out to gain insight about the structure, bonding, and the electronic properties of these complexes. The NHC-metal interaction in the ionic 1b, 1c, 2b, and 2c complexes is primarily composed of the interaction of the carbene lone pair with the empty p orbital of the metal (5p for Ag and 6p for Au) while the same in the macrometallacyclic 3b, 3c, 4b, and 4c complexes consisted of the interaction of the carbene lone pair with the empty s orbital of the metal (5s for Ag and 6s for Au). The observation of a low energy emission in about the 580-650 nm region has been tentatively assigned to originate from the presence of weak metallophilic interaction in these macrometallacyclic 3b, 3c, 4b, and 4c complexes.
UR - http://www.scopus.com/inward/record.url?scp=44349188622&partnerID=8YFLogxK
U2 - 10.1021/ic702186g
DO - 10.1021/ic702186g
M3 - Article
C2 - 18410089
AN - SCOPUS:44349188622
SN - 0020-1669
VL - 47
SP - 4153
EP - 4165
JO - Inorganic chemistry
JF - Inorganic chemistry
IS - 10
ER -