First-Generation Organic Reaction Intermediates in Zeolite Chemistry and Catalysis

Xuan Gong, Mustafa Caglayan, Yiru Ye, Kun Liu, Jorge Gascon, Abhishek Dutta Chowdhury

Research output: Contribution to journalArticlepeer-review

5 Scopus citations

Abstract

Zeolite chemistry and catalysis are expected to play a decisive role in the next decade(s) to build a more decentralized renewable feedstock-dependent sustainable society owing to the increased scrutiny over carbon emissions. Therefore, the lack of fundamental and mechanistic understanding of these processes is a critical "technical bottleneck" that must be eliminated to maximize economic value and minimize waste. We have identified, considering this objective, that the chemistry related to the first-generation reaction intermediates (i.e., carbocations, radicals, carbenes, ketenes, and carbanions) in zeolite chemistry and catalysis is highly underdeveloped or undervalued compared to other catalysis streams (e.g., homogeneous catalysis). This limitation can often be attributed to the technological restrictions to detect such "short-lived and highly reactive" intermediates at the interface (gas-solid/solid-liquid); however, the recent rise of sophisticated spectroscopic/analytical techniques (including under in situ/operando conditions) and modern data analysis methods collectively compete to unravel the impact of these organic intermediates. This comprehensive review summarizes the state-of-the-art first-generation organic reaction intermediates in zeolite chemistry and catalysis and evaluates their existing challenges and future prospects, to contribute significantly to the "circular carbon economy" initiatives.
Original languageEnglish (US)
JournalChemical Reviews
DOIs
StatePublished - Aug 10 2022

Bibliographical note

KAUST Repository Item: Exported on 2022-09-14
Acknowledgements: We acknowledge the financial support from the National Natural Science Foundation of China (NSFC) (grant no. 22050410276 to A.D.C.), the start-up research grant from Wuhan University (China), King Abdullah University of Science and Technology (Saudi Arabia), and the China Postdoctoral Science Foundation (2021M702515 and 2022T150493 to X.G.).

ASJC Scopus subject areas

  • Chemistry(all)

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