Femtosecond pump - probe spectroscopy reveals the photo-excited state and charge transfer of a photocatalytic metal-organic framework

M. A. Van Der Veen; K. Mazur; M. Nasalevich; M. Hurkmans; J. Gascon; F. Kapteijn; A. Houtepen; F. Grozema; M. Bonn; J. Hunger

Femtosecond pump - probe spectroscopy reveals the photo-excited state and charge transfer of a photocatalytic metal-organic framework

M. A. Van Der Veen, K. Mazur, M. Nasalevich, M. Hurkmans, J. Gascon, F. Kapteijn, A. Houtepen, F. Grozema, M. Bonn, J. Hunger

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

Metal-organic frameworks are nanoporous materials recently shown capable of photocatalysis. To optimize them as photocatalysts we need to understand the charge transfer to species included in the pores. We measured for the first time with femtosecond pump-probe spectroscopy the metal-organic framework NH2-MIL-125. We found that the after photoexcitation the hole resides on -NH2. Charge transfer from the MOF to an occluded molecule capable to shuttle single charges to a reaction centre is extremely fast (< 200 fs) while charge recombination only occurs on the ns-μs time scale.

Original language	English (US)
Title of host publication	19th International Conference on Ultrafast Phenomena, UP 2014
Publisher	Optical Society of American (OSA)
ISBN (Print)	1557522790, 9781557522795
State	Published - 2014
Externally published	Yes
Event	19th International Conference on Ultrafast Phenomena, UP 2014 - Okinawa, Japan Duration: Jul 7 2014 → Jul 11 2014

Conference

Conference	19th International Conference on Ultrafast Phenomena, UP 2014
Country/Territory	Japan
City	Okinawa
Period	07/7/14 → 07/11/14

ASJC Scopus subject areas

Instrumentation
Atomic and Molecular Physics, and Optics

Cite this

Van Der Veen, M. A., Mazur, K., Nasalevich, M., Hurkmans, M., Gascon, J., Kapteijn, F., Houtepen, A., Grozema, F., Bonn, M., & Hunger, J. (2014). Femtosecond pump - probe spectroscopy reveals the photo-excited state and charge transfer of a photocatalytic metal-organic framework. In 19th International Conference on Ultrafast Phenomena, UP 2014 Optical Society of American (OSA).

@inproceedings{393f332820bf4f7290a02978098ea18f,

title = "Femtosecond pump - probe spectroscopy reveals the photo-excited state and charge transfer of a photocatalytic metal-organic framework",

abstract = "Metal-organic frameworks are nanoporous materials recently shown capable of photocatalysis. To optimize them as photocatalysts we need to understand the charge transfer to species included in the pores. We measured for the first time with femtosecond pump-probe spectroscopy the metal-organic framework NH2-MIL-125. We found that the after photoexcitation the hole resides on -NH2. Charge transfer from the MOF to an occluded molecule capable to shuttle single charges to a reaction centre is extremely fast (< 200 fs) while charge recombination only occurs on the ns-μs time scale.",

author = "{Van Der Veen}, {M. A.} and K. Mazur and M. Nasalevich and M. Hurkmans and J. Gascon and F. Kapteijn and A. Houtepen and F. Grozema and M. Bonn and J. Hunger",

year = "2014",

language = "English (US)",

isbn = "1557522790",

booktitle = "19th International Conference on Ultrafast Phenomena, UP 2014",

publisher = "Optical Society of American (OSA)",

note = "19th International Conference on Ultrafast Phenomena, UP 2014 ; Conference date: 07-07-2014 Through 11-07-2014",

}

Van Der Veen, MA, Mazur, K, Nasalevich, M, Hurkmans, M, Gascon, J, Kapteijn, F, Houtepen, A, Grozema, F, Bonn, M & Hunger, J 2014, Femtosecond pump - probe spectroscopy reveals the photo-excited state and charge transfer of a photocatalytic metal-organic framework. in 19th International Conference on Ultrafast Phenomena, UP 2014. Optical Society of American (OSA), 19th International Conference on Ultrafast Phenomena, UP 2014, Okinawa, Japan, 07/7/14.

Femtosecond pump - probe spectroscopy reveals the photo-excited state and charge transfer of a photocatalytic metal-organic framework. / Van Der Veen, M. A.; Mazur, K.; Nasalevich, M. et al.
19th International Conference on Ultrafast Phenomena, UP 2014. Optical Society of American (OSA), 2014.

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - Femtosecond pump - probe spectroscopy reveals the photo-excited state and charge transfer of a photocatalytic metal-organic framework

AU - Van Der Veen, M. A.

AU - Mazur, K.

AU - Nasalevich, M.

AU - Hurkmans, M.

AU - Gascon, J.

AU - Kapteijn, F.

AU - Houtepen, A.

AU - Grozema, F.

AU - Bonn, M.

AU - Hunger, J.

PY - 2014

Y1 - 2014

N2 - Metal-organic frameworks are nanoporous materials recently shown capable of photocatalysis. To optimize them as photocatalysts we need to understand the charge transfer to species included in the pores. We measured for the first time with femtosecond pump-probe spectroscopy the metal-organic framework NH2-MIL-125. We found that the after photoexcitation the hole resides on -NH2. Charge transfer from the MOF to an occluded molecule capable to shuttle single charges to a reaction centre is extremely fast (< 200 fs) while charge recombination only occurs on the ns-μs time scale.

AB - Metal-organic frameworks are nanoporous materials recently shown capable of photocatalysis. To optimize them as photocatalysts we need to understand the charge transfer to species included in the pores. We measured for the first time with femtosecond pump-probe spectroscopy the metal-organic framework NH2-MIL-125. We found that the after photoexcitation the hole resides on -NH2. Charge transfer from the MOF to an occluded molecule capable to shuttle single charges to a reaction centre is extremely fast (< 200 fs) while charge recombination only occurs on the ns-μs time scale.

UR - http://www.scopus.com/inward/record.url?scp=84906663688&partnerID=8YFLogxK

M3 - Conference contribution

SN - 1557522790

SN - 9781557522795

BT - 19th International Conference on Ultrafast Phenomena, UP 2014

PB - Optical Society of American (OSA)

T2 - 19th International Conference on Ultrafast Phenomena, UP 2014

Y2 - 7 July 2014 through 11 July 2014

ER -

Femtosecond pump - probe spectroscopy reveals the photo-excited state and charge transfer of a photocatalytic metal-organic framework

Abstract

Conference

ASJC Scopus subject areas

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