Four-phase triple coaxial cylindrical microdomain morphology in a linear tetrablock quaterpolymer of styrene, isoprene, dimethylsiloxane, and 2-vinylpyridine [4]

Keiko Takahashi; Hirokazu Hasegawa; Takeji Hashimoto; Vasilios Bellas; Hermis Iatrou; Nikos Hadjichristidis

doi:10.1021/ma0255074

Four-phase triple coaxial cylindrical microdomain morphology in a linear tetrablock quaterpolymer of styrene, isoprene, dimethylsiloxane, and 2-vinylpyridine [4]

Keiko Takahashi, Hirokazu Hasegawa^*, Takeji Hashimoto, Vasilios Bellas, Hermis Iatrou, Nikos Hadjichristidis

^*Corresponding author for this work

Research output: Contribution to journal › Letter › peer-review

57 Scopus citations

Abstract

The four-phase triple coaxial cylindrical microdomain morphology in a linear tetrablock quarterpolymer, consisting of polystyrene (PS), polyisoprene (PI), poly(dimethylsiloxane) (PDMS) and poly(2-vinylpyridine) (P2VP) was discussed. The four phases were clearly distinguished by transmission electron microscopy (TEM) when the two-step selective staining was applied. The results showed that the PI, PDMS, and P2VP microphases formed triple coaxial cylinders with a hexagonal shape packed in a hexogonal array in the PS microphases, which formed the honeycomb shaped matrix.

Original language	English (US)
Pages (from-to)	4859-4861
Number of pages	3
Journal	Macromolecules
Volume	35
Issue number	13
DOIs	https://doi.org/10.1021/ma0255074
State	Published - Jun 18 2002
Externally published	Yes

ASJC Scopus subject areas

Materials Chemistry
Polymers and Plastics
Inorganic Chemistry
Organic Chemistry

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@article{85e9849eda734f959db28c7944a97ef2,

title = "Four-phase triple coaxial cylindrical microdomain morphology in a linear tetrablock quaterpolymer of styrene, isoprene, dimethylsiloxane, and 2-vinylpyridine [4]",

abstract = "The four-phase triple coaxial cylindrical microdomain morphology in a linear tetrablock quarterpolymer, consisting of polystyrene (PS), polyisoprene (PI), poly(dimethylsiloxane) (PDMS) and poly(2-vinylpyridine) (P2VP) was discussed. The four phases were clearly distinguished by transmission electron microscopy (TEM) when the two-step selective staining was applied. The results showed that the PI, PDMS, and P2VP microphases formed triple coaxial cylinders with a hexagonal shape packed in a hexogonal array in the PS microphases, which formed the honeycomb shaped matrix.",

author = "Keiko Takahashi and Hirokazu Hasegawa and Takeji Hashimoto and Vasilios Bellas and Hermis Iatrou and Nikos Hadjichristidis",

year = "2002",

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doi = "10.1021/ma0255074",

language = "English (US)",

volume = "35",

pages = "4859--4861",

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TY - JOUR

T1 - Four-phase triple coaxial cylindrical microdomain morphology in a linear tetrablock quaterpolymer of styrene, isoprene, dimethylsiloxane, and 2-vinylpyridine [4]

AU - Takahashi, Keiko

AU - Hasegawa, Hirokazu

AU - Hashimoto, Takeji

AU - Bellas, Vasilios

AU - Iatrou, Hermis

AU - Hadjichristidis, Nikos

PY - 2002/6/18

Y1 - 2002/6/18

N2 - The four-phase triple coaxial cylindrical microdomain morphology in a linear tetrablock quarterpolymer, consisting of polystyrene (PS), polyisoprene (PI), poly(dimethylsiloxane) (PDMS) and poly(2-vinylpyridine) (P2VP) was discussed. The four phases were clearly distinguished by transmission electron microscopy (TEM) when the two-step selective staining was applied. The results showed that the PI, PDMS, and P2VP microphases formed triple coaxial cylinders with a hexagonal shape packed in a hexogonal array in the PS microphases, which formed the honeycomb shaped matrix.

AB - The four-phase triple coaxial cylindrical microdomain morphology in a linear tetrablock quarterpolymer, consisting of polystyrene (PS), polyisoprene (PI), poly(dimethylsiloxane) (PDMS) and poly(2-vinylpyridine) (P2VP) was discussed. The four phases were clearly distinguished by transmission electron microscopy (TEM) when the two-step selective staining was applied. The results showed that the PI, PDMS, and P2VP microphases formed triple coaxial cylinders with a hexagonal shape packed in a hexogonal array in the PS microphases, which formed the honeycomb shaped matrix.

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U2 - 10.1021/ma0255074

DO - 10.1021/ma0255074

M3 - Letter

AN - SCOPUS:0037129995

SN - 0024-9297

VL - 35

SP - 4859

EP - 4861

JO - Macromolecules

JF - Macromolecules

IS - 13

ER -

Four-phase triple coaxial cylindrical microdomain morphology in a linear tetrablock quaterpolymer of styrene, isoprene, dimethylsiloxane, and 2-vinylpyridine [4]

Abstract

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